Extending the chemistry of weakly basic ligands: solvates of Ag+ and Cu+ stabilized by [Al{OC(CF3)3}4]− anion as model examples in the screening for useful weakly-interacting solvents

2021 ◽  
Author(s):  
Przemysław Jan Malinowski ◽  
Vadim Zhuravlev ◽  
Tomasz Jaroń ◽  
Gustavo Santiso-Quinones ◽  
Ingo Krossing
Keyword(s):  
Cationic Species ◽  
Weakly Coordinating Anions ◽  
Weakly Interacting ◽  
Weakly Coordinating ◽  
Synthetic Approaches

Weakly Coordinating Anions (WCAs) facilitate formation of exotic “naked” cationic species. However, feasibility of the respective synthetic approaches may be limited by the basicity of solvent utilized, as the latter...

scholarly journals Synthetic, Spectroscopic, Structural, and Electrochemical Investigations of Ferricenium Derivatives with Weakly Coordinating Anions: Ion Pairing, Substituent, and Solvent Effects

2021 ◽  
Author(s):  
Firoz Shah Tuglak Khan ◽  
Amy L Waldbusser ◽  
Maria C. C. Carrasco ◽  
Hadi Pourhadi ◽  
Shabnam Hematian
Keyword(s):  
Solvent Effects ◽  
Ion Pairing ◽  
Effective Strategy ◽  
Weakly Coordinating Anions ◽  
Weakly Coordinating ◽  
Electron Withdrawing Substituents

A facile and effective strategy for the preparation of a series of ferricenium complexes bearing either electron-donating or electron-withdrawing substituents with weakly coordinating anions such as [B(C6F5)4]– or SbF6– is...

scholarly journals Super-electrophiles of Tri- and Tetra-Anions Stabilized by Selected Terminal Groups and Their Role in Binding Noble Gas atoms

2021 ◽  
Author(s):  
MingMin Zhong ◽  
Hong Fang ◽  
Deepika Deepika ◽  
Purusottam Jena
Keyword(s):  
Gas Phase ◽  
Noble Gas ◽  
Atomic Clusters ◽  
Weakly Coordinating Anions ◽  
Multiply Charged ◽  
Potential Applications ◽  
Weakly Coordinating

Stabilization of multiply-charged atomic clusters in the gas phase has been a topic of great interest not only because of their potential applications as weakly-coordinating anions, but also for their...

Taming the Cationic Beast: Novel Developments in the Synthesis and Application of Weakly Coordinating Anions

2018 ◽  
Vol 57 (43) ◽  
pp. 13982-14024 ◽  
Author(s):  
Ian M. Riddlestone ◽  
Anne Kraft ◽  
Julia Schaefer ◽  
Ingo Krossing
Keyword(s):  
Weakly Coordinating Anions ◽  
Weakly Coordinating

Comparing Interactions of a Three-Coordinate Pd Cation with Common Weakly Coordinating Anions

2018 ◽  
Vol 37 (14) ◽  
pp. 2376-2385 ◽  
Author(s):  
Derek I. Wozniak ◽  
William A. Sabbers ◽  
Kushan C. Weerasiri ◽  
Luckym V. Dinh ◽  
Jacqueline L. Quenzer ◽  
...  
Keyword(s):  
Weakly Coordinating Anions ◽  
Weakly Coordinating

Aluminum-Ion Electrolytes with Weakly Coordinating Anions

2021 ◽  
Vol MA2021-01 (6) ◽  
pp. 308-308
Author(s):  
Xiaoyu Wen ◽  
Juchen Guo
Keyword(s):  
Aluminum Ion ◽  
Weakly Coordinating Anions ◽  
Weakly Coordinating

Synthesis and Crystal Structures of Silver Thianthrene Complexes with Weakly Coordinating Anions

2007 ◽  
Vol 62 (10) ◽  
pp. 1291-1297 ◽  
Author(s):  
Rachmat Triandi ◽  
Johannes Beck
Keyword(s):  
Sulfur Dioxide ◽  
Silver Complexes ◽  
Molecular Symmetry ◽  
Bridging Ligands ◽  
Liquid Sulfur ◽  
Structure Selection ◽  
Weakly Coordinating Anions ◽  
Secondary Bonds ◽  
Weakly Coordinating ◽  
Selection Of

