Thermally robust and valence-variation-induced white-light emission of a novel stannate phosphor Sr3Al10SnO20:Dy3+: crystal structure, luminescence property, and mechanism investigation

2020 ◽  
Vol 49 (44) ◽  
pp. 15800-15809
Author(s):  
Shuangyu Xin ◽  
Miao Gao ◽  
Jialing Ma ◽  
Heng Dai ◽  
Ge Zhu

Structure, luminescence property, and mechanism investigation of a valence-variation-induced tunable white-light emission of a novel stannate phosphor with robust thermal stability.

2018 ◽  
Vol 29 (15) ◽  
pp. 12632-12638 ◽  
Author(s):  
Zaifa Yang ◽  
Changjian Ji ◽  
Gongnian Zhang ◽  
Guimei Han ◽  
Hui Wang ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (17) ◽  
pp. 9777-9782 ◽  
Author(s):  
Xiaobin Wang ◽  
Yi Guo ◽  
Zhuoyi Li ◽  
Wen Ying ◽  
Danke Chen ◽  
...  

The nanoconfined R-phycoerythrin protein in ZIF-8 shows dual color emissions and exhibits high-quality white light emission and good thermal stability.


CrystEngComm ◽  
2014 ◽  
Vol 16 (36) ◽  
pp. 8390-8397 ◽  
Author(s):  
Yi-Hua Zhang ◽  
Xia Li ◽  
Shuang Song ◽  
Hong-Yu Yang ◽  
Dou Ma ◽  
...  

New lanthanide coordination frameworks were synthesized. White light emission and up-conversion emission were realized using Gd:Tb,Eu/Gd:Yb,Er doped complexes, respectively.


CrystEngComm ◽  
2015 ◽  
Vol 17 (20) ◽  
pp. 3838-3844 ◽  
Author(s):  
Rui Huo ◽  
Xia Li ◽  
Dou Ma

3D frameworks were constructed from tetrameric Ln4 as SBUs by 1,3-BDC and ox. The Yb:Tb:Eu doped complex reveals significant multicolor luminescence. High-efficiency white light emission was achieved.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Ning Liu ◽  
Lefu Mei ◽  
Libing Liao ◽  
Jie Fu ◽  
Dan Yang

Abstract What ideal w-LED phosphors always aim to do is to achieve a single phase near-sunlight emission phosphor simultaneously with both high luminescence efficiency and high thermal stability at operation temperature. And It is well known that apatite compound phosphors are one of the most promising optical materials to realize those above because of their unique structure enhanced luminescence properties and thermal stability. Here, we synthesized a co-doped single phase apatite phosphors Ca2La8(SiO4)6O2:Dy3+/Sm3+ (CLSO:Dy3+/Sm3+) for white light emission, which was provided with excellent thermal stability and of which luminescence intensity at 150 °C still was 92 percentage of that at room temperature. Moreover, X-ray diffraction technique, Fourier transform infrared spectroscopy, scanning electron microscope were employed to characterization of phase structure and morphology, and consequently pure apatite structure and gravel-like morphology of phosphors were proved. Analysis of photoluminescence spectra indicated that concentration quenching effect exist in single-doped CLSO:Dy3+ phosphors owing to dipole-dipole interaction between Dy3+ ions. It is revealed that maybe exist Dy3+ ↔ Sm3+ bilateral non-radiative energy transfer processes in Dy3+/Sm3+ co-doped CLSO system by PL spectra and decay curves. And variation of Sm3+ ion concentration can control color emission, namely CIE chromaticity coordinates and correlated color temperature, finally to achieve white light emission (0.309,0.309) with CCT 6848 K, able to be a potential candidate for commercial lighting applications.


CrystEngComm ◽  
2015 ◽  
Vol 17 (34) ◽  
pp. 6575-6582 ◽  
Author(s):  
Dou Ma ◽  
Rui Huo ◽  
Xia Li

Lanthanide complexes with a 63 net topology were synthesized. White light emissions were realized by the Sm(iii) complex and Ln(iii)-doped Eu(iii) complexes.


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