A four-parameter system for rationalising the electronic properties of transition metal–radical ligand complexes

2020 ◽  
Vol 49 (28) ◽  
pp. 9735-9742
Author(s):  
N. M. Mews ◽  
M. Reimann ◽  
G. Hörner ◽  
M. Kaupp ◽  
H. Schubert ◽  
...  
Keyword(s):  
Transition Metal ◽  
Electronic Properties ◽  
Transition Metal Compounds ◽  
Parameter System ◽  
Metal Compounds ◽  
Radical Ligand ◽  
Parameter Scheme ◽  
Metal Radical

A heuristic four-parameter scheme captures and predicts the electronic properties of radical-ligand transition metal compounds, overcoming ligand specific descriptions.

scholarly journals Thermoelectricity in transition metal compounds: the role of spin disorder

2016 ◽  
Vol 18 (46) ◽  
pp. 31777-31786 ◽  
Author(s):  
Prashun Gorai ◽  
Eric S. Toberer ◽  
Vladan Stevanović
Keyword(s):  
Low Temperature ◽  
Transition Metal ◽  
Electronic Properties ◽  
Magnetic Materials ◽  
Room Temperature ◽  
Paramagnetic State ◽  
Transition Metal Compounds ◽  
Metal Compounds ◽  
Spin Disorder

At room temperature and above, most magnetic materials adopt a spin-disordered (paramagnetic) state whose electronic properties can differ significantly from their low-temperature, spin-ordered counterparts.

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