Two novel silver complexes with thianthrene (TA) as a ligand have been synthesized in the poorly coordinating solvent liquid sulfur dioxide, using silver salts with weakly coordinating anions [BF4]− and [SbF6]−. Both colorless compounds contain discrete molecular entities and SO2 molecules included in the crystal structure. Selection of crystals and the diffraction data collection were performed at low temperatures (123 K). The tris(μ-thianthrene-κ2S)disilver(I) bis(hexafluoroantimonate) sulfur dioxide solvate [Ag2(TA)3][SbF6]2·5SO2 (1) (monoclinic, P21/c, a = 21.644(3), b = 12.4216(4), c = 21.934(3) Å , β = 115.04(1)°, Z = 4) is made up of complexes bearing three TA units acting as bridging ligands with both S atoms towards two Ag+ ions with d(Ag+-Ag+) = 2.911 Å giving the [Ag2(TA)3]2+ unit approximately D3h molecular symmetry. The bis(μ-thianthrene-κ2S)disilver(I) bis(tetrafluoroborate) sulfur dioxide solvate [Ag2(TA)2][BF4]2・3SO2 (2) (monoclinic, C2/c, a = 21.0045(6), b = 7.4553(2), c = 22.6024(6) A° , β = 109.65(0)°, Z = 4) is made up of [Ag2(TA)2]2+units with two bridging TA units coordinating two Ag+ ions with d(Ag+-Ag+) = 2.925 Å giving the complexes approximately D2h molecular symmetry. Weak, secondary bonds between Ag+ and the F atoms of the anions, such as Ag···F-SbF5 = 2.862(4) Å in 1 or Ag···F-BF3 = 2.773(2) Å in 2, and with O atoms of SO2 molecules link the complexes with the anions and the solvate molecules, respectively.

Weakly Coordinating Anions:  Crystallographic and NQR Studies of Halogen−Metal Bonding in Silver, Thallium, Sodium, and Potassium Halomethanesulfonates

2002 ◽  
Vol 41 (8) ◽  
pp. 2032-2040 ◽  
Author(s):  
Gary Wulfsberg ◽  
Katherine D. Parks ◽  
Richard Rutherford ◽  
Debra Jones Jackson ◽  
Frank E. Jones ◽  
...  
Keyword(s):  
Metal Bonding ◽  
Weakly Coordinating Anions ◽  
Weakly Coordinating ◽  
Sodium And Potassium

Innentitelbild: Weakly Coordinating Cations as Alternatives to Weakly Coordinating Anions (Angew. Chem. 5/2009)

2009 ◽  
Vol 121 (5) ◽  
pp. 844-844
Author(s):  
Craig J. Price ◽  
Hsuan-Ying Chen ◽  
L. Marie Launer ◽  
Stephen A. Miller
Keyword(s):  
Weakly Coordinating Anions ◽  
Weakly Coordinating

Weakly Coordinating Anions HA2-Generated from Oxoanions A-and Their Conjugate Acids. Coordination Equilibria, Ionic Conductivities, and the Structures of {Cu2(H(CH3SO3)2)4}nand [Cu(CO)(H(CF3CO2)2)]2

2000 ◽  
Vol 39 (8) ◽  
pp. 1735-1742 ◽  
Author(s):  
Oleg G. Polyakov ◽  
Benjamin G. Nolan ◽  
Benjamin P. Fauber ◽  
Susie M. Miller ◽  
Oren P. Anderson ◽  
...  
Keyword(s):  
Ionic Conductivities ◽  
Weakly Coordinating Anions ◽  
Weakly Coordinating

C–H Functionalization Reactions of Phenyl and Vinyl Carbocations Paired with Weakly Coordinating Anions

Synlett ◽  
2020 ◽  
Vol 31 (19) ◽  
pp. 1851-1856
Author(s):  
Hosea M. Nelson ◽  
Stasik Popov ◽  
Brian Shao ◽  
Alex L. Bagdasarian ◽  
Benjamin Wigman
Keyword(s):  
High Energy ◽  
Mechanistic Studies ◽  
Insertion Reactions ◽  
Weakly Coordinating Anions ◽  
Recent Developments ◽  
Weakly Coordinating ◽  
Weakly Coordinating Anion

Carbocations have played a central role in the chemical sciences for over a century. In a synthetic setting, most methods utilize stabilized tricoordinate carbocations, while there are far fewer examples of reactions featuring nonstabilized dicoordinate cations. Here, we provide an overview of recent developments in the generation of high-energy carbocations mediated by weakly coordinating anions and the C–H insertion reactions of such carbocations. Moreover, we discuss mechanistic studies of these catalytic C–H insertion reactions aimed at furthering our understanding of the reactive nature of these rarely invoked cationic intermediates.1 Introduction2 Background: Phenyl Carbocations3 Silylium/Carborane-Catalyzed C–H Insertion Reactions of Phenyl Carbocations4 Silane-Fueled, Weakly Coordinating Anion-Catalyzed, Reductive C–H Insertion Reactions of Vinyl Carbocations5 C–H Insertion Reactivity of Vinyl Carbocations under Basic Conditions6 Conclusion and Outlook

Sign in / Sign up

Export Citation Format

Share Document