Nitrogen, sulfur co-doped carbon coated zinc sulfide for efficient hydrogen peroxide electrosynthesis

2021 ◽  
Author(s):  
Chengxiang Dai ◽  
Rongrong Li ◽  
Haichuan Guo ◽  
Shuqin Liang ◽  
Hangjia Shen ◽  
...  

Oxygen electroreduction (ORR) via two-electron pathway is a promising alternative for hydrogen peroxide (H2O2) synthesis in small-scale applications. In this work, nitrogen and sulfur co-doped carbon coated zinc sulfide nanoparticles...

2014 ◽  
Vol 118 (51) ◽  
pp. 30063-30070 ◽  
Author(s):  
Chang Hyuck Choi ◽  
Han Chang Kwon ◽  
Sunwoo Yook ◽  
Hyeyoung Shin ◽  
Hyungjun Kim ◽  
...  

2009 ◽  
Vol 45 (2) ◽  
pp. 177-188 ◽  
Author(s):  
D. N. RODRÍGUEZ-NAVARRO ◽  
M. CAMACHO ◽  
F. TEMPRANO ◽  
C. SANTAMARÍA ◽  
E. O. LEIDI

SUMMARYAhipa is a legume of great interest for the production of raw materials (starch, sugar, oil and proteins) for industrial use. Its yield potential and ability to fix atmospheric N2 in association with rhizobia makes it an attractive option for low input agriculture systems. At present, it is cultivated on a very small scale as a food crop in a few South American countries. Little information is available on symbiotic N2 fixation in ahipa and no work has been performed on strain selection for inoculant production. Soils in southwest Europe are devoid of specific rhizobia able to nodulate on ahipa. Selecting rhizobia for symbiotic effectiveness from a collection led to the isolation of strains which provided greater shoot growth and N content under controlled conditions. In the field, inoculation at sowing with the selected strains increased significantly seed and tuberous root yield and seed protein content. The amount of N2 fixed, estimated by 15N natural abundance, reached 160–260 kg N ha−1. In previous work, ahipa appeared to be a promising alternative crop for the production of industrial raw materials. The results of the present study showed a yield increase in tuberous roots and seeds when applying effective rhizobia inoculants. Furthermore, a positive soil N balance was left after its cultivation making ahipa even more interesting for sustainable farming systems.


Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4531
Author(s):  
Mihaela-Ramona Buga ◽  
Adnana Alina Spinu-Zaulet ◽  
Cosmin Giorgian Ungureanu ◽  
Raul-Augustin Mitran ◽  
Eugeniu Vasile ◽  
...  

Porous silica-based materials are a promising alternative to graphite anodes for Li-ion batteries due to their high theoretical capacity, low discharge potential similar to pure silicon, superior cycling stability compared to silicon, abundance, and environmental friendliness. However, several challenges prevent the practical application of silica anodes, such as low coulombic efficiency and irreversible capacity losses during cycling. The main strategy to tackle the challenges of silica as an anode material has been developed to prepare carbon-coated SiO2 composites by carbonization in argon atmosphere. A facile and eco-friendly method of preparing carbon-coated SiO2 composites using sucrose is reported herein. The carbon-coated SiO2 composites were characterized using X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetry, transmission and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, cyclic voltammetry, and charge–discharge cycling. A C/SiO2-0.085 M calendered electrode displays the best cycling stability, capacity of 714.3 mAh·g−1, and coulombic efficiency as well as the lowest charge transfer resistance over 200 cycles without electrode degradation. The electrochemical performance improvement could be attributed to the positive effect of the carbon thin layer that can effectively diminish interfacial impedance.


OALib ◽  
2015 ◽  
Vol 02 (05) ◽  
pp. 1-8 ◽  
Author(s):  
Milind Bodke ◽  
Hari Khawal ◽  
Umesh Gawai ◽  
Babasaheb Dole

2019 ◽  
Vol 25 (4) ◽  
pp. 270-281
Author(s):  
Asadollah Asadi ◽  
◽  
Arash Abdolmaleki ◽  
◽  

Aims Nanoparticles (particles with a diameter of 10-500 nm) are currently used in the cosmetics industry as well as for pharmaceuticals, diagnostic imaging, and tissue engineering. Since these nanoparticles are used in industry and drug delivery, they can also be used by pregnant women. Thus, the current study investigated the teratogenic and cytotoxic effects of Zinc Sulfide (ZnS) nanoparticles on the embryo and their fibroblastic cell culture. Methods & Materials Zinc sulfide (ZnS) nanoparticles were synthesized. Then, nanoparticles at the concentrations of 5, 10, 15, 30, and 40 mg/mL/egg were injected into the air sac of the eggs in three replicates on the third day of incubation. Next, the treated and control eggs, on day 19 of incubation were opened, and embryos were weighted, and the relevant mortality rate was recorded. Fibroblast cells were isolated, cultured, and treated from the control embryo, and morphological changes and cell survival percentages were recorded. Findings The obtained results revealed that the embryos’ survival rate depends on the nanoparticle concentration. As a result, at the highest concentration, only 36.32% of the embryos survived, and the lethal dose 50% (LD50) was equal to 32.47 mg/egg. Morphological study of the treated embryos club foot and skeletal staining suggested the deletion of caudal vertebrate. The cytotoxicity study results of ZnS nanoparticles on fibroblastic cells indicated the survival fractions of 88.45%, 68.75%, and 49.32%, respectively, and its IC50 value was measured aas1460 μM. Conclusion The present study results suggested that ZnS nanoparticles had no significant toxic effects on the embryos and culture of chicken fibroblastic cells at low concentrations.


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