Toward ideal hole transport materials: a review on recent progress in dopant-free hole transport materials for fabricating efficient and stable perovskite solar cells

2020 ◽  
Vol 13 (11) ◽  
pp. 4057-4086 ◽  
Author(s):  
Xinxing Yin ◽  
Zhaoning Song ◽  
Zaifang Li ◽  
Weihua Tang
Keyword(s):  
Solar Cells ◽  
Rational Design ◽  
Recent Progress ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Free Hole ◽  
Fundamental Understanding

A review on the fundamental understanding and rational design of ideal, dopant-free HTMs for fabricating efficient and stable perovskite solar cells.

Structurally‐tuned benzo[1,2‐b:4,5:b'] dithiophene‐based polymer as a dopant‐free hole transport material for perovskite solar cells

2021 ◽  
Author(s):  
Henry Opoku ◽  
Ji Hyeon Lee ◽  
Benjamin Nketia‐Yawson ◽  
Hyungju Ahn ◽  
Jae‐Joon Lee ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Free Hole

scholarly journals Substituents interplay in piperidinyl-perylenediimide as dopant-free hole-selective layer for perovskite solar cells fabrication

2021 ◽  
Author(s):  
David Payno ◽  
Manuel Salado ◽  
Michael Andresini ◽  
David Gutiérrez-Moreno ◽  
Peng Huang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Performance Enhancement ◽  
Twist Angle ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Fine Tuning ◽  
Free Hole ◽  
Selective Layer ◽  
Energetic Level

AbstractThe charge selective layer is of significance for the fabrication of emerging photovoltaics, including perovskite-based solar cells. Molecular hole transport materials (HTMs) are being employed as charge transporters, owing to their synthetic molecular flexibility that allows the fine-tuning of their electro-optical properties. Typically, doping of HTMs is essential, but it is a trade-off between long-term durability and device performance. The energetic level of perylenediimides (PDIs) was altered by the position of the substituent. The substituent’s position influences the geometry of the PDI core, which can lose planarity, thus presenting a core twist angle between the two naphthalene subunits to find its application as hole-selective layers for fabrication. We have fabricated perovskite solar cells, with pristine PDI, and it gave a competitive performance. New design protocols for PDIs are required for aligned energetic levels, which will minimize recombination losses in solar cells, favoring a performance enhancement. Graphical abstract

scholarly journals Design and synthesis of dopant-free organic hole-transport materials for perovskite solar cells

2018 ◽  
Vol 54 (69) ◽  
pp. 9571-9574 ◽  
Author(s):  
Linqin Wang ◽  
Jinbao Zhang ◽  
Peng Liu ◽  
Bo Xu ◽  
Biaobiao Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Facile Synthesis ◽  
Free Hole ◽  
Design And Synthesis ◽  
Synthesis Routes

Two novel dopant-free hole-transport materials for perovskite solar cells with spiro[dibenzo[c,h]xanthene-7,9′-fluorene] skeletons were prepared via facile synthesis routes.

Annealing- and Doping-free Hole Transport Material for p-i-n Perovskite Solar Cells with Efficiency Achieving over 21%

2021 ◽  
pp. 133265
Author(s):  
Yikai Wang ◽  
Qiaoyun Chen ◽  
Jianfei Fu ◽  
Zhengxu Liu ◽  
Zhe Sun ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Free Hole

Conjugated copolymers as doping- and annealing-free hole transport materials for highly stable and efficient p–i–n perovskite solar cells

2021 ◽  
Author(s):  
Hui Ma ◽  
Ligang Yuan ◽  
Qiaoyun Chen ◽  
Jianfei Fu ◽  
Jiajia Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Free Hole ◽  
As Doping ◽  
Halide Perovskite ◽  
Conjugated Copolymers

Significant advances in organic–inorganic halide perovskite solar cells (Pero-SCs) have been achieved in recent times.

Simultaneously enhanced performance and stability of inverted perovskite solar cells via a rational design of hole transport layer

2019 ◽  
Vol 73 ◽  
pp. 69-75 ◽  
Author(s):  
Zhenhua Lin ◽  
Jiawen Zhou ◽  
Long Zhou ◽  
Kaixuan Wang ◽  
Wenqiang Li ◽  
...  
Keyword(s):  
Solar Cells ◽  
Rational Design ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer

Making benzotrithiophene derivatives dopant-free for perovskite solar cells: Step-saving installation of π-spacers by a direct C–H arylation strategy

2019 ◽  
Vol 7 (43) ◽  
pp. 24765-24770 ◽  
Author(s):  
Yi-Kai Peng ◽  
Kun-Mu Lee ◽  
Chang-Chieh Ting ◽  
Ming-Wei Hsu ◽  
Ching-Yuan Liu
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Free Hole

Perovskite solar cells using a new benzotrithiophene-based derivative as the dopant-free hole-transport material display promising efficiencies of up to 16.15%.

Recent Progress of Inverted Perovskite Solar Cells with a Modified PEDOT:PSS Hole Transport Layer

2020 ◽  
Vol 12 (44) ◽  
pp. 49297-49322
Author(s):  
Wenbin Han ◽  
Guanhua Ren ◽  
Jiuming Liu ◽  
Zhiqi Li ◽  
Hongchang Bao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Recent Progress ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer
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