scholarly journals Advances in applied supramolecular technologies

2021 ◽  
Author(s):  
George T. Williams ◽  
Cally J. E. Haynes ◽  
Mohamed Fares ◽  
Claudia Caltagirone ◽  
Jennifer R. Hiscock ◽  
...  
Keyword(s):  
Supramolecular Chemistry ◽  
Fundamental Understanding

Supramolecular chemistry has successfully built a foundation of fundamental understanding. However, with this now achieved, we show how this area of chemistry is moving out of the laboratory towards successful commercialisation.

Gaseous Cyclodextrin-closo-Dodecaborate Complexes ΧCD·[B12X12]2- (Χ = α, β, γ; X = F, Cl, Br, I): Electronic Structures and Intramolecular Interactions

2021 ◽  
Author(s):  
Yanrong Jiang ◽  
Qinqin Yuan ◽  
Wenjin Cao ◽  
Markus Rohdenburg ◽  
Marc C. Nierstenhöfer ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Supramolecular Chemistry ◽  
Inclusion Complexes ◽  
Electronic Structures ◽  
Systematic Investigation ◽  
Intramolecular Interactions ◽  
Fundamental Understanding

A fundamental understanding of cyclodextrin-closo-dodecaborate inclusion complexes has become of great interest in supramolecular chemistry. Herein, we report a systematic investigation on the electronic structure and intramolecular interactions of perhalogenated...

Strain analysis in composite ceramics

1986 ◽  
Vol 44 ◽  
pp. 494-497
Author(s):  
W. M. Kriven
Keyword(s):  
Strain Field ◽  
Strain Analysis ◽  
Processing Temperature ◽  
Transformation Toughening ◽  
Zirconia Ceramics ◽  
Volume Increase ◽  
Analysis Technique ◽  
Fundamental Understanding ◽  
Contrast Analysis ◽  
Elastic Strain Field

Significant progress towards a fundamental understanding of transformation toughening in composite zirconia ceramics was made possible by the application of a TEM contrast analysis technique for imaging elastic strains. Spherical zirconia particles dispersed in a large-grained alumina matrix were examined by 1 MeV HVEM to simulate bulk conditions. A thermal contraction mismatch arose on cooling from the processing temperature of 1500°C to RT. Tetragonal ZrO2 contracted amisotropically with α(ct) = 16 X 10-6/°C and α(at) = 11 X 10-6/°C and faster than Al2O3 which contracted relatively isotropically at α = 8 X 10-6/°C. A volume increase of +4.9% accompanied the transformation to monoclinic symmetry at room temperature. The elastic strain field surrounding a particle before transformation was 3-dimensionally correlated with the internal crystallographic orientation of the particle and with the strain field after transformation. The aim of this paper is to theoretically and experimentally describe this technique using the ZrO2 as an example and thereby to illustrate the experimental requirements Tor such an analysis in other systems.

Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries

2020 ◽  
Vol 13 (5) ◽  
pp. 1429-1461 ◽  
Author(s):  
Xiaona Li ◽  
Jianwen Liang ◽  
Xiaofei Yang ◽  
Keegan R. Adair ◽  
Changhong Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Lithium Batteries ◽  
Electrochemical Stability ◽  
Superionic Conductors ◽  
Fundamental Understanding ◽  
Potential Applications ◽  
Synthesis Routes

This review focuses on fundamental understanding, various synthesis routes, chemical/electrochemical stability of halide-based lithium superionic conductors, and their potential applications in energy storage as well as related challenges.

Predictive tool for frictional performance of piston ring-pack/liner conjunction

2019 ◽  
Vol 13 (3) ◽  
pp. 5513-5527
Author(s):  
J. W. Tee ◽  
S. H. Hamdan ◽  
W. W. F. Chong
Keyword(s):  
Film Thickness ◽  
Mathematical Models ◽  
Piston Ring ◽  
Published Data ◽  
Predictive Tool ◽  
Frictional Losses ◽  
Fundamental Understanding ◽  
Minimum Film Thickness ◽  
Piston Ring Pack ◽  
Ring Pack

Fundamental understanding of piston ring-pack lubrication is essential in reducing engine friction. This is because a substantial portion of engine frictional losses come from piston-ring assembly. Hence, this study investigates the tribological impact of different piston ring profiles towards engine in-cylinder friction. Mathematical models are derived from Reynolds equation by using Reynolds’ boundary conditions to generate the contact pressure distribution along the complete piston ring-pack/liner conjunction. The predicted minimum film thickness is then used to predict the friction generated between the piston ring-pack and the engine cylinder liner. The engine in-cylinder friction is predicted using Greenwood and Williamson’s rough surface contact model. The model considers both the boundary friction and the viscous friction components. These mathematical models are integrated to simulate the total engine in-cylinder friction originating from the studied piston ring-pack for a complete engine cycle. The predicted minimum film thickness and frictional properties from the current models are shown to correlate reasonably with the published data. Hence, the proposed mathematical approach prepares a simplistic platform in predicting frictional losses of piston ring-pack/liner conjunction, allowing for an improved fundamental understanding of the parasitic losses in an internal combustion engine.

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