Design of thiol–lithium ion interaction in metal–organic framework for high-performance quasi-solid lithium metal batteries

2021 ◽  
Author(s):  
Qi Zhang ◽  
Yingbo Xiao ◽  
Qi Li ◽  
Jia Wang ◽  
Sijia Guo ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
High Performance ◽  
Metal Organic Framework ◽  
Lithium Ion ◽  
Lithium Metal ◽  
Thiol Groups ◽  
Narrow Channels ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework (Zr–MA) was designed to serve as high-performance solid electrolyte in quasi-solid lithium metal batteries. Both the high-density thiol groups and narrow channels in framework contributed to the improved ion transport.

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

Metal-organic framework-engaged synthesis of core-shell MoO2/ZnSe@N-C nanorod for high-performance lithium-ion battery anode

2021 ◽  
Author(s):  
Bitao Su ◽  
Ming Zhong ◽  
Lingling Li ◽  
Kun Zhao ◽  
Hui Peng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
High Performance ◽  
Metal Organic Framework ◽  
Lithium Ion ◽  
Graphite Anode ◽  
Core Shell ◽  
Metal Organic ◽  
Battery Anode ◽  
Organic Framework

Searching for novel alternatives to traditional graphite anode for high performance lithium-ion batteries is of great significance, which, however, faces many challenges. In this work, a pyrolysis coupled with selenization...

Synthesis of ZnS/C Composites by Metal-Organic Framework as High-Performance Lithium-Ion Batteries

2019 ◽  
Vol 54 (6) ◽  
pp. 1800281 ◽  
Author(s):  
Hongda Wu ◽  
Guang Li ◽  
Yue Li ◽  
Zhongxing Geng ◽  
Tieqiang Ren ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Metal Organic Framework ◽  
Lithium Ion ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Kwan Woo Nam ◽  
Sarah S. Park ◽  
Roberto dos Reis ◽  
Vinayak P. Dravid ◽  
Heejin Kim ◽  
...  
Keyword(s):  
High Performance ◽  
Large Scale ◽  
High Current Density ◽  
Metal Organic Framework ◽  
Lithium Ion ◽  
Rechargeable Batteries ◽  
Economic Feasibility ◽  
Interfacial Resistance ◽  
Metal Organic ◽  
Organic Framework

Abstract Currently, there is considerable interest in developing advanced rechargeable batteries that boast efficient distribution of electricity and economic feasibility for use in large-scale energy storage systems. Rechargeable aqueous zinc batteries are promising alternatives to lithium-ion batteries in terms of rate performance, cost, and safety. In this investigation, we employ Cu3(HHTP)2, a two-dimensional (2D) conductive metal-organic framework (MOF) with large one-dimensional channels, as a zinc battery cathode. Owing to its unique structure, hydrated Zn2+ ions which are inserted directly into the host structure, Cu3(HHTP)2, allow high diffusion rate and low interfacial resistance which enable the Cu3(HHTP)2 cathode to follow the intercalation pseudocapacitance mechanism. Cu3(HHTP)2 exhibits a high reversible capacity of 228 mAh g−1 at 50 mA g−1. At a high current density of 4000 mA g−1 (~18 C), 75.0% of the initial capacity is maintained after 500 cycles. These results provide key insights into high-performance, 2D conductive MOF designs for battery electrodes.

A general anion exchange strategy to transform metal-organic framework embedded nanofibers into high-performance lithium-ion capacitors

Nano Energy ◽  
2020 ◽  
Vol 75 ◽  
pp. 104935
Author(s):  
Ye Bian ◽  
Shijie Wang ◽  
Dongdong Jin ◽  
Rutao Wang ◽  
Chun Chen ◽  
...  
Keyword(s):  
Anion Exchange ◽  
High Performance ◽  
Metal Organic Framework ◽  
Lithium Ion ◽  
Metal Organic ◽  
Organic Framework
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