scholarly journals Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis

2020 ◽  
Vol 22 (10) ◽  
pp. 3117-3121
Author(s):  
Chunping Chen ◽  
Maxwell Greenwood ◽  
Jean-Charles Buffet ◽  
Dermot O'Hare

Surface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.

2015 ◽  
Vol 44 (37) ◽  
pp. 16392-16398 ◽  
Author(s):  
Chunping Chen ◽  
Aunchana Wangriya ◽  
Jean-Charles Buffet ◽  
Dermot O'Hare

We report the synthesis of tuneable ultra high specific surface area Aqueous Miscible Organic solvent-Layered Double Hydroxides (AMO-LDHs).


2020 ◽  
Vol 9 (2) ◽  
pp. 108-116
Author(s):  
Tarmizi Taher ◽  
◽  
Nyanyu Ummu Hani ◽  
Neza Rahayu Palapa ◽  
Risfidian Mohadi ◽  
...  

In this work, two synthetic layered double hydroxides (LDH) consists of Zn2+ as M2+ cation with different M3+ cation, i.e., Al3+ and Cr3+ were used as an adsorbent for Congo Red removal aqueous solution. Both Zn-Al and Zn-Cr LDH were characterized by X-ray diffraction, FT-IR, and BET surface area analyzer. The effect of contact time, initial dye concentration, and temperature were evaluated in a batch technique in order to investigate the characteristic of Congo Red adsorption onto both adsorbents. The experimental data were assessed according to the parameter of adsorption kinetics, isotherm, and thermodynamics. The results of LDH characterization showed that Zn-Al LDH has a higher interlayer distance than Zn-Cr LDH, although Zn-Cr LDH has a higher surface area. The FT-IR analysis indicated the interlayer space of both Zn-Cr and Zn-Al LDH was dominated by CO32- as the interlayer anion species. The adsorption kinetics study of Congo Red on both LDH revealed that the adsorption process followed the pseudo-second-order model. For the adsorption isotherm, the experimental data fit well with the Freundlich model rather than the Langmuir model. The thermodynamic study indicated that the adsorption process that occurred on both adsorbents was spontaneous with exothermic nature.


2018 ◽  
Vol 6 (1) ◽  
pp. 12-29 ◽  
Author(s):  
Rajkumar Patel ◽  
Jung Tae Park ◽  
Madhumita Patel ◽  
Jatis Kumar Dash ◽  
E. Bhoje Gowd ◽  
...  

Transition metal based layered double hydroxides are important energy storage materials. The overall performances of the electrodes are dependent on conductivity, crystallinity, morphology, and surface area.


2016 ◽  
Vol 127 (3) ◽  
pp. 1863-1867 ◽  
Author(s):  
Ana C. F. Coriolano ◽  
Aline A. Alves ◽  
Renkel A. Araujo ◽  
Regina C. O. B. Delgado ◽  
Florival R. Carvalho ◽  
...  

2020 ◽  
Vol 29 ◽  
pp. 2633366X2092652 ◽  
Author(s):  
Haiyan Li ◽  
Xianping Wang ◽  
Xuemao Guan ◽  
Dinghua Zou

In this study, LiAl-layered double hydroxides Lithium aluminum hydrotalcite (LiAl-LDH) with different specific surface area were prepared by the separate nucleation and aging steps (SNAS) method and then were employed to prepare calcium sulfoaluminate cement-based grouting material (CBGM) paste. The influence of LiAl-LDH slurries on fresh and hardened properties of the CBGM paste was investigated in terms of fluidity, stability, setting time, and compressive strength. Additionally, the hydration process and hydration products of the CBGM paste were characterized by hydration heat, X-ray diffraction, differential thermal analysis–thermogravimetry, and Fourier transform infrared analyses. The acquired results illustrated that LiAl-LDH with larger specific surface area led to a faster hydration rate at early age, a lower fluidity, a shorter setting time, and a higher stability. Furthermore, due to the crystal nucleation effect, the addition of LiAl-LDH slurries did not cause a new phase to form but changed the morphology and increased the amount of hydration products, yielding higher compressive strength.


2017 ◽  
Vol 2 (6) ◽  
pp. 2077-2083 ◽  
Author(s):  
Hullukere ◽  
R. Prakruthi ◽  
Bellundagere ◽  
M. Chandrashekara ◽  
Bangalore ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (9) ◽  
pp. 5076-5083 ◽  
Author(s):  
Valentina Erastova ◽  
Matteo T. Degiacomi ◽  
Dermot O'Hare ◽  
H. Chris Greenwell

Molecular modelling elucidates the mechanism of layered double hydroxide dispersion, increasing surface area, during aqueous miscible organic solvent treatment.


2021 ◽  
Vol 23 (4) ◽  
pp. 1616-1620
Author(s):  
W. L. Joyce Kwok ◽  
Hongri Suo ◽  
Chunping Chen ◽  
D. W. Justin Leung ◽  
Jean-Charles Buffet ◽  
...  

An atom economic synthesis of dense porous layered double hydroxides (SLDHs) using an undesirable waste in wastewater treatment plants (struvite) is reported. The obtained SLDHs show high specific surface area, large pore volume and high density.


Sign in / Sign up

Export Citation Format

Share Document