Thermodynamic and kinetic hydricity of transition metal hydrides

2020 ◽  
Vol 49 (22) ◽  
pp. 7929-7948 ◽  
Author(s):  
Kelsey R. Brereton ◽  
Nicholas E. Smith ◽  
Nilay Hazari ◽  
Alexander J. M. Miller
Keyword(s):  
Transition Metal ◽  
Case Studies ◽  
Metal Hydrides ◽  
Transition Metal Hydrides

This review of thermodynamic and kinetic hydricity provides conceptual overviews, tutorials on how to determine hydricity both experimentally and computationally, and salient case studies.

scholarly journals Complex transition metal hydrides: linear correlation of countercation electronegativity versus T–D bond lengths

2015 ◽  
Vol 51 (56) ◽  
pp. 11248-11251 ◽  
Author(s):  
T. D. Humphries ◽  
D. A. Sheppard ◽  
C. E. Buckley
Keyword(s):  
Transition Metal ◽  
Bond Length ◽  
Linear Correlation ◽  
Metal Hydrides ◽  
Bond Lengths ◽  
Transition Metal Hydrides ◽  
Complex Hydrides

For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T–deuterium bond length and the average electronegativity of the metal countercations.

Kinetic hydricity of transition-metal hydrides toward trityl cation

1995 ◽  
Vol 14 (9) ◽  
pp. 4031-4033 ◽  
Author(s):  
Tan-Yun Cheng ◽  
R. Morris Bullock
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Trityl Cation

Positive ions of the first‐ and second‐row transition metal hydrides

1987 ◽  
Vol 87 (1) ◽  
pp. 481-492 ◽  
Author(s):  
Lars G. M. Pettersson ◽  
Charles W. Bauschlicher ◽  
Stephen R. Langhoff ◽  
Harry Partridge
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Positive Ions

The Formation and Properties of Rare-Earth and Transition Metal Hydrides

1975 ◽  
pp. 659-674 ◽  
Author(s):  
L. C. Beavis ◽  
R. S. Blewer ◽  
J. W. Guthrie ◽  
E. J. Nowak ◽  
W. G. Perkins
Keyword(s):  
Rare Earth ◽  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides

Addition of acrylonitrile to anionic transition metal hydrides. An ionic model for homogeneous olefin processes

1989 ◽  
Vol 30 (14) ◽  
pp. 1781-1784 ◽  
Author(s):  
Marcetta Y. Darensbourg ◽  
Barbara Floris ◽  
Kay A. Youngdahl
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Ionic Model ◽  
Transition Metal Hydrides

scholarly journals Hydricity of Transition-Metal Hydrides: Thermodynamic Considerations for CO2 Reduction

ACS Catalysis ◽  
2018 ◽  
Vol 8 (2) ◽  
pp. 1313-1324 ◽  
Author(s):  
Kate M. Waldie ◽  
Andrew L. Ostericher ◽  
Mark H. Reineke ◽  
Alissa F. Sasayama ◽  
Clifford P. Kubiak
Keyword(s):  
Transition Metal ◽  
Co2 Reduction ◽  
Metal Hydrides ◽  
Transition Metal Hydrides
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