The first pentagonal-bipyramidal vanadium(iii) complexes with a Schiff-base N3O2 pentadentate ligand: synthesis, structure and magnetic properties

2020 ◽  
Vol 49 (43) ◽  
pp. 15287-15298
Author(s):  
Tamara A. Bazhenova ◽  
Leokadiya V. Zorina ◽  
Sergey V. Simonov ◽  
Vladimir S. Mironov ◽  
Olga V. Maximova ◽  
...  

A series of three mononuclear pentagonal-bipyramidal V(iii) complexes with the equatorial pentadentate N3O2-ligand were synthesized and characterized structurally and magnetically.

Polyhedron ◽  
2021 ◽  
pp. 115603
Author(s):  
Anup Choudhury ◽  
Prashurya Pritam Mudoi ◽  
Kaushik Narayan Eshore ◽  
Dhruva Jyoti Lahkar ◽  
Bipul Sarma ◽  
...  

2008 ◽  
Vol 63 (1) ◽  
pp. 6-10 ◽  
Author(s):  
Hulya Kara Balikesir

The synthesis, crystal structure and magnetic properties of [Mn(III)L(H2O)]2(H2O)(ClO4) (1)(L = N,N'-bis(rac-5-chlorosalicylidenato)-1,2-diaminopropane) are reported. Compound 1 consists of a structurally dinuclear system in which two Mn ions are bridged by the oxygen atoms of μ-phenoxo ligands. Low temperature magnetic susceptibility measurements show a ferromagnetic intra-dimer interaction with J = +1.75 cm−1, g = 2.01 and α = −0.32.


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