Ce-MIL-140: expanding the synthesis routes for cerium(iv) metal–organic frameworks

2020 ◽  
Vol 49 (32) ◽  
pp. 11396-11402 ◽  
Author(s):  
Jannick Jacobsen ◽  
Lasse Wegner ◽  
Helge Reinsch ◽  
Norbert Stock

A solvothermal synthetic route to Ce(iv)-MOFs using acetonitrile as solvent is reported that avoids the formation of the extremely dominant hexanuclear inorganic building unit (IBU) and paves the way for higher IBU diversity in Ce(iv)-MOFs.

2014 ◽  
Vol 5 (1) ◽  
Author(s):  
Dawei Feng ◽  
Kecheng Wang ◽  
Zhangwen Wei ◽  
Ying-Pin Chen ◽  
Cory M. Simon ◽  
...  

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Dawei Feng ◽  
Kecheng Wang ◽  
Zhangwen Wei ◽  
Ying-Pin Chen ◽  
Cory M. Simon ◽  
...  

2017 ◽  
Vol 201 ◽  
pp. 9-45 ◽  
Author(s):  
Bunyarat Rungtaweevoranit ◽  
Christian S. Diercks ◽  
Markus J. Kalmutzki ◽  
Omar M. Yaghi

Reticular chemistry, the linking of molecular building units by strong bonds to make crystalline, extended structures such as metal–organic frameworks (MOFs), zeolitic imidazolate frameworks (ZIFs), and covalent organic frameworks (COFs), is currently one of the most rapidly expanding fields of science. In this contribution, we outline the origins of the field; the key intellectual and practical contributions, which have led to this expansion; and the new directions reticular chemistry is taking that are changing the way we think about making new materials and the manner with which we incorporate chemical information within structures to reach additional levels of functionality. This progress is described in the larger context of chemistry and unexplored, yet important, aspects of this field are presented.


CrystEngComm ◽  
2017 ◽  
Vol 19 (37) ◽  
pp. 5558-5564 ◽  
Author(s):  
Constance R. Pfeiffer ◽  
Naomi Biggins ◽  
William Lewis ◽  
Neil R. Champness

The influence of intermolecular interactions and metal coordination geometry on MOF framework dimensions are discussed.


2019 ◽  
Vol 48 (9) ◽  
pp. 2967-2976 ◽  
Author(s):  
Niels Tannert ◽  
Christian Jansen ◽  
Sandra Nießing ◽  
Christoph Janiak

We confirm that the investigated Al-MOFs are robust with respect to reproducible synthesis and concomitant porosity as a prerequisite for applications.


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