Identifying the liquid and glassy states of coordination polymers and metal–organic frameworks

2021 ◽  
Author(s):  
Alice M. Bumstead ◽  
Michael F. Thorne ◽  
Thomas D. Bennett
Keyword(s):  
Differential Scanning Calorimetry ◽  
Coordination Polymers ◽  
Glass Formation ◽  
Metal Organic Frameworks ◽  
Scanning Calorimetry ◽  
Melting Glass ◽  
Metal Organic

Melting, glass formation, amorphisation and crystallisation were confirmed in coordination polymers and metal–organic frameworks by differential scanning calorimetry.

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

Synthesis, designing strategies and photocatalytic charge dynamics of Metal-Organic Frameworks (MOFs): A catalyzed Photo-degradation approach towards Organic Dyes

2021 ◽  
Author(s):  
Ayushi Singh ◽  
Ashish Kumar Singh ◽  
Jian-Qiang Liu ◽  
Abhinav Kumar
Keyword(s):  
Small Molecule ◽  
Coordination Polymers ◽  
Organic Dyes ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
New Variety ◽  
Photo Degradation ◽  
Charge Dynamics ◽  
Potential Applications ◽  
Metal Organic

Metal-organic frameworks (MOFs) or coordination polymers (CPs) are regarded as new variety of materials that find potential applications in plethora of areas such as gas/small molecule absorption/separation, gas storage, membranes...

scholarly journals Coordination Polymers and Metal Organic Frameworks Derived from 1,2,4-Triazole Amino Acid Linkers

Polymers ◽  
2011 ◽  
Vol 3 (4) ◽  
pp. 1750-1775 ◽  
Author(s):  
Anil D. Naik ◽  
Marinela M. Dîrtu ◽  
Antoine P. Railliet ◽  
Jacqueline Marchand-Brynaert ◽  
Yann Garcia
Keyword(s):  
Amino Acid ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Investigation of the Preparation and Reactivity of Metal-Organic Frameworks of Cerium and Pyridine-2,4,6-Tricarboxylate

2021 ◽  
Author(s):  
Juliana Fonseca de Lima ◽  
Fernanda V.S. Moreno ◽  
Bruno A.T. Menezes ◽  
Jader da Silva Barbosa ◽  
Matthew C. Waddington ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Hydrothermal Conditions ◽  
Metal Organic

The synthesis of three coordination polymers of cerium(III) and the ligand pyridine-2,4,6-tricarboxylate (PTC) is reported. Two of the materials crystallise under hydrothermal conditions at 180 °C, with [Ce(PTC)(H2O)2]·1.5H2O, (1), being...

Coordination Polymers Versus Metal−Organic Frameworks

2009 ◽  
Vol 9 (7) ◽  
pp. 2969-2970 ◽  
Author(s):  
Kumar Biradha ◽  
Arunachalam Ramanan ◽  
Jagadese J. Vittal
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Prospects for electroactive and conducting framework materials

2019 ◽  
Vol 377 (2149) ◽  
pp. 20180226 ◽  
Author(s):  
Ryuichi Murase ◽  
Bowen Ding ◽  
Qinyi Gu ◽  
Deanna M. D'Alessandro
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Inorganic Materials ◽  
Framework Materials ◽  
Solar Energy Harvesting ◽  
Harvesting Systems ◽  
Potential Applications ◽  
History Of ◽  
Metal Organic ◽  
The Rich

Electroactive and conducting framework materials, encompassing coordination polymers and metal–organic frameworks, have captured the imagination of the scientific community owing to their highly designable nanoporous structures and their potential applications in electrochromic devices, electrocatalysts, porous conductors, batteries and solar energy harvesting systems, among many others. While they are now considered integral members of the broader field of inorganic materials, it is timely to reflect upon their strengths and challenges compared with ‘traditional’ solid-state materials such as minerals, pigments and zeolites. Indeed, the latter have been known since ancient times and have been prized for centuries in fields as diverse as art, archaeology and industrial catalysis. This opinion piece considers a brief historical perspective of traditional electroactive and conducting inorganic materials, with a view towards very recent experimental progress and new directions for future progress in the burgeoning area of coordination polymers and metal–organic frameworks. Overall, this article bears testament to the rich history of electroactive solids and looks at the challenges inspiring a new generation of scientists. This article is part of the theme issue ‘Mineralomimesis: natural and synthetic frameworks in science and technology’.

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