Manufacturing pure cellulose films by recycling ionic liquids as plasticizers

2020 ◽  
Vol 22 (12) ◽  
pp. 3835-3841
Author(s):  
Longhui Li ◽  
Yun Zhang ◽  
Yanling Sun ◽  
Shuang Sun ◽  
Guancheng Shen ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Green Manufacturing ◽  
Manufacturing Method ◽  
Cellulose Films ◽  
Pure Cellulose ◽  
P Recycling ◽  
Electronic Substrates

Recycling ionic liquids as plasticizers, a green manufacturing method of pure cellulose films which can be used as electronic substrates is successfully demonstrated.

scholarly journals Synthesis of Quaternary Ammonium Room-Temperature Ionic Liquids and their Application in the Dissolution of Cellulose

2019 ◽  
Vol 9 (9) ◽  
pp. 1750 ◽  
Author(s):  
Yao-Hsuan Tseng ◽  
Yu-Yin Lee ◽  
Shih-Hsun Chen
Keyword(s):  
Ionic Liquids ◽  
Quaternary Ammonium ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Regenerated Cellulose ◽  
Exchange Reactions ◽  
Cellulose Films ◽  
Structural Regularity ◽  
Rapid Dissolution ◽  
Regenerated Cellulose Films

In this work, several kinds of quaternary ammonium-based room-temperature ionic liquids (QA RTILs) are synthesized by alkylation and ion-exchange reactions for the rapid dissolution of cellulose. The applications of cellulose materials have been limited due to their poor solubility in conventional organic solvents, because of a high degree of structural regularity and a large number of hydrogen bonds. The prepared ionic liquids were identified by nuclear magnetic resonance, elemental analysis, and liquid chromatography-mass spectrometry. The results indicated that N,N,N-triethylhexan-1-aminium acetate (N6222OAc), tetrahexylammonium acetate (N6666OAc), and N,N,N,N′,N′,N′-hexaethyldecane-1,10-diaminium acetate (C10(N222OAc)2) exhibited good cellulose-dissolution without any pretreatment. The regenerated cellulose films with a low degree of crystallization of the cellulose II phase were also prepared easily in this process using N6222OAc due to its polar and small cation. These QA RTILs can be used as non-derivatizing solvents for cellulose and can also be easily recycled because of their thermostable and nonvolatile properties.

Recycling textiles: the use of ionic liquids in the separation of cotton polyester blends

RSC Advances ◽  
2014 ◽  
Vol 4 (55) ◽  
pp. 29094-29098 ◽  
Author(s):  
Rasike De Silva ◽  
Xungai Wang ◽  
Nolene Byrne
Keyword(s):  
Ionic Liquids ◽  
Environmentally Sustainable ◽  
P Recycling

Recycling textiles: the use of ionic liquids in the separation of cotton polyester blends. A facile and environmentally sustainable solution.

Production of Bioactive Cellulose Films Reconstituted from Ionic Liquids

2004 ◽  
Vol 5 (4) ◽  
pp. 1379-1384 ◽  
Author(s):  
Megan B. Turner ◽  
Scott K. Spear ◽  
John D. Holbrey ◽  
Robin D. Rogers
Keyword(s):  
Ionic Liquids ◽  
Cellulose Films

Dissolution of Absorbent Cotton in Ionic Liquid and Characterization of the Regenerated Cellulose

2013 ◽  
Vol 830 ◽  
pp. 163-166 ◽  
Author(s):  
Ri Na Wu ◽  
Hu Zhu ◽  
Bei Hai He
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Chemical Properties ◽  
Regenerated Cellulose ◽  
Absorbent Cotton ◽  
Cellulose Films ◽  
Cotton Linters ◽  
Regenerated Cellulose Films ◽  
Tga Analysis

Dissolution of absorbent cotton (DP above 4000) using ionic liquids as solvent and regeneration was investigated. The results show that 1-ally-3-methylimidazolium chloride (AMIMCl) was a good solvent to dissolve absorbent cotton and a solution of 3 wt% can be reached in 18 min at 120°C. Besides, as the dissolving temperature increased the time needed for the cotton linters to dissolve decreased. The physic-chemical properties of the regenerated cellulose films were also characterized by XRD, FTIR and TGA analysis.

