scholarly journals 2-Pyridone-stabilized iridium silylene/silyl complexes: structure and QTAIM analysis

2020 ◽  
Vol 49 (48) ◽  
pp. 17665-17673
Author(s):  
Jefferson Guzmán ◽  
Ana M. Bernal ◽  
Pilar García-Orduña ◽  
Fernando J. Lahoz ◽  
Víctor Polo ◽  
...  
Keyword(s):  
Qtaim Analysis ◽  
Silyl Complexes ◽  
Silylene Complexes

An example of chelate-stabilized iridium-silylene complexes.

1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group

2015 ◽  
Vol 51 (84) ◽  
pp. 15465-15468 ◽  
Author(s):  
Holger Braunschweig ◽  
Rian D. Dewhurst ◽  
Krzysztof Radacki ◽  
Benedikt Wennemann ◽  
Qing Ye
Keyword(s):  
Alkyl Group ◽  
Elimination Reaction ◽  
Silyl Complexes ◽  
Silylene Complexes

The results present a new elimination reaction, the 1,2-alkylborane elimination, as a new route to silylene complexes.

scholarly journals Hidden aspects of the Structural theory of chemistry: MC-QTAIM analysis reveals “alchemical” transformation from a triatomic to a diatomic structure

2015 ◽  
Vol 17 (1) ◽  
pp. 245-255 ◽  
Author(s):  
Mohammad Goli ◽  
Shant Shahbazian
Keyword(s):  
Critical Mass ◽  
Structural Theory ◽  
Qtaim Analysis ◽  
Triatomic Molecules

The structures of the triatomic molecules transform topologically into the diatomics diminishing the mass of quantum proton below the critical mass.

Formation of Unique Platinum–Silyl Complexes by the Reactions of a Zero-valent Platinum Complex with Various Trisilanes

2012 ◽  
Vol 41 (11) ◽  
pp. 1538-1540 ◽  
Author(s):  
Hidekazu Arii ◽  
Makiko Takahashi ◽  
Hideyuki Takahashi ◽  
Kunio Mochida ◽  
Takayuki Kawashima
Keyword(s):  
Platinum Complex ◽  
Silyl Complexes

QTAIM Analysis of the Bonding in Mo–Mo Bonded Dimolybdenum Complexes

2012 ◽  
Vol 51 (13) ◽  
pp. 7384-7391 ◽  
Author(s):  
Juan F. Van der Maelen ◽  
Javier A. Cabeza
Keyword(s):  
Qtaim Analysis
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