scholarly journals Pentamethyl- and 1,2,4-tri(tert-butyl)cyclopentadienyl containing p-block complexes – differences and similarities

2021 ◽  
Vol 50 (6) ◽  
pp. 2067-2074
Author(s):  
Yi Ding ◽  
Paul Niklas Ruth ◽  
Regine Herbst-Irmer ◽  
Dietmar Stalke ◽  
Zhi Yang ◽  
...  

The sterically encumbered cyclopentadienyl ligand 1,2,4-(Me3C)3C5H2 (Cp′′′) effectively stabilizes the main group metals of Al, Ga, In, Ge and Sn with σ- or π-bonds.

2018 ◽  
Vol 130 (49) ◽  
pp. 16346-16351 ◽  
Author(s):  
Sisi He ◽  
Fenglou Ni ◽  
Yujin Ji ◽  
Lie Wang ◽  
Yunzhou Wen ◽  
...  
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