Characterization of the regenerated cellulose films in ionic liquids and rheological properties of the solutions

2011 ◽  
Vol 128 (1-2) ◽  
pp. 220-227 ◽  
Author(s):  
Zhen Liu ◽  
Hui Wang ◽  
Zengxi Li ◽  
Xingmei Lu ◽  
Xiangping Zhang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Rheological Properties ◽  
Regenerated Cellulose ◽  
Cellulose Films ◽  
Regenerated Cellulose Films

Preparation of Chitin/Cellulose Films Compatibilized with Polymeric Ionic Liquids

2013 ◽  
Vol 21 (3) ◽  
pp. 795-801 ◽  
Author(s):  
Miwa Setoyama ◽  
Takeshi Kato ◽  
Kazuya Yamamoto ◽  
Jun-ichi Kadokawa
Keyword(s):  
Ionic Liquids ◽  
Polymeric Ionic Liquids ◽  
Cellulose Films

scholarly journals Blending of Cellulose and Chitosan in Alkyl Imidazolium Ionic Liquids

2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
Olga Kuzmina ◽  
Thomas Heinze ◽  
Dariusz Wawro
Keyword(s):  
Mechanical Properties ◽  
Ionic Liquids ◽  
Ethyl Acetate ◽  
Cellulose Film ◽  
Imidazolium Ionic Liquids ◽  
Pure Cellulose ◽  
Polymer Aggregates ◽  
Chitosan Films ◽  
Chitosan Blends ◽  
Blended Film

The production of cellulose/chitosan blends in alkyl imidazolium ionic liquids (ILs) was studied in this work. Selected organic solvents, such as dimethyl sulfoxide, ethyl acetate, and diethyl ether, were used as cosolvents. The addition of cosolvents decreased the viscosity of cellulose/chitosan solutions in ILs and facilitated the dissolution of polysaccharides, thereby decreasing the and polymer aggregates sizes in the solutions. The cellulose/chitosan films were produced from the studied solutions. The presence of one of cosolvent and ILs in the blended films was confirmed by FTIR spectroscopy. The blended film is stronger than pure cellulose film, and the addition of cosolvents has an influence on its mechanical properties.

scholarly journals Fabrication and Characterization of Regenerated Cellulose Films Using Different Ionic Liquids

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Jin-Hui Pang ◽  
Xin Liu ◽  
Miao Wu ◽  
Yu-Ying Wu ◽  
Xue-Ming Zhang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Magic Angle Spinning ◽  
Regenerated Cellulose ◽  
Magic Angle ◽  
Force Microscopy ◽  
Cellulose Films ◽  
Atomic Force ◽  
Negative Impacts ◽  
Regenerated Cellulose Films ◽  
Angle Spinning

The demand for substitution of fossil-based materials by renewable bio-based materials is increasing with the fossil resources reduction and its negative impacts on the environment. In this study, environmentally friendly regenerated cellulose films were successfully prepared using 1-allyl-3-methylimidazolium chloride (AmimCl), 1-butyl-3-methylimidazolium chloride (BmimCl), 1-ethyl-3-methylimidazolium chloride (EmimCl), and 1-ethyl-3-methylimidazolium acetate (EmimAc) as solvents, respectively. The results of morphology from scanning electron microscopy (SEM) and atomic force microscopy (AFM) showed that all the cellulose films possessed smooth, highly uniform, and dense surface. The solid-state cross-polarization/magic angle spinning (CP/MAS)13C NMR spectra and X-ray diffraction (XRD) corroborated that the transition from cellulose I to II had occurred after preparation. Moreover, it was shown that the ionic liquid EmimAc possessed much stronger dissolubility for cellulose as compared with other ionic liquids and the cellulose film regenerated from EmimCl exhibited the most excellent tensile strength (119 Mpa). The notable properties of regenerated cellulose films are promising for applications in transparent biodegradable packaging and agricultural purpose as a substitute for PP and PE.

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