scholarly journals Gd(NO3)(Se2O5)·3H2O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge

2020 ◽  
Vol 49 (10) ◽  
pp. 3253-3259 ◽  
Author(s):  
Chao Wu ◽  
Longhua Li ◽  
Lin Lin ◽  
Zhipeng Huang ◽  
Mark G. Humphrey ◽  
...  
Keyword(s):  
Rare Earth ◽  
Hydrothermal Method ◽  
Rare Earth Metal ◽  
Nonlinear Optical ◽  
Earth Metal ◽  
Metal Nitrate ◽  
Nonlinear Optical Material ◽  
Nonlinear Optical Crystal ◽  
Ultraviolet Cutoff ◽  
Optical Crystal

A rare-earth metal nitrate–selenite nonlinear optical crystal Gd(NO3)(Se2O5)·3H2O with a short ultraviolet cutoff edge was synthesized by a hydrothermal method.

Deep-ultraviolet transparent alkali metal-rare earth metal sulfate NaY(SO4)2.H2O as a nonlinear optical crystal: synthesis and characterization

CrystEngComm ◽  
2021 ◽  
Author(s):  
Chao Wu ◽  
Lin Lin ◽  
Tianhui Wu ◽  
Zhipeng Huang ◽  
Chi Zhang
Keyword(s):  
Rare Earth ◽  
Alkali Metal ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Synthesis And Characterization ◽  
Nonlinear Optical Crystal ◽  
Metal Sulfate ◽  
Deep Ultraviolet ◽  
Crystal Synthesis ◽  
Optical Crystal

A new alkali metal-rare earth metal sulfate with the formula NaY(SO4)2.H2O has been synthesized using a mild hydrothermal method. It crystallizes in the noncentrosymmetric trigonal space group P3121 (No. 152)...

scholarly journals Alkali metal–alkaline earth metal borate crystal LiBa3(OH)(B9O16)[B(OH)4] as a new deep-UV nonlinear optical material

2016 ◽  
Vol 4 (35) ◽  
pp. 8189-8196 ◽  
Author(s):  
Chao Wu ◽  
Junling Song ◽  
Longhua Li ◽  
Mark G. Humphrey ◽  
Chi Zhang
Keyword(s):  
Alkali Metal ◽  
Hydrothermal Method ◽  
Nonlinear Optical ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Nonlinear Optical Material ◽  
Facile Hydrothermal Method ◽  
Deep Uv ◽  
Metal Borate

A new deep-UV nonlinear optical borate, with the formula LiBa3(OH)(B9O16)[B(OH)4] is synthesized using a facile hydrothermal method.

2(C3H7N6)+·2Cl−·H2O: an ultraviolet nonlinear optical crystal with large birefrigence and strong second-harmonic generation

2020 ◽  
Vol 56 (93) ◽  
pp. 14657-14660
Author(s):  
Lehui Liu ◽  
Chun-Li Hu ◽  
Zhiyong Bai ◽  
Feifei Yuan ◽  
Yisheng Huang ◽  
...  
Keyword(s):  
Second Harmonic Generation ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Optical Material ◽  
Nonlinear Optical Material ◽  
Nonlinear Optical Crystal ◽  
Second Harmonic Generation Intensity ◽  
Optical Crystal

An ultraviolet nonlinear optical material benefited from benzene-like planar π-conjugated (C3N6) groups, achieved significant balance between large birefringence (Δn = 0.277 at 546 nm) and strong second-harmonic generation intensity ∼4.3 × KDP.

scholarly journals Синтез и характеризация нового двойного бората рубидия–гольмия Rb3HoB6O12

2019 ◽  
Vol 21 (2) ◽  
pp. 278-286
Author(s):  
Alexey K. Subanakov ◽  
Evgeniy V. Kovtunets ◽  
Sampil Zh. Choydonov ◽  
Sesegma G. Dorzhieva ◽  
Bair G. Bazarov
Keyword(s):  
Rare Earth ◽  
Optical Materials ◽  
Nonlinear Optical ◽  
Luminescent Properties ◽  
Spectroscopic Properties ◽  
Nonlinear Optical Materials ◽  
Nonlinear Optical Crystal ◽  
Nonlinear Optical Crystals ◽  
Optical Crystals ◽  
Optical Crystal

Методом цитратной золь-гель технологии получен новый двойной борат рубидия–гольмия состава Rb3HoB6O12. Соединение кристаллизуется в тригональной сингонии (пр. гр. R32, a = 13.4038(7), с = 30.315(2) Å, V = 4716.76 Å3) и плавится инконгруэнтно при 818 °С. Попытки получить в однофазном состоянии Rb3HoB6O12 методом твердофазных реакций не привели к положительному результату     REFERENCES Wu C., Yang G., Humphrey M.G., Zhang C. Recent advances in ultraviolet and deep-ultraviolet secondorder nonlinear optical crystals // Chem. Rev., 2018, v. 375, pp. 1–30. https://doi.org/10.1016/j.ccr.2018.02.017 Bubnova R., Volkov S., Albert B., Filatov S. Borates – crystal structures of prospective nonlinear optical materials: high anisotropy of the thermal expansion caused by anharmonic atomic vibrations // Crystals, 2017, v. 7, pp.1–32. DOI: 10.3390/cryst7030093 Becker P. Borate materials in nonlinear optics // Mater., 1998, v. 10, pp. 979–992. https://doi.org/10.1002/(SICI)1521-4095(199809)10:13<979::AIDADMA979>3.0.CO;2-N Chen C., Li R. The anionic group theory of the nonlinear optical effect and its applications in the development of new high-quality NLO crystals in the borate series // Rev. Phys. Chem., 1988, v. 8, pp. 65–91. https://doi.org/10.1080/01442358909353223 Chen C., Wu Y., Jiang A., Wu B., You G., Li R., Lin S. New nonlinear-optical crystal: LiB3O5 // Opt. Soc. Am. B: Opt. Phys., 1989, v. 6, pp. 616–621. https://doi.org/10.1364/JOSAB.6.000616 French R. H., Ling J. W., Ohuchi F. S., Chen C. T. Electronic structure of b-BaB2O4 and LiB3O5 nonlinear optical crystals // Rev. B: Condens. Matter, 1991, v. 44, pp. 8496–8502. https://doi.org/10.1103/Phys-RevB.44.8496 Yusuke Mori, Ikio Kuroda, Satoshi Nakajima, Takamoto Sasaki, Sadao Nakai. New nonlinear optical crystal: Cesium lithium borate // Phys. Lett., 1995, v. 67, pp. 1818–1820. https://doi.org/10.1063/1.115413 Haohai Yu, Zhongben Pan, Huaijin Zhang, Jiyang Wang. Recent advances in self-frequency-doubling crystals // Materiomics, 2016, v. 2, pp. 55–65. https://doi.org/10.1016/j.jmat.2015.12.001 Bajor A.L., Kisielewski J., Klos A., Kopzyński K., Lukasiewicz T., Mierczyk J., Mlyńczak J. Assessment of gadolinium calcium oxoborate (GdCOB) for laser applications // Opto-electronics Review, 2011, v. 19, pp. 439–448. https://doi.org/10.2478/s11772-011-0042-2 Dan Zhao, Cong-Kui Nie, Ye Tian, Bao-Zhong Liu, Yun-Chang Fan, Ji Zhao. A new luminescent host material K3GdB6O12: synthesis, crystal structure and luminescent properties activated by Sm3+ // Kristallogr., 2018, v. 233, pp. 411–419. https://doi.org/10.1515/zkri-2017-2101 Dan Zhao, Fa-Xue Ma, Rui-Juan Zhang, Wei Wei, Juan Yang, Ying-Jie Li. A new rare-earth borate K3LuB6O12: crystal and electronic structure, and luminescent properties activated by Eu3+ // Mater Sci: Mater Electron., 2017, pp. 1–9. https://doi.org/10.1007/s10854-016-5501-6 Atuchin V. V., Subanakov A. K., Aleksandrovsky A. S., Bazarov B. G., Bazarova J. G., Dorzhieva S. G., Gavrilova T. A., Krylov A. S., Molokeev M. S., Oreshonkov A. S., Pugachev A. M., Tushinova Yu. L., Yelisseyev A. P. Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12 // Powder Technol., 2017, v. 28, pp. 1309–1315. https://doi.org/10.1016/j.apt.2017.02.019 Atuchin V. V., Subanakov A. K., Aleksandrovsky A. S., Bazarov B. G., Bazarova J. G., Gavrilova T. A., Krylov A. S., Molokeev M. S., Oreshonkov A. S., Stefanovich S. Yu. Structural and spectroscopic properties of new noncentrosymmetric selfactivated borate Rb3EuB6O12 with B5O10 units // Des., 2018, v. 140, pp. 488–494. https://doi.org/10.1016/j.matdes.2017.12.004 Sangen Zhao, Guochun Zhang, Jiyong Yao, Yicheng Wu. K3YB6O12: A new nonlinear optical crystal with a short UV cutoff edge // Res. Bull., 2012, v. 47, pp. 3810–3813. https://doi.org/10.1016/j.materresbull.2012.05.062 Miriding Mutailipu, Zhiqing Xie, Xin Su, Min Zhang, Ying Wang, Zhihua Yang, Muhammad Ramzan Saeed Ashraf Janjua, Shilie Pan. Chemical cosubstitution- oriented design of rare-earth borates as potential ultraviolet nonlinear optical materials // Am. Chem. Soc., 2017, v. 139, pp. 18397–18405. https://doi.org/10.1021/jacs.7b11263 Li Yang, Yingpeng Wan, Honggen Weng, Yanlin Huang, Cuili Chen, Hyo Jin Seo. Luminescence and color center distributions in K3YB6O12 : Ce3+ phosphor // Phys. D: Appl. Phys., 2016, v. 49 (325303), pp. 1–12. https://doi.org/10.1088/0022-3727/49/32/325303

Abnormal bandgap enlargement resulted in a promising mid-infrared nonlinear optical material Rb2CdBrI3 with an ultrahigh laser damage threshold

2020 ◽  
Vol 8 (26) ◽  
pp. 9005-9011 ◽  
Author(s):  
Qi Wu ◽  
Xian Liu ◽  
Yeshuang Du ◽  
Chunlin Teng ◽  
Fei Liang
Keyword(s):  
Nonlinear Optical ◽  
Damage Threshold ◽  
Optical Material ◽  
Laser Damage Threshold ◽  
Laser Damage ◽  
Nonlinear Optical Material ◽  
Nonlinear Optical Crystal ◽  
Mid Infrared ◽  
Optical Crystal

An abnormal bandgap enlargement resulted in the Rb2CdBrI3 material as a good candidate for mid-infrared nonlinear optical crystal materials.

Hierarchized band gap and enhanced optical responses of trivalent rare-earth metal nitrates due to (d–p)π conjugation interactions

2016 ◽  
Vol 4 (26) ◽  
pp. 6295-6301 ◽  
Author(s):  
Bing-Hua Lei ◽  
Qingrong Kong ◽  
Zhihua Yang ◽  
Yun Yang ◽  
Ying Wang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Band Gap ◽  
Rare Earth Metal ◽  
Nonlinear Optical ◽  
Earth Metal ◽  
Optical Responses ◽  
Metal Nitrates ◽  
Trivalent Rare Earth ◽  
Linear And Nonlinear

A hierarchized band gap, as well as enhanced linear and nonlinear optical responses, result from (d–p)π conjugation interactions in trivalent rare-earth metal nitrates.

A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation response

2017 ◽  
Vol 5 (8) ◽  
pp. 2130-2134 ◽  
Author(s):  
Lei Xiao ◽  
Zhenbo Cao ◽  
Jiyong Yao ◽  
Zheshuai Lin ◽  
Zhanggui Hu
Keyword(s):  
Rare Earth ◽  
High Temperature ◽  
Second Harmonic Generation ◽  
Hydrothermal Method ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Optical Material ◽  
Nonlinear Optical Material

A new rare earth ternary iodate, Ce2I6O18, has been synthesized by a high temperature hydrothermal method with homemade alloy reactor equipment.

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