Efficient photocatalytic chemoselective and stereoselective C–C bond formation over AuPd@N-rich carbon nitride

2021 ◽  
Author(s):  
Heyan Jiang ◽  
Jie Xu ◽  
Sishi Zhang ◽  
Hongmei Cheng ◽  
Cuicui Zang ◽  
...  
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Carbon Nitride ◽  
Bond Formation ◽  
Reaction Products ◽  
Mild Conditions ◽  
Light Color

High unsymmetrical chemoselective Ullmann biaryl products and satisfactory Z-type stereoselective Heck reaction products could be achieved through changing the visible light color over AuPd@N-Rich carbon nitride under mild conditions.

Palladium chloride catalyzed photochemical Heck reaction

2013 ◽  
Vol 91 (5) ◽  
pp. 348-351 ◽  
Author(s):  
Suresh B. Waghmode ◽  
Sudhir S. Arbuj ◽  
Bina N. Wani ◽  
C.S. Gopinath
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Aryl Halides ◽  
Palladium Chloride ◽  
Carbon Bond ◽  
Excellent Yield ◽  
Carbon Carbon Bond ◽  
Uv Visible

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

scholarly journals Ni/Photoredox Dual Catalysis Sulfone Compounds Synthesised with Carbon Nitride as the Semiheterogeneous Photocatalyst

2021 ◽  
Author(s):  
Yang Liu ◽  
Joost Berkhong
Keyword(s):  
Large Scale ◽  
Carbon Nitride ◽  
Bond Formation ◽  
Reaction System ◽  
Nickel Catalysts ◽  
Practical Application ◽  
Mild Conditions ◽  
Aryl Bromides ◽  
Application Potential ◽  
Electron Donating Groups

An easily available heterogeneous semiconductor material, g-CN, proved to be feasible when combined with homogeneous nickel catalysts for light-mediated C(sp2)-SO2Ar bond formation of aryl bromides with aryl sulfinates under mild conditions and base-free, unlocking a variety of cross-couplings. The metal-free heterogeneous semiconductor is totally recyclable from reaction system, and experimental results demonstrated a series of differently substituted substrates including electron donating groups and electron withdrawing groups can be tolerated with a satisfactory result. The method could even pro-duce the classic drug Dapsone in large scale, showing strong practical application potential.

Synthesis of 2-trifluoromethyl indoles via visible-light induced intramolecular radical cyclization

RSC Advances ◽  
2015 ◽  
Vol 5 (49) ◽  
pp. 39625-39629 ◽  
Author(s):  
Xichang Dong ◽  
Yumin Hu ◽  
Tiebo Xiao ◽  
Lei Zhou
Keyword(s):  
Visible Light ◽  
Formation Process ◽  
Bond Formation ◽  
Radical Cyclization ◽  
Mild Conditions ◽  
Rapid Construction

A visible-light induced intramolecular radical cyclization is described. The reaction allows the rapid construction of 2-trifluoromethyl-3-acylindoles in a sequential C–C and C–O bond formation process under mild conditions.

scholarly journals Carbon nitride creates thioamides in high yields by the photocatalytic Kindler reaction

2018 ◽  
Vol 20 (4) ◽  
pp. 838-842 ◽  
Author(s):  
B. Kurpil ◽  
B. Kumru ◽  
T. Heil ◽  
M. Antonietti ◽  
A. Savateev
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Carbon Nitride ◽  
Elemental Sulfur ◽  
Bond Formation ◽  
Building Blocks ◽  
Light Irradiation ◽  
High Yields

Potassium poly(heptazine imide), a carbon nitride based photocatalyst, effectively promotes the Kindler reaction of thioamide bond formation using amines and elemental sulfur as building blocks under visible light irradiation.

Visible light driven efficient metal free single atom catalyst supported on nanoporous carbon nitride for nitrogen fixation

2019 ◽  
Vol 21 (23) ◽  
pp. 12346-12352 ◽  
Author(s):  
Kalishankar Bhattacharyya ◽  
Ayan Datta
Keyword(s):  
Nitrogen Fixation ◽  
Visible Light ◽  
Carbon Nitride ◽  
Industrial Applications ◽  
Chemical Processes ◽  
Single Atom ◽  
Metal Free ◽  
Mild Conditions ◽  
Visible Light Driven ◽  
Production Of Ammonia

The production of ammonia (NH3), an important carbon-free chemical, through nitrogen (N2) fixation under mild conditions, is one of the most challenging and attractive chemical processes for industrial applications.

Visible Light Photocatalyzed Carbon-Heteroatom Bond Formation and Synthesis of Related Compounds

2017 ◽  
Vol 3 (4) ◽  
pp. 279-317 ◽  
Author(s):  
Nirmalya Mukherjee ◽  
Pintu Maity ◽  
Tubai Ghosh ◽  
Subir Panja ◽  
Brindaban C. Ranu
Keyword(s):  
Visible Light ◽  
Bond Formation ◽  
Related Compounds

scholarly journals Fabrication of AgCl/Ag3PO4/graphitic carbon nitride heterojunctions for enhanced visible light photocatalytic decomposition of methylene blue, methylparaben and E. coli

RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 6383-6394 ◽  
Author(s):  
Haishuai Li ◽  
Linlin Cai ◽  
Xin Wang ◽  
Huixian Shi
Keyword(s):  
Methylene Blue ◽  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Carbon Nitride ◽  
Light Irradiation ◽  
Graphitic Carbon Nitride ◽  
Photocatalytic Decomposition ◽  
E Coli ◽  
Visible Light Photocatalytic

A noval ternary nanocomposite AgCl/Ag3PO4/g-C3N4 was successfully synthesized for photocatalytic degradation of methylene blue, methylparaben and inactivation of E. coli under visible light irradiation, showing excellent photocatalytic degradation performance and stability.

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