Similarities and differences between Mn(ii) and Zn(ii) coordination polymers supported by porphyrin-based ligands: synthesis, structures and nonlinear optical properties

2020 ◽  
Vol 49 (36) ◽  
pp. 12622-12631
Author(s):  
Bo-Wei Xu ◽  
Ru-Jie Niu ◽  
Quan Liu ◽  
Jun-Yi Yang ◽  
Wen-Hua Zhang ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Coordination Polymers ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Similarities And Differences

Pyridine- and pyridinemethanol-based coordination polymers of Mn(ii) and Zn(ii) with porphyrinic ligand skeleton demonstrate rich similarities and differences in terms of solution and solid-state properties.

Isoreticular Tp*–W–Cu–S cluster-based one-dimensional coordination polymers with an uncommon [Tp*WS3Cu2] + [Cu] combination and their third-order nonlinear optical properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (21) ◽  
pp. 3343-3348 ◽  
Author(s):  
Quan Liu ◽  
Hong-Juan Xu ◽  
Li-Ce Yu ◽  
Ming-Jie Lu ◽  
Yan-Fang Shang ◽  
...  
Keyword(s):  
Optical Properties ◽  
Coordination Polymers ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Third Order ◽  
One Dimensional

Three isoreticular W/Cu/S 1D coordination polymers show good third-order NLO performance.

New Borate Structures for Nlo Applications

1993 ◽  
Vol 329 ◽  
Author(s):  
Douglas A. Keszler ◽  
Annapoorna Akella ◽  
Kathleen I. Schaffers ◽  
Theodore Alekel
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Linear Optical Properties ◽  
Linear And Nonlinear ◽  
Linear Optical ◽  
Optical Applications ◽  
Nonlinear Optical Applications

AbstractBy considering selected examples of new structure types, guidelines are set forth for the synthesis of new solid-state inorganic borates that are likely to have desirable properties for nonlinear optical applications. The structures of two new, noncentrosymmetric orthoborate fluorides BaCaBO3F and Ba7(BO3)3F5 demonstrate a feasibility for controlling linear optical properties and for producing noncentrosymmetric borates that melt congruently. The structure of SrLi(B3O5)3 represents an additional example of a noncentrosymmetric borate resulting from chirality of the B3O7 ring. In addition to potential practical value, crystals of the type AMOB2O5 (A = K, Rb, and Cs; M = Nb and Ta) provide a unique means for examining the structural dependent interrelationships of linear and nonlinear optical properties.

ROOM-TEMPERATURE SOLID-STATE REACTION TO TREE-LIKE FRACTAL NANO-CdS AND THIRD-ORDER NONLINEAR OPTICAL PROPERTIES

NANO ◽  
2013 ◽  
Vol 08 (04) ◽  
pp. 1350035
Author(s):  
TAO-YU ZHOU ◽  
HUI WANG ◽  
XIAO-PING KANG ◽  
XIN-QUAN XIN
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Cadmium Sulfide ◽  
Solid State Reaction ◽  
Nonlinear Optical ◽  
Room Temperature ◽  
Average Diameter ◽  
Nonlinear Optical Properties ◽  
Third Order ◽  
Focusing Effect

A novel tree-like nano-cadmium sulfide (CdS) with the fractal feature is synthesized by solid-state reaction at room temperature from complex precursor with aminotrimethylenephosphonic acid (ATMP) as ligand. The obtained sample is the crystalline cubic beta cadmium sulfide. The tree is composed of nanorods with an average diameter of ca. 95 nm and a length of up to 100–650 nm. The nanorods grow in the asymmetrical "Y" shape. The amount of ATMP plays an important role in the formation of fractal structure. Nonlinear optical (NLO) measurements by the Z-scan technique exhibit that the tree-like fractal nano- CdS has the third-order nonlinear optical properties of both NLO absorption and NLO refraction with self-focusing effect and the optical limiting performance.

Effects of Dendronization on the Linear and Third-Order Nonlinear Optical Properties of Bis(thiopyrylium) Polymethine Dyes in Solution and the Solid State

2012 ◽  
Vol 24 (9) ◽  
pp. 1606-1618 ◽  
Author(s):  
Annabelle Scarpaci ◽  
Arpornrat Nantalaksakul ◽  
Joel M. Hales ◽  
Jonathan D. Matichak ◽  
Stephen Barlow ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Polymethine Dyes ◽  
Third Order
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