scholarly journals An 8-hydroxyquinoline–proline hybrid with multidrug resistance reversal activity and the solution chemistry of its half-sandwich organometallic Ru and Rh complexes

2020 ◽  
Vol 49 (23) ◽  
pp. 7977-7992
Author(s):  
János P. Mészáros ◽  
Jelena M. Poljarević ◽  
István Szatmári ◽  
Oszkár Csuvik ◽  
Ferenc Fülöp ◽  
...  

Synthesis and characterization of an 8-hydroxyquinoline–proline hybrid, and its complex formation with half-sandwich organometallic cations: aqueous chemistry, lipophilicity, cellular uptake and anticancer activity.

2020 ◽  
Vol 840 ◽  
pp. 64-70
Author(s):  
Dian Mira Fadela ◽  
Mudasir Mudasir ◽  
Adhitasari Suratman

The research of adsorption of Cu2+ metal ion on dithizone-immobilized natural bentonite (DNB) had been carried out. The experiment was begun by the activation of natural bentonite with HCl 4 M and dithizone-immobilized on activated bentonite surface. This study included synthesis and characterization of dithizone-immobilized bentonite and its application in adsorption of Cu2+ metal ions. The type of interaction occurred in the adsorption was tested by sequential desorption. The result showed that dithizone successfully immobilized on activated natural bentonite (ANB). The optimum conditions for Cu2+ metal ions adsorption using dithizone-immobilized natural bentonite are at pH 5; 0.1 g mass of adsorbent, with interaction time 60 min, and the initial concentration of ion at 80 ppm. Kinetics and adsorption isotherm studies suggest that the capacity, of the dithizone-immobilized natural bentonite in adsorbing Cu2+ metal ion is significantly improved compared to activated natural bentonite. The adsorption of Cu2+ metal ions by activated natural bentonite was through several interactions dominated by electrostatic interaction (82%). Otherwise, the interaction of dithizone-immobilized natural bentonite with Cu2+ metal ions in the sequence were dominated by the mechanism of complex formation of (75%). The result shows that the immobilization of dithizone changes the type of electrostatic interaction into complex formation.


2019 ◽  
Vol 102 ◽  
pp. 536-540 ◽  
Author(s):  
Mariadhas Valan Arasu ◽  
A. Madankumar ◽  
J. Theerthagiri ◽  
Sunitha Salla ◽  
S. Prabu ◽  
...  

2020 ◽  
Vol 50 (11) ◽  
pp. 1724-1735
Author(s):  
Pratik Nariya ◽  
Falguni Shukla ◽  
Hitarthi Vyas ◽  
Ranjitsinh Devkar ◽  
Sonal Thakore

2008 ◽  
Vol 78 (3) ◽  
pp. 231-238 ◽  
Author(s):  
Kamil Kopecky ◽  
Petr Zimcik ◽  
Veronika Novakova ◽  
Miroslav Miletin ◽  
Zbynek Musil ◽  
...  

1998 ◽  
Vol 28 (9) ◽  
pp. 1505-1520 ◽  
Author(s):  
Xiufeng Hou ◽  
Zhen Pang ◽  
Zuen Huang ◽  
Ruifang Cai ◽  
Xigeng Zhou

Sign in / Sign up

Export Citation Format

Share Document