Iridium(iii) complexes with the dithieno[3,2-b:2′,3′-d]phosphole oxide group and their high optical power limiting performances

2020 ◽  
Vol 49 (15) ◽  
pp. 4967-4976 ◽  
Author(s):  
Zhao Liu ◽  
Yanmin Xu ◽  
Ling Yue ◽  
Ming Li ◽  
Xiaolong Yang ◽  
...  

New cyclometalated iridium(iii) complexes with the dithieno[3,2-b:2′,3′-d]phosphole oxide group can show a higher optical power limiting ability than C60 for a 532 nm laser.

1994 ◽  
Vol 374 ◽  
Author(s):  
Chris M. Lawson ◽  
Tianyi Zhai ◽  
David C. Gale ◽  
Gary M. Gray

AbstractNonlinear optical properties of transition metal-phosphine complexes have been measured at 532 nm by degenerate four-wave mixing. Large second-order molecular hyperpolarizabilities, γ, have been found for complexes containing two phosphine ligands. The measured γ values are closely related to the type and coordination geometry of the phosphine ligands, and the γ values vary as the fifth power of the number of substituents with π-electrons structure.


2000 ◽  
Vol 09 (03) ◽  
pp. 289-296 ◽  
Author(s):  
JINGJIN YU ◽  
LIMING WANG ◽  
QING WANG ◽  
MANKIT NG ◽  
LUPING YU

A novel ZnPc monomer as well as PPV-ZnPc conjugated polymers have been synthesized and their optical power limiting (OPL) performances toward picosecond laser pulses at 532 nm have been measured. The comparison with the performance of C 60 under the same condition indicates that two of the compounds synthesized outperformed C 60 at picosecond time scale. It was found that conjugated PPV polymers containing a small amount of ZnPc cannot only preserve, but have also showed improvement over the monomer's OPL properties. It is believed that the backbone modification was responsible for the enhanced OPL performance.


2001 ◽  
Vol 708 ◽  
Author(s):  
B. Sahraoui ◽  
K.J. Pluciński ◽  
I. V. Kityk ◽  
B. Paci ◽  
P. Baldeck ◽  
...  

ABSTRACTMeasurements of the third-order susceptibilities of new dithienylethylenes in solutions using a degenerate four wave mixing technique at λ=532 nm in picosecond regime were made. From these measurements we deduced the second order hyperpolarizabilities. Optical power limiting properties of the mentioned compounds using nanosecond laser pulses in the visible range are evaluated. The dispersion of nonlinear absorption coefficients is obtained. The appropriate quantum chemical calculations are carried out.


2021 ◽  
Vol 13 (14) ◽  
pp. 2769
Author(s):  
Xiaomei Lu ◽  
Yongxiang Hu ◽  
Ali Omar ◽  
Rosemary Baize ◽  
Mark Vaughan ◽  
...  

Recent studies indicate that the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) aboard the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite provides valuable information about ocean phytoplankton distributions. CALIOP’s attenuated backscatter coefficients, measured at 532 nm in receiver channels oriented parallel and perpendicular to the laser’s linear polarization plane, are significantly improved in the Version 4 data product. However, due to non-ideal instrument effects, a small fraction of the backscattered optical power polarized parallel to the receiver polarization reference plane is misdirected into the perpendicular channel, and vice versa. This effect, known as polarization crosstalk, typically causes the measured perpendicular signal to be higher than its true value and the measured parallel signal to be lower than its true value. Therefore, the ocean optical properties derived directly from CALIOP’s measured signals will be biased if the polarization crosstalk effect is not taken into account. This paper presents methods that can be used to estimate the CALIOP crosstalk effects from on-orbit measurements. The global ocean depolarization ratios calculated both before and after removing the crosstalk effects are compared. Using CALIOP crosstalk-corrected signals is highly recommended for all ocean subsurface studies.


2003 ◽  
Vol 196 (1) ◽  
pp. 289-300 ◽  
Author(s):  
Jacky Wing Yip Lam ◽  
Junwu Chen ◽  
Charles Chi Wang Law ◽  
Han Peng ◽  
Zhiliang Xie ◽  
...  

1994 ◽  
Vol 64 (21) ◽  
pp. 2785-2787 ◽  
Author(s):  
J. E. Wray ◽  
K. C. Liu ◽  
C. H. Chen ◽  
W. R. Garrett ◽  
M. G. Payne ◽  
...  

2014 ◽  
Vol 2 (26) ◽  
pp. 5105 ◽  
Author(s):  
Denis Château ◽  
Quentin Bellier ◽  
Frederic Chaput ◽  
Patrick Feneyrou ◽  
Gérard Berginc ◽  
...  

1998 ◽  
Vol 34 (12) ◽  
pp. 2279-2285 ◽  
Author(s):  
G.S. He ◽  
C. Weder ◽  
P. Smith ◽  
P.N. Prasad

2018 ◽  
Vol 27 (10) ◽  
pp. 104209 ◽  
Author(s):  
Ji-Cai Liu ◽  
Fen-Fen Guo ◽  
Ya-Nan Zhao ◽  
Xing-Zhe Li

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