Boron-doped graphene as electrocatalytic support for iridium oxide for oxygen evolution reaction

2020 ◽  
Vol 10 (19) ◽  
pp. 6599-6610 ◽  
Author(s):  
Prerna Joshi ◽  
Hsin-Hui Huang ◽  
Rohit Yadav ◽  
Masanori Hara ◽  
Masamichi Yoshimura
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Iridium Oxide ◽  
Boron Doped ◽  
Reduced Graphene ◽  
Doped Graphene ◽  
Electrochemical Water Splitting

The present work details the development of IrO2 nanoparticles (nps) supported on B-doped reduced graphene oxide as an oxygen evolution reaction (OER) electrocatalyst for electrochemical water splitting.

Co–Fe Bimetal Phosphate Composite Loaded on Reduced Graphene Oxide for Oxygen Evolution

NANO ◽  
2019 ◽  
Vol 14 (01) ◽  
pp. 1950003 ◽  
Author(s):  
Guoxing Zhu ◽  
Xulan Xie ◽  
Lisong Xiao ◽  
Xiaoyun Li ◽  
Xiaoping Shen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Synergistic Effects ◽  
Water Electrolysis ◽  
Onset Potential ◽  
Reduced Graphene

Development of high-performance nonprecious metal-based catalysts for oxygen evolution reaction (OER) is crucial to improve the efficiency of water electrolysis and photoelectrochemical water splitting for harvesting and storage of solar energy. Herein, Co–Fe phosphates and their composites with reduced graphene oxide (rGO) were prepared by a simple hydrothermal method, which then acted as oxygen evolution reaction catalysts. In 1.0 M KOH aqueous solution, the as-obtained optimal composite, Co–Fe phosphate/rGO, can catalyze oxygen evolution reaction with a very sharp onset potential and a small over-potential of 338[Formula: see text]mV to achieve a current density of 10[Formula: see text]mA[Formula: see text]cm[Formula: see text]. It was found that in these Co–Fe phosphates, the optimal Co:Fe ratio is 0.75:0.25. The excellent electrocatalytic performance of the Co–Fe phosphate/rGO composite would benefit from the synergistic effects between Fe and Co species, as well as rGO substrate providing conductive channels. The formed Co–Fe phosphate/rGO electrocatalysts can be the promising replacement of precious metal-based catalysts for more practical and cost-efficient water splitting.

Nano-spinel Cobalt decorated sulphur doped graphene: An efficient and durable electrocatalyst for Oxygen Evolution Reaction and Non- Enzymatic sensing of H2O2

2021 ◽  
Author(s):  
Adil Amin Wani ◽  
Murtaza Manzoor Bhat ◽  
Feroz Ahmad Sofi ◽  
Sajad Ahmad Bhat ◽  
Pravin Ingole ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Electrochemical Stability ◽  
Electrocatalytic Performance ◽  
Reduced Graphene ◽  
Doped Graphene

We report the synthesis of a nano-spinel cobalt decorated sulphur doped reduced Graphene oxide (Co@S-rGO) composite exhibiting excellent electrocatalytic performance and electrochemical stability toward oxygen evolution reaction (OER) in alkaline...

A novel strategy to boost the oxygen evolution reaction activity of NiFe-LDHs with in situ synthesized 3D porous reduced graphene oxide matrix as both the substrate and electronic carrier

2019 ◽  
Vol 43 (17) ◽  
pp. 6555-6562 ◽  
Author(s):  
Yanfang Gu ◽  
Yuanqiang Wang ◽  
Wei An ◽  
Yong Men ◽  
Yichuan Rui ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Stable Operating ◽  
Reduced Graphene ◽  
Oxide Matrix ◽  
Novel Strategy ◽  
Operating Potential

NiFe-LDHs anchored on a 3D rGO matrix achieved a small overpotential and a relatively stable operating potential.

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