A dinuclear iron complex as an efficient electrocatalyst for homogeneous water oxidation reaction

2020 ◽  
Vol 10 (9) ◽  
pp. 2830-2837
Author(s):  
Suhana Karim ◽  
Aratrika Chakraborty ◽  
Debabrata Samanta ◽  
Ennio Zangrando ◽  
Totan Ghosh ◽  
...  
Keyword(s):  
Schiff Base ◽  
Renewable Energy ◽  
Water Splitting ◽  
Schiff Base Ligand ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Real Life ◽  
Iron Complex ◽  
Dinuclear Iron

A novel dinuclear iron complex of a Schiff base ligand has been exploited as a homogeneous water splitting electrocatalyst having possible real life application in renewable energy.

CoOx/UiO-66 and NiO/UiO-66 Heterostructures with UiO-66 Frameworks for Enhanced Oxygen Evolution Reactions

2021 ◽  
Author(s):  
Guangjin Zhang ◽  
Victor Charles ◽  
Yong Yang ◽  
Menglei Yuan ◽  
Jitao Zhang ◽  
...  
Keyword(s):  
Water Splitting ◽  
Oxygen Evolution ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Widespread Application ◽  
Coupled Process

Water oxidation reaction involves a four electron-proton coupled process that is kinetically sluggish and has hindered the widespread application of water-splitting technology. Metal-MOF-coupled heterostructures serve as good OER electrocatalysts due...

Fe and Cu dual-doped Ni3S4 nanoarray with less low-valence Ni species for boosting water oxidation reaction

2022 ◽  
Author(s):  
Xiaoqiang Du ◽  
Jiaxin Li ◽  
Xiaoshuang Zhang
Keyword(s):  
Transition Metal ◽  
Water Splitting ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
High Efficiency ◽  
Ni Foam ◽  
Metal Materials ◽  
Ni Species ◽  
Co Doped

Transition metal materials with high efficiency and durable electrocatalytic water splitting activity have aroused widespread concern among scientists. In this work, two cation co-doped Ni3S4 nanoarrays grown on Ni foam...

scholarly journals Mediator-assisted water oxidation by the ruthenium “blue dimer” cis,cis-[(bpy)2(H2O)RuORu(OH2)(bpy)2]4+

2008 ◽  
Vol 105 (46) ◽  
pp. 17632-17635 ◽  
Author(s):  
Javier J. Concepcion ◽  
Jonah W. Jurss ◽  
Joseph L. Templeton ◽  
Thomas J. Meyer
Keyword(s):  
Carbon Dioxide ◽  
Electron Transfer ◽  
Renewable Energy ◽  
Photosystem Ii ◽  
Water Splitting ◽  
Water Oxidation ◽  
Oxygenic Photosynthesis ◽  
Reduced Water ◽  
Insight Into ◽  
Recent Insight

Light-driven water oxidation occurs in oxygenic photosynthesis in photosystem II and provides redox equivalents directed to photosystem I, in which carbon dioxide is reduced. Water oxidation is also essential in artificial photosynthesis and solar fuel-forming reactions, such as water splitting into hydrogen and oxygen (2 H2O + 4 hν → O2 + 2 H2) or water reduction of CO2 to methanol (2 H2O + CO2 + 6 hν → CH3OH + 3/2 O2), or hydrocarbons, which could provide clean, renewable energy. The “blue ruthenium dimer,” cis,cis-[(bpy)2(H2O)RuIIIORuIII(OH2)(bpy)2]4+, was the first well characterized molecule to catalyze water oxidation. On the basis of recent insight into the mechanism, we have devised a strategy for enhancing catalytic rates by using kinetically facile electron-transfer mediators. Rate enhancements by factors of up to ≈30 have been obtained, and preliminary electrochemical experiments have demonstrated that mediator-assisted electrocatalytic water oxidation is also attainable.

Defect management and efficient photocatalytic water oxidation reaction over Mg modified SrNbO2N

2018 ◽  
Vol 6 (23) ◽  
pp. 10947-10957 ◽  
Author(s):  
Xiaoqin Sun ◽  
Gang Liu ◽  
Xiaoxiang Xu
Keyword(s):  
Photocatalytic Activity ◽  
Band Gap ◽  
Water Splitting ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Defect Management ◽  
Solar Water ◽  
Solar Water Splitting

Although SrNbO2N has a promising band gap of ∼1.8 eV for solar water splitting, its photocatalytic activity is generally very poor under ordinary conditions, we have managed to improve this by Mg modifications.

scholarly journals Water oxidation catalyzed by molecular di- and nonanuclear Fe complexes: importance of a proper ligand framework

2016 ◽  
Vol 45 (34) ◽  
pp. 13289-13293 ◽  
Author(s):  
Biswanath Das ◽  
Bao-Lin Lee ◽  
Erik A. Karlsson ◽  
Torbjörn Åkermark ◽  
Andrey Shatskiy ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Iron Complexes ◽  
Iron Complex ◽  
Oxidation Catalysts ◽  
Dinuclear Iron ◽  
Fe Complexes

The synthesis of two molecular iron complexes, a dinuclear iron(iii,iii) complex and a nonanuclear iron complex, and their use as water oxidation catalysts is described.

Nitric oxide (NO) reactivity studies on mononuclear iron(ii) complexes supported by a tetradentate Schiff base ligand

RSC Advances ◽  
2016 ◽  
Vol 6 (116) ◽  
pp. 115326-115333 ◽  
Author(s):  
Nidhi Tyagi ◽  
Ovender Singh ◽  
Udai P. Singh ◽  
Kaushik Ghosh
Keyword(s):  
Nitric Oxide ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Iron Complex ◽  
Mononuclear Iron ◽  
Tetradentate Schiff Base ◽  
Tetradentate Ligands ◽  
Vis Spectroscopy

Mononuclear iron(ii) complexes were synthesised and characterized from tetradentate ligands. The reactivity of NO afforded ligand nitrated iron(ii) complex along with the in situ formation of an unstable nitrosylated iron complex which was monitored by UV-vis spectroscopy.

Electrodeposited-film electrodes derived from a precursor dinitrosyl iron complex for electrocatalytic water splitting

2018 ◽  
Vol 47 (21) ◽  
pp. 7128-7134 ◽  
Author(s):  
Wei-Liang Li ◽  
Tzung-Wen Chiou ◽  
Chien-Hong Chen ◽  
Yi-Ju Yu ◽  
Li-Kang Chu ◽  
...  
Keyword(s):  
Renewable Energy ◽  
Water Splitting ◽  
Artificial Photosynthesis ◽  
Renewable Energy Sources ◽  
Iron Complex ◽  
Energy Sources ◽  
Dinitrosyl Iron Complex ◽  
Electrodeposited Film ◽  
Dinitrosyl Iron ◽  
And Storage

In artificial photosynthesis, water splitting plays an important role for the conversion and storage of renewable energy sources.

scholarly journals Quasi-1D hyperbranched WO3 nanostructures for low-voltage photoelectrochemical water splitting

2015 ◽  
Vol 3 (11) ◽  
pp. 6110-6117 ◽  
Author(s):  
Mehrdad Balandeh ◽  
Alessandro Mezzetti ◽  
Alessandra Tacca ◽  
Silvia Leonardi ◽  
Gianluigi Marra ◽  
...  
Keyword(s):  
Gas Phase ◽  
Water Splitting ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Low Voltage ◽  
Photoelectrochemical Water Splitting ◽  
Self Assembled ◽  
Wo3 Nanostructures

Arrays of hyperbranched mesostructures self-assembled from the gas phase display a decreased overpotential for the water oxidation reaction.

A dinuclear iron complex as a precatalyst for water oxidation under alkaline conditions

2021 ◽  
Author(s):  
Amirreza Valizadeh ◽  
Rahman Bikas ◽  
Pavlo Aleshkevych ◽  
Anna Kozakiewicz ◽  
Suleyman I. Allakhverdiev ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Iron Complex ◽  
Dinuclear Iron ◽  
Alkaline Conditions
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