Ultradeep hydrodesulfurization of fuel over superior NiMoS phases constructed by a novel Ni(MoS4)2(C13H30N)2 precursor

2020 ◽  
Vol 10 (17) ◽  
pp. 6065-6075
Author(s):  
Jundong Xu ◽  
Chenglong Wen ◽  
Shuisen He ◽  
Yu Fan
Keyword(s):  
Hydrodesulfurization Activity

Ni(MoS4)2(C13H30N)2 was synthesized and adopted for preparing a NiMoS/γ-Al2O3 hydrodesulfurization catalyst, and the as-prepared catalyst exhibits superior 4,6-dimethyldibenzothiophene hydrodesulfurization activity.

The Effect of γ-Al2O3, TiO2 and ZrO2 Supports on Hydrodesulfurization Activity of Transition-Metal Sulfides

2008 ◽  
Vol 73 (8-9) ◽  
pp. 945-955 ◽  
Author(s):  
Luděk Kaluža ◽  
Miroslav Zdražil
Keyword(s):  
Transition Metal ◽  
Aqueous Solutions ◽  
Model Reaction ◽  
Metal Sulfides ◽  
Vacuum Impregnation ◽  
Transition Metal Sulfides ◽  
Highly Active ◽  
System A ◽  
Benzothiophene Hydrodesulfurization ◽  
Hydrodesulfurization Activity

The transition metals V, Cr, Mn, Fe, Co, Ni, Mo, Ru, Rh, Pd, W, Re, Os, Ir and Pt were deposited from aqueous solutions of their salts onto conventional γ-Al2O3 and unconventional TiO2 and ZrO2 supports by vacuum impregnation and characterized in their sulfided form by a model reaction of benzothiophene hydrodesulfurization. It was found that the TiO2 and ZrO2 supports influenced predominantly positively the resulting activity of relatively low-active metals (V, Cr, Mn, Fe, Co, Ni, Mo, Ru, W and Os), whereas the highly active metals (Rh, Pd, Ir, Pt and Re) were influenced slightly negatively or not at all by those supports compared with the γ-Al2O3-supported system. A significant effect of the supports on the hydrodesulfurization-activity ranking of the transition-metal sulfides studied was ascertained.

Hydrodesulfurization activity of NiMo/TiO2Al2O3 catalysts

1998 ◽  
Vol 167 (1) ◽  
pp. 39-48 ◽  
Author(s):  
Z.B. Wei ◽  
Weihong Yan ◽  
Hui Zhang ◽  
Tieli Ren ◽  
Qin Xin ◽  
...  
Keyword(s):  
Hydrodesulfurization Activity

Hydrodesulfurization activity of CoMo and NiMo supported on Al2O3–TiO2 for some model compounds and gas oils

1998 ◽  
Vol 18 (3-4) ◽  
pp. 325-330 ◽  
Author(s):  
Emmanuel Lecrenay ◽  
Kinya Sakanishi ◽  
Tomoshige Nagamatsu ◽  
Isao Mochida ◽  
Teruo Suzuka
Keyword(s):  
Model Compounds ◽  
Hydrodesulfurization Activity

Preparation of Highly Active Noble Metal Phosphide Catalysts: Effect of Precursors on the Formation of the Active Phase and Hydrodesulfurization Activity

2013 ◽  
Vol 42 (4) ◽  
pp. 404-406 ◽  
Author(s):  
Yasuharu Kanda ◽  
Takuma Ichiki ◽  
Shohei Kayaoka ◽  
Ayaka Sawada ◽  
Masatoshi Sugioka ◽  
...  
Keyword(s):  
Noble Metal ◽  
Active Phase ◽  
Metal Phosphide ◽  
Highly Active ◽  
Hydrodesulfurization Activity
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