Two-way desorption coupling to enhance the conversion of syngas into aromatics by MnO/H-ZSM-5

2020 ◽  
Vol 10 (10) ◽  
pp. 3366-3375
Author(s):  
Syed Zulfiqar Ali Gilani ◽  
Le Lu ◽  
Muhammad Tahir Arslan ◽  
Babar Ali ◽  
Qi Wang ◽  
...  

We herein report a composite catalyst containing partially reducible and highly active manganese oxide and nano-size H-ZSM-5 with short b-axis, prepared for the direct conversion of syngas into aromatics.

2016 ◽  
Vol 4 (2) ◽  
pp. 620-631 ◽  
Author(s):  
Islam M. Mosa ◽  
Sourav Biswas ◽  
Abdelhamid M. El-Sawy ◽  
Venkatesh Botu ◽  
Curtis Guild ◽  
...  

Understanding the origin of manganese oxide activity for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is a key step towards rationally designing of highly active catalysts capable of competing with the widely used, state-of-art noble metal catalysts.


2006 ◽  
Vol 6 (2) ◽  
pp. 58 ◽  
Author(s):  
Didi Dwi Anggoro ◽  
Nor Aishah Saidina Amin

The direct conversion of natural gas-in particular, its principal component, methane into useful products has been the subject of intense study over the past decades. However, commercialization of this process is still not viable because its conversion and selectivity potentials remain low. Thus, the search continues to come up with a suitable catalyst that allows methane to be oxidized in a controlled environment to yield a high percentage of higher hydrocarbons. ZSM-5 zeolite has been known to be a suitable catalyst for olefin oligomerization. Previous studies, however, have indicated that ZSM-5 zeolites are not resistant to high temperatures. In this work, ZSM-5 was modified with copper and tungsten to develop a highly active and heat-resistant bifunctional oxidative acid catalyst. The oxidation of methane was performed over W/Cu/HZSM-5 catalyst and the results compared with the catalytic performance of W/ HZSM-5 and HZSM-5 catalysts. The metal oxide on the catalyst surface led to enhanced conversion of Hz and CO to CZ-3 ydrocarbons and, hence, reduced HzO selectivity. Inh the liquid hydrocarbons, Cs+ selectivity increased with increasing amount of surface Bn1Jnstedacid sites. The experimental results indicated higher methane conversion and liquid hydrocarbon selectivity than that of W/3.0Cu/HZSM-5 catalyst.


2011 ◽  
Vol 54 (13-15) ◽  
pp. 768-777 ◽  
Author(s):  
Johan P. den Breejen ◽  
Anne M. Frey ◽  
Jia Yang ◽  
Anders Holmen ◽  
Matti M. van Schooneveld ◽  
...  

2016 ◽  
Vol 4 (17) ◽  
pp. 6585-6594 ◽  
Author(s):  
Feng Rong ◽  
Jiao Zhao ◽  
Zheng Chen ◽  
Yuxing Xu ◽  
Yaopeng Zhao ◽  
...  

Nanostructured biomimetic birnessite CaxMnOy oxides with an intermediate Mn oxidation state and proper structural distortion show improved catalytic activity for the WOR.


2020 ◽  
Vol 27 (12) ◽  
pp. 13488-13500 ◽  
Author(s):  
Yibo Gao ◽  
Zhongpeng Wang ◽  
Chenchen Cui ◽  
Baoqin Wang ◽  
Wenxu Liu ◽  
...  

Author(s):  
Fanhui Meng ◽  
Xiaojing Li ◽  
Peng Zhang ◽  
Langlang Yang ◽  
Guinan Yang ◽  
...  

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