Nucleophilic degradation of diazinon in thermoreversible polymer–polymer aqueous biphasic systems

2021 ◽  
Vol 23 (7) ◽  
pp. 4133-4140
Author(s):  
Daniela Millan ◽  
Mafalda R. Almeida ◽  
Ana F. C. S. Rufino ◽  
João A. P. Coutinho ◽  
Mara G. Freire

Polymer–polymer aqueous two-phase systems involve thermoreversible reaction–separation processes in the nucleophilic degradation of diazinon and further separation of the reaction products.

2015 ◽  
Vol 17 (5) ◽  
pp. 3026-3034 ◽  
Author(s):  
Ranyere L. Souza ◽  
Sónia P. M. Ventura ◽  
Cleide M. F. Soares ◽  
João A. P. Coutinho ◽  
Álvaro S. Lima

Ionic liquids as adjuvant in aqueous two-phase systems (ATPS) are efficient, environmentally friendly, and “biocompatible” separation processes, which allow the high purification of enzymes.


2019 ◽  
Vol 43 (1) ◽  
pp. 348-359 ◽  
Author(s):  
Rong‐tao Zhao ◽  
Dong Pei ◽  
Pei‐liang Yu ◽  
Jan‐teng Wei ◽  
Ning‐li Wang ◽  
...  

2010 ◽  
Vol 29 (11) ◽  
pp. 1336-1346 ◽  
Author(s):  
Zhiyong Li ◽  
Yuanchao Pei ◽  
Huiyong Wang ◽  
Jing Fan ◽  
Jianji Wang

Molecules ◽  
2021 ◽  
Vol 26 (21) ◽  
pp. 6612
Author(s):  
Sandra C. Bernardo ◽  
Emanuel V. Capela ◽  
Jorge F. B. Pereira ◽  
Sónia P. M. Ventura ◽  
Mara G. Freire ◽  
...  

Cholinium-based ionic liquids ([Ch]-based ILs) were investigated as electrolytes in the formation of aqueous biphasic systems (ABS) composed of polyethylene glycol (PEG) and sodium polyacrylate (NaPA) polymers. Both enhancement and decrease in the liquid-liquid demixing ability induced by electrolytes in PEG-NaPA aqueous biphasic systems were observed. It is shown that the ILs that most extensively partition to the PEG-rich phase tend to act as inorganic salts enhancing the two-phase formation ability, while those that display a more significant partition to the NaPA-rich phase decrease the ABS formation capacity. The gathered results allowed us to confirm the tailoring ability of ILs and to identify, for the first time, opposite effects induced by electrolytes on the PEG-NaPA ABS formation ability. The distribution of the electrolyte ions between the coexisting phases and the polyelectrolyte ion compartmentalization are key factors behind the formation of PEG-NaPA-based ABS.


2004 ◽  
Vol 47 (5) ◽  
pp. 685-691 ◽  
Author(s):  
Leonie Asfora Sarubbo ◽  
Luciana Alves de Oliveira ◽  
Ana Lúcia Figueiredo Porto ◽  
Galba Maria de Campos-Takaki ◽  
Elias Basile Tambourgi

The partitioning of two proteins, bovine serum albumin (BSA) and trypsin was studied in an aqueous poly(ethylene glycol)(PEG)- Cashew-nut tree gum system. The phase diagram was provided