Influence of anion induced geometry change in Zn(ii) on the magnetization relaxation dynamics of Dy(iii) in Zn–Dy–Zn complexes

2020 ◽  
Vol 49 (30) ◽  
pp. 10580-10593
Author(s):  
Pragya Shukla ◽  
Kamal Uddin Ansari ◽  
Chen Gao ◽  
Shefali Vaidya ◽  
Shalini Tripathi ◽  
...  

A series of [Zn2Dy(L1)2(OAc)4](X) where X = (NO3)0.92(Br)0.08 (1), ClO4 (2), Cl (3) and PF6 (4) complexes were synthesized and their dc and ac magnetic data investigated. Experimental results are validated through MOLCAS calculations.

2018 ◽  
Vol 57 (6) ◽  
pp. 3371-3386 ◽  
Author(s):  
Shefali Vaidya ◽  
Pragya Shukla ◽  
Shalini Tripathi ◽  
Eric Rivière ◽  
Talal Mallah ◽  
...  

2021 ◽  
Author(s):  
Maheswaran Shanmugam ◽  
Amaleswari Rasamsetty ◽  
Sakshi Mehta ◽  
Kamal Uddin Ansari ◽  
Pardeep Kumar ◽  
...  

A series of rare six-coordinate dinuclear Ln(III) complexes [Ln2(µ-Cl)2Cl4Li2(L)2(THF)6] were structurally characterized using a bulky amide ligand (L; Ln = Gd(1); Dy(2) and Y(3)). Detailed magnetic studies disclose that a...


2021 ◽  
Vol 3 (3) ◽  
Author(s):  
Fangzhou Wang ◽  
Daniel E. Bürgler ◽  
Roman Adam ◽  
Umut Parlak ◽  
Derang Cao ◽  
...  

2020 ◽  
Vol 56 (87) ◽  
pp. 13397-13400
Author(s):  
Chinmoy Das ◽  
Amaleswari Rasamsetty ◽  
Shalini Tripathi ◽  
Maheswaran Shanmugam

A three-coordinate Co(ii) complex with the molecular formula [Li(DME)3][Co(L)3] (1) was isolated. The influence of the geometry on the SH parameters, and in turn on the magnetization relaxation, is investigated by SQUID and EPR measurements.


Polyhedron ◽  
2022 ◽  
Vol 212 ◽  
pp. 115613
Author(s):  
Kamal Uddin Ansari ◽  
Amaleswari Rasamsetty ◽  
Pardeep Kumar ◽  
Pragya Shukla ◽  
Shalini Tripathi ◽  
...  

2018 ◽  
Vol 57 (15) ◽  
pp. 9002-9011 ◽  
Author(s):  
Chinmoy Das ◽  
Apoorva Upadhyay ◽  
Maheswaran Shanmugam

1988 ◽  
Vol 102 ◽  
pp. 357-360
Author(s):  
J.C. Gauthier ◽  
J.P. Geindre ◽  
P. Monier ◽  
C. Chenais-Popovics ◽  
N. Tragin ◽  
...  

AbstractIn order to achieve a nickel-like X ray laser scheme we need a tool to determine the parameters which characterise the high-Z plasma. The aim of this work is to study gold laser plasmas and to compare experimental results to a collisional-radiative model which describes nickel-like ions. The electronic temperature and density are measured by the emission of an aluminium tracer. They are compared to the predictions of the nickel-like model for pure gold. The results show that the density and temperature can be estimated in a pure gold plasma.


Author(s):  
Y. Harada ◽  
T. Goto ◽  
H. Koike ◽  
T. Someya

Since phase contrasts of STEM images, that is, Fresnel diffraction fringes or lattice images, manifest themselves in field emission scanning microscopy, the mechanism for image formation in the STEM mode has been investigated and compared with that in CTEM mode, resulting in the theory of reciprocity. It reveals that contrast in STEM images exhibits the same properties as contrast in CTEM images. However, it appears that the validity of the reciprocity theory, especially on the details of phase contrast, has not yet been fully proven by the experiments. In this work, we shall investigate the phase contrast images obtained in both the STEM and CTEM modes of a field emission microscope (100kV), and evaluate the validity of the reciprocity theory by comparing the experimental results.


Author(s):  
A. Ourmazd ◽  
G.R. Booker ◽  
C.J. Humphreys

A (111) phosphorus-doped Si specimen, thinned to give a TEM foil of thickness ∼ 150nm, contained a dislocation network lying on the (111) plane. The dislocation lines were along the three <211> directions and their total Burgers vectors,ḇt, were of the type , each dislocation being of edge character. TEM examination under proper weak-beam conditions seemed initially to show the standard contrast behaviour for such dislocations, indicating some dislocation segments were undissociated (contrast A), while other segments were dissociated to give two Shockley partials separated by approximately 6nm (contrast B) . A more detailed examination, however, revealed that some segments exhibited a third and anomalous contrast behaviour (contrast C), interpreted here as being due to a new dissociation not previously reported. Experimental results obtained for a dislocation along [211] with for the six <220> type reflections using (g,5g) weak-beam conditions are summarised in the table below, together with the relevant values.


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