Two new isolated Zn-ε-Keggin clusters modified by conjugated organic ligands with decent electrocatalytic and third-order NLO properties

2020 ◽  
Vol 49 (40) ◽  
pp. 14251-14257
Author(s):  
Xiao-Mei Liu ◽  
Fan-Qiong Meng ◽  
Wei-Wei Cheng ◽  
Jia-Peng Cao ◽  
Ji-Lei Wang ◽  
...  
Keyword(s):  
Organic Ligands ◽  
Third Order ◽  
Nlo Properties

Compound 2 is the first isolated Zn5PMo12 cluster, and the two Zn-ε-Keggin-based compounds display excellent electrocatalytic and third-order NLO properties.

Optical, electrochemical and third-order nonlinear optical studies of triphenylamine substituted zinc phthalocyanine

2016 ◽  
Vol 20 (08n11) ◽  
pp. 1173-1181 ◽  
Author(s):  
Narra Vamsi Krishna ◽  
Puliparambil Thilakan Anusha ◽  
S. Venugopal Rao ◽  
L. Giribabu
Keyword(s):  
Nonlinear Optical ◽  
Emission Spectra ◽  
Optical Emission ◽  
Soret Band ◽  
Laser Pulses ◽  
Zinc Phthalocyanine ◽  
Third Order ◽  
Time Resolved ◽  
Nlo Properties ◽  
Scan Data

Zinc phthalocyanine possessing triphenylamine at its peripheral position has been synthesized and its optical, emission, electrochemical and third-order nonlinear optical (NLO) properties were investigated. Soret band was broadened due to the presence of triphenylamine moiety. Electrochemical properties indicated that both oxidation and reduction processes were ring centered. Emission spectra were recorded in different solvents and the fluorescence yields obtained were in the range of 0.02–0.17 while the time-resolved fluorescence data revealed radiative lifetimes of typically few ns. Third-order NLO properties of this molecule have been examined using the Z-scan technique with picosecond (ps) and femtoseocnd (fs) pulses. Closed and open aperture Z-scan data were recorded with 2 ps/1 50 fs laser pulses at a wavelength of 800 nm and NLO coefficients were extracted from both the data. Our data clearly suggests the potential of this molecule for photonics applications.

Correlation between structural studies and third order NLO properties of selected new quinolinium semi-organic compounds

2010 ◽  
Vol 375 (1) ◽  
pp. 1-7 ◽  
Author(s):  
K. Bouchouit ◽  
E.E. Bendeif ◽  
H. EL Ouazzani ◽  
S. Dahaoui ◽  
C. Lecomte ◽  
...  
Keyword(s):  
Organic Compounds ◽  
Structural Studies ◽  
Third Order ◽  
Nlo Properties

Controlling the growth of porphyrin based nanostructures for tuning third-order NLO properties

Nanoscale ◽  
2014 ◽  
Vol 6 (3) ◽  
pp. 1871-1878 ◽  
Author(s):  
Liang Wang ◽  
Yanli Chen ◽  
Jianzhuang Jiang
Keyword(s):  
Third Order ◽  
Nlo Properties

Third-order NLO properties of solution grown methyl-p-hydroxy benzoate single crystals

2014 ◽  
Vol 117 (3) ◽  
pp. 469-473 ◽  
Author(s):  
S. Manikandan ◽  
T. C. Sabari Girisun ◽  
R. Mohandoss ◽  
S. Dhanuskodi ◽  
S. Manivannan
Keyword(s):  
Single Crystals ◽  
Third Order ◽  
Nlo Properties

Third-order NLO properties of metal complexes containing delocalised nitrogen donor ligands

1995 ◽  
Vol 5 (2) ◽  
pp. 261 ◽  
Author(s):  
A. S. Dhindsa ◽  
A. E. Underhill ◽  
S. Oliver ◽  
S. Kershaw
Keyword(s):  
Metal Complexes ◽  
Donor Ligands ◽  
Third Order ◽  
Nitrogen Donor Ligands ◽  
Nlo Properties ◽  
Nitrogen Donor

Synthesis and third-order nonlinear optical properties of novel ethynyl-linked heteropentamer composed of four porphyrins and one pyrene

2009 ◽  
Vol 13 (02) ◽  
pp. 275-282 ◽  
Author(s):  
Ning Sheng ◽  
Jing Sun ◽  
Yongzhong Bian ◽  
Jianzhuang Jiang ◽  
Dong Xu
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Three Dimensional ◽  
Spectroscopic Methods ◽  
Third Order ◽  
Zinc Compounds ◽  
Nlo Properties ◽  
Metal Free ◽  
The Third ◽  
Wide Range

Novel heteropentameric porphyrins-pyrene arrays, in which four meso-tetraphenyl porphyrins are linked to the center unit of pyrene by four acetylenyl bonds, were designed and synthesized. The newly synthesized heteropentameric compounds have been characterized by a wide range of spectroscopic methods. The third-order nonlinear optical (NLO) properties of both the metal-free and zinc compounds of the three-dimensional arrays were investigated by Z-scan experiments, showing enhanced NLO properties compared with that of the porphyrin and pyrene monomers.

Synthesis and Third-order NLO Properties of polymethacrylates containing Pendent Azobenzene Groups

2007 ◽  
Vol 19 (3) ◽  
pp. 356-367 ◽  
Author(s):  
Najun Li ◽  
Jianmei Lu ◽  
Qingfeng Xu ◽  
Xuewei Xia ◽  
Lihua Wang
Keyword(s):  
Third Order ◽  
Nlo Properties ◽  
Azobenzene Groups

Structure–property relation and third-order nonlinear optical studies of two new halogenated chalcones

2017 ◽  
Vol 0 (0) ◽  
Author(s):  
Huey Chong Kwong ◽  
M. S. Rakesh ◽  
C. S. Chidan Kumar ◽  
Shivaraj R. Maidur ◽  
Parutagouda Shankaragouda Patil ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Nonlinear Optical ◽  
Structure Property ◽  
Optical Studies ◽  
Third Order ◽  
Nlo Properties ◽  
Chalcone Derivatives ◽  
Property Relation

AbstractIn the present work, the crystal structure and third-order nonlinear optical (NLO) properties of two novel chalcone derivatives namely (E)-3-(4-bromo-2-fluorophenyl)-1-(3,4-dimethoxyphenyl)prop-2-en-1-one (

Enhancement of third-order nonlinear optical properties of HMTA stabilized pure and doped ZnS nanoparticles and their electronic structures

2018 ◽  
Vol 27 (02) ◽  
pp. 1850016 ◽  
Author(s):  
K. Vijai Anand ◽  
G. Vinitha ◽  
Sanjeev Gautam ◽  
K. H. Chae ◽  
R. Mohan ◽  
...  
Keyword(s):  
Transition Metals ◽  
Electronic Structures ◽  
Nonlinear Optical ◽  
Zns Nanoparticles ◽  
Third Order ◽  
Tetrahedral Symmetry ◽  
Nonlinear Optical Susceptibility ◽  
Nlo Properties ◽  
The Third ◽  
Mn Doped

This study reports the third-order nonlinear optical (NLO) properties of hexamethylenetetramine (HMTA) stabilized pure and transition metals (Cu, Co and Mn) doped ZnS nanoparticles (NPs) and their electronic structures. The third-order NLO properties of pure and transition metals (Cu, Co and Mn) doped ZnS NPs were measured by [Formula: see text]-scan technique. From these measurements, the pure and doped ZnS samples exhibit negative nonlinearity i.e., self-defocusing. The open aperture [Formula: see text]-scan measurement shows saturated absorption within the medium. The prepared pure and doped ZnS samples exhibit nonlinear refractive index of the order of 10[Formula: see text][Formula: see text](cm2/W), nonlinear absorption (NLA) coefficient of the order of 10[Formula: see text][Formula: see text]cm/W and nonlinear optical susceptibility of the order of 10[Formula: see text][Formula: see text]esu. The electronic structures of these ZnS NPs were investigated using near edge X-ray absorption fine structure (NEXAFS) measurements at the C K-, N K- and Co L[Formula: see text]-edges. The C K- and N K-edges XANES spectra reveal the appearance of several spectral features in the range 285–290[Formula: see text]eV and 390–430[Formula: see text]eV respectively. The Co L[Formula: see text]-edge NEXAFS spectrum exhibits multiplet absorption lines similar to those of Co[Formula: see text] ions coordinated in tetrahedral symmetry with four sulfur nearest neighbors. These results clearly demonstrate that divalent Co ions substitute Zn sites. From the Raman spectra, the appearance of multiple resonance Raman peaks indicates that the prepared ZnS samples have good optical quality.

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