Homogeneous vs. heterogeneous: mechanistic insights into iron group metal-catalyzed reductions from poisoning experiments

2020 ◽  
Vol 10 (11) ◽  
pp. 3502-3514 ◽  
Author(s):  
Dominik Gärtner ◽  
Sebastian Sandl ◽  
Axel Jacobi von Wangelin
Keyword(s):  
Noble Metal ◽  
Metal Catalysts ◽  
Iron Group ◽  
Promising Alternative ◽  
Reduction Reactions ◽  
Noble Metal Catalysts ◽  
Group Metal ◽  
Iron Group Metal ◽  
Metal Catalyzed

Iron group catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. This review advocates the use of kinetic poisoning experiments to distinguish between homotopic and heterotopic mechanisms.

CC Hydrogenations with Iron Group Metal Catalysts

2018 ◽  
pp. 97-126
Author(s):  
Tim N. Gieshoff ◽  
Axel Jacobi von Wangelin
Keyword(s):  
Metal Catalysts ◽  
Iron Group ◽  
Group Metal ◽  
Iron Group Metal

HCN formation from CCI2F2 (CFC12) over iron group metal catalysts

1992 ◽  
Vol 136 (2) ◽  
pp. 617-620 ◽  
Author(s):  
Y TAKITA ◽  
T IMAMURA ◽  
Y MIZUHARA ◽  
T ISHIHARA
Keyword(s):  
Metal Catalysts ◽  
Iron Group ◽  
Group Metal ◽  
Iron Group Metal

Growth of single-layer carbon tubes assisted with iron-group metal catalysts in carbon arc

1997 ◽  
Vol 40 (1-4) ◽  
pp. 421-424 ◽  
Author(s):  
Yahachi Saito ◽  
Tadao Koyama ◽  
Kenichiro Kawabata
Keyword(s):  
Single Layer ◽  
Metal Catalysts ◽  
Iron Group ◽  
Group Metal ◽  
Iron Group Metal ◽  
Carbon Arc

Electrodeposition of Strained-Layer Superlattices

1996 ◽  
Vol 451 ◽  
Author(s):  
T. P. Moffat
Keyword(s):  
Charge Transfer ◽  
Mass Transport ◽  
Structural Evolution ◽  
Iron Group ◽  
Morphological Instability ◽  
Group Metal ◽  
Iron Group Metal ◽  
Transport Control ◽  
Strained Layer Superlattices ◽  
Interfacial Charge

ABSTRACTA variety of Cu/(Ni, Co) multilayers have been grown on Cu single crystals by pulse plating from an alloy electroplating bath. Copper is deposited under mass transport control while the iron group metal is deposited under interfacial charge transfer control. The structural evolution of these films is influenced by the morphological instability of the mass transport limited copper deposition reaction and the development of growth twins during iron-group metal deposition. Specular films have been obtained for growth on Cu(100) while rough, defective films were typically obtained for growth on Cu(111) and Cu(110).

Styrene-divinylbenzene polymer oxidation catalyst

1981 ◽  
Vol 46 (11) ◽  
pp. 2657-2662
Author(s):  
Zdeněk Prokop ◽  
Karel Setínek
Keyword(s):  
Functional Groups ◽  
Noble Metal ◽  
Additional Data ◽  
Catalytic Properties ◽  
Metal Catalysts ◽  
Oxidation Catalyst ◽  
Noble Metal Catalysts ◽  
Polymer Catalyst ◽  
Styrene Divinylbenzene ◽  
Polymer Oxidation

Some additional data about properties and applicability of a styrene-divinylbenzene polymer catalyst containing acidic and redox functional groups are reported. It is shown that the catalysts of this type can be prepared reproducibly and exhibit catalytic properties comparable to the properties of noble metal catalysts.

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