scholarly journals Disentangling the magnetic dimensionality of an alleged magnetically isolated cuprate spin-ladder CuHpCl system: a long-lasting issue

2021 ◽  
Vol 50 (5) ◽  
pp. 1754-1765
Author(s):  
J. Jornet-Somoza ◽  
F. Cosi ◽  
M. Fumanal ◽  
M. Deumal

Ab initio computations reveal that the magnetic topology of CuHpCl is 3D calling into question the validity of being quoted as a spin-ladder system. The calculated magnetization enables discriminating between its gapped, gapless and polarized phases.

2013 ◽  
Vol 154 ◽  
pp. 60-63 ◽  
Author(s):  
K. Naruse ◽  
T. Kawamata ◽  
M. Ohno ◽  
Y. Matsuoka ◽  
K. Kumagai ◽  
...  

2014 ◽  
Vol 70 (a1) ◽  
pp. C927-C927
Author(s):  
Marie Colmont ◽  
Lukas Palatinus ◽  
Marielle Huvé ◽  
Olivier Mentré ◽  
Pascal Roussel

This communication will present the case study of ALa5O5(VO4)2 (A= Li, Na, K, Rb), example of the use of a combination of Precession Electron and X-ray Powder Data for the solution and the refinement of new materials. Indeed, an original structural type has been evidenced in the system (A, La, V, O) with A=Li, Na, K, Rb. Attempts to solve the structure ab initio on X-ray powder data were unsuccessful (more particularly because the powder was a mixture of the title compound and of unreacted precursors). The structure was finally solved by charge flipping using Precession Electron Data (3D tomography) on a nanocrystal, enabling a posteriori the good formulation of a pure powder. This powder was then classically refined by Rietveld method showing the correctness of the electron-solved structure. It crystallizes in a monoclinic unit cell with space group C2/m and a=20.2282(14) b=5.8639(4) c=12.6060(9) Å and β=117.64(1)0. The ALa5O5(VO4)2 structure is built of (OLa4) tetrahedral units creating Crenel-like 2D ribbons. These ribbons, surrounded by four isolated VO4 tetrahedra, are creating channels parallel to b axis in which A+ ions are located.


1996 ◽  
Vol 263 (1-4) ◽  
pp. 475-481 ◽  
Author(s):  
J. Akimitsu ◽  
M. Uehara ◽  
T. Nagata ◽  
S. Matsumoto ◽  
Y. Kitaoka ◽  
...  

2000 ◽  
Vol 281-282 ◽  
pp. 654-655 ◽  
Author(s):  
T. Yosihama ◽  
M. Nishi ◽  
K. Nakajima ◽  
N. Aso ◽  
K. Kakurai ◽  
...  

2004 ◽  
Vol 132 (9) ◽  
pp. 577-581 ◽  
Author(s):  
T. Suemoto ◽  
M. Nakajima ◽  
M. Aiba ◽  
M. Isob ◽  
Y. Ueda

2001 ◽  
Vol 70 (9) ◽  
pp. 2711-2716 ◽  
Author(s):  
Takeo Otsuka ◽  
Masahiro Yoshimaru ◽  
Kunio Awaga ◽  
Hiroyuki Imai ◽  
Tamotsu Inabe ◽  
...  

1999 ◽  
Vol 82 (3) ◽  
pp. 636-639 ◽  
Author(s):  
S. Katano ◽  
T. Nagata ◽  
J. Akimitsu ◽  
M. Nishi ◽  
K. Kakurai

2011 ◽  
Vol 13 (6) ◽  
pp. 065028 ◽  
Author(s):  
Wade DeGottardi ◽  
Diptiman Sen ◽  
Smitha Vishveshwara

Sign in / Sign up

Export Citation Format

Share Document