Aza-crown compounds synthesised by the self-condensation of 2-amino-benzyl alcohol over a pincer ruthenium catalyst and applied in the transfer hydrogenation of ketones

2020 ◽  
Vol 49 (44) ◽  
pp. 15821-15827
Author(s):  
Shanshan Zhang ◽  
Zheng Wang ◽  
Qianrong Cao ◽  
Erlin Yue ◽  
Qingbin Liu ◽  
...  

Three aza-crown compounds are synthesized through the self-condensation of 2-aminobenzyl alcohol, and their iron complexes conducted hydrogenation of ketones into alcohols.

Synlett ◽  
2019 ◽  
Vol 30 (04) ◽  
pp. 503-507 ◽  
Author(s):  
Jacob Schneekönig ◽  
Kathrin Junge ◽  
Matthias Beller

The asymmetric transfer hydrogenation of ketones using isopropyl alcohol (IPA) as hydrogen donor in the presence of novel manganese catalysts is explored. The selective and active systems are easily generated in situ from [MnBr(CO)5] and inexpensive C 2-symmeric bisoxalamide ligands. Under the optimized reaction conditions, the Mn-derived catalyst gave higher enantioselectivity compared with the related ruthenium catalyst.


2011 ◽  
Vol 30 (23) ◽  
pp. 6339-6342 ◽  
Author(s):  
Ismael Nieto ◽  
Michelle S. Livings ◽  
John B. Sacci ◽  
Lauren E. Reuther ◽  
Matthias Zeller ◽  
...  

2015 ◽  
Vol 33 (4) ◽  
pp. 405-408 ◽  
Author(s):  
Nan Dai ◽  
Rui Shang ◽  
Mingchen Fu ◽  
Yao Fu

2018 ◽  
Vol 47 (11) ◽  
pp. 3764-3774 ◽  
Author(s):  
Pooja Dubey ◽  
Sonu Gupta ◽  
Ajai K. Singh

Base free transfer hydrogenation and N-alkylation of aniline with benzyl alcohol were catalyzed by Ir(iii) complexes (0.1–0.5 mol%).


ChemPlusChem ◽  
2016 ◽  
Vol 81 (6) ◽  
pp. 541-549 ◽  
Author(s):  
Yinzheng Xie ◽  
Mengpan Wang ◽  
Xiaohui Wu ◽  
Chen Chen ◽  
Wenbo Ma ◽  
...  

ACS Catalysis ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 11302-11306 ◽  
Author(s):  
Lorenz Pardatscher ◽  
Benjamin J. Hofmann ◽  
Pauline J. Fischer ◽  
Sebastian M. Hölzl ◽  
Robert M. Reich ◽  
...  

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