Reactions of [(dmpe)2MnH(C2H4)]: synthesis and characterization of manganese(i) borohydride and hydride complexes

2020 ◽  
Vol 49 (29) ◽  
pp. 9983-9994
Author(s):  
Jeffrey S. Price ◽  
Declan M. DeJordy ◽  
David J. H. Emslie ◽  
James F. Britten
Keyword(s):  
Reaction Pathways ◽  
Synthesis And Characterization ◽  
Hydride Complexes

Reactions of trans-[(dmpe)2MnH(C2H4)] with hydroboranes and phosphines afforded manganese(i) borohydride and hydride complexes; reaction pathways, structures and bonding are discussed.

Reaction Pathways to 2-Aminothiophenes and Thiophene-3-carbonitriles

2009 ◽  
Vol 62 (5) ◽  
pp. 402 ◽  
Author(s):  
Luigi Aurelio ◽  
Bernard L. Flynn ◽  
Peter J. Scammells
Keyword(s):  
Comparative Studies ◽  
Reaction Pathway ◽  
Reaction Pathways ◽  
Synthesis And Characterization ◽  
The Past ◽  
Adenosine A1 ◽  
Unexpected Reaction ◽  
Potential Applications ◽  
A1 Receptor

Over the past two decades 2-amino-3-benzoylthiophenes have been found to act as allosteric enhancers of the adenosine A1 receptor (A1AR). As such, compounds of this type have potential applications in the therapy of a variety of disorders by enhancing A1AR activation. Initial studies in this field identified various 2-amino-3-benzoylthiophenes as potential leads and of these PD 81723 1a has become the benchmark for comparative studies due to its favourable ratio of allosteric enhancement to antagonism. Surprisingly the synthesis and characterization of PD 81723 1a has not been previously reported. Herein we report the synthesis and characterization of this important A1AR allosteric enhancer. As part of this study we also found an unexpected reaction pathway to 2-phenylthiophene-3-carbonitriles.

Synthesis and characterization of new pentamethylcyclopentadienyl iridium hydride complexes

2012 ◽  
Vol 715 ◽  
pp. 113-118 ◽  
Author(s):  
María Talavera ◽  
Sandra Bolaño ◽  
Jorge Bravo ◽  
Jesús Castro ◽  
Soledad García-Fontán
Keyword(s):  
Synthesis And Characterization ◽  
Hydride Complexes

Facile synthesis of air-stable heterobimetallic osmium-silver hydride complexes

2021 ◽  
Author(s):  
Haiyu Zhou ◽  
Tongtong Bai ◽  
Yanlin Pan ◽  
Yongliang Wei ◽  
Tongdao Wang
Keyword(s):  
Synthesis And Characterization ◽  
Facile Synthesis ◽  
Hydride Complexes

The synthesis and characterization of air-stable heterobimetallic Os-Ag hydrides were described. All of the new heterobimetallic Os-Ag hydrides are neutral, and the in-situ generated and presynthesized cis-[Os](H)-C≡C-R units in these...

Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes

2019 ◽  
Vol 48 (46) ◽  
pp. 17174-17178 ◽  
Author(s):  
Lucas A. Freeman ◽  
Jacob E. Walley ◽  
Diane A. Dickie ◽  
Robert J. Gilliard
Keyword(s):  
Magnesium Hydride ◽  
Heterocyclic Carbenes ◽  
Synthesis And Characterization ◽  
Hydride Complexes

Herein we report the synthesis and characterization of dinuclear magnesium–hydride complexes coordinated by NHCs, [(IiPrMe2)Mg(μ-H)(N(SiMe3)2)]2and {(IiPrMe2)Mg(μ-H)[((CH2)Me2Si)2N]}2(IiPrMe2= N,N’-diisopropyl-2,3-dimethylimidazol-2-ylidine).

Synthesis and characterization of HY zeolite-supported rhodium carbonyl hydride complexes

2014 ◽  
Vol 311 ◽  
pp. 230-243 ◽  
Author(s):  
Artem D. Vityuk ◽  
Oleg S. Alexeev ◽  
Michael D. Amiridis
Keyword(s):  
Synthesis And Characterization ◽  
Hy Zeolite ◽  
Hydride Complexes
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