scholarly journals New Insights into the Biphasic “CO-free” Pauson-Khand Cyclisation Reaction through Combined In Situ Spectroscopy and Multiple Linear Regression Modelling

2021 ◽  
Author(s):  
Robert Geitner ◽  
Tianbai Huang ◽  
Stephan Kupfer ◽  
Stefanie Gräfe ◽  
Florian Meirer ◽  
...  
Keyword(s):  
Linear Regression ◽  
Multiple Linear Regression ◽  
Synthesis Gas ◽  
Catalytic Reactions ◽  
In Situ Spectroscopy ◽  
Regression Modelling

“CO-free” carbonylations are catalytic reactions, which strive to replace toxic synthesis gas for less harmful surrogate molecules like formaldehyde. This study sheds light on the mechanism of the biphasic, Rh-catalysed...

The electron-transfer intermediates of the oxygen evolution reaction (OER) as polarons by in situ spectroscopy

2021 ◽  
Author(s):  
Hanna Lyle ◽  
Suryansh Singh ◽  
Michael Paolino ◽  
Ilya Vinogradov ◽  
Tanja Cuk
Keyword(s):  
Electron Transfer ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Catalytic Reactions ◽  
In Situ Spectroscopy ◽  
Chemical Bonds

The conversion of diffusive forms of energy (electrical and light) into short, compact chemical bonds by catalytic reactions regularly involves moving a carrier from an environment that favors delocalization to one that favors localization.

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