Bismuth-rich bismuth oxyiodide microspheres with abundant oxygen vacancies as an efficient photocatalyst for nitrogen fixation

2020 ◽  
Vol 49 (26) ◽  
pp. 9123-9129 ◽  
Author(s):  
Meng Lan ◽  
Nan Zheng ◽  
Xiaoli Dong ◽  
Chenghe Hua ◽  
Hongchao Ma ◽  
...  

A combined bismuth-rich and defect introduction strategy was used to prepare the H-Bi5O7I with abundant oxygen vacancies, which can effectively yield ammonia under visible light without any organic scavengers or noble-metal cocatalysts.

2020 ◽  
Vol 142 (28) ◽  
pp. 12430-12439 ◽  
Author(s):  
Peishen Li ◽  
Ziang Zhou ◽  
Qiang Wang ◽  
Ming Guo ◽  
Shaowei Chen ◽  
...  

Langmuir ◽  
2022 ◽  
Author(s):  
Zhixiong Yang ◽  
Jiquan Wang ◽  
Junting Wang ◽  
Meng Li ◽  
Qiang Cheng ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2206
Author(s):  
Gaoqian Yuan ◽  
Gen Zhang ◽  
Kezhuo Li ◽  
Faliang Li ◽  
Yunbo Cao ◽  
...  

Loading a noble metal on Bi4Ti3O12 could enable the formation of the Schottky barrier at the interface between the former and the latter, which causes electrons to be trapped and inhibits the recombination of photoelectrons and photoholes. In this paper, AgPt/Bi4Ti3O12 composite photocatalysts were prepared using the photoreduction method, and the effects of the type and content of noble metal on the photocatalytic performance of the catalysts were investigated. The photocatalytic degradation of rhodamine B (RhB) showed that the loading of AgPt bimetallic nanoparticles significantly improved the catalytic performance of Bi4Ti3O12. When 0.10 wt% noble metal was loaded, the degradation rate for RhB of Ag0.7Pt0.3/Bi4Ti3O12 was 0.027 min−1, which was respectively about 2, 1.7 and 3.7 times as that of Ag/Bi4Ti3O12, Pt/Bi3Ti4O12 and Bi4Ti3O12. The reasons may be attributed as follows: (i) the utilization of visible light was enhanced due to the surface plasmon resonance effect of Ag and Pt in the visible region; (ii) Ag nanoparticles mainly acted as electron acceptors to restrain the recombination of photogenerated electron-hole pairs under visible light irradiation; and (iii) Pt nanoparticles acted as electron cocatalysts to further suppress the recombination of photogenerated electron-hole pairs. The photocatalytic performance of Ag0.7Pt0.3/Bi4Ti3O12 was superior to that of Ag/Bi4Ti3O12 and Pt/Bi3Ti4O12 owing to the synergistic effect between Ag and Pt nanoparticles.


Author(s):  
Yanwen Wang ◽  
Rong Liang ◽  
Chao Qin ◽  
Lei Ren ◽  
Zhizhen Ye ◽  
...  

Antimony sulfide (Sb2S3) is a light absorbing material with strong visible light response, which is suitable for efficient and low-cost photoelectrodes. Nano-structured films have unique advantages in constructing photoelectrodes due...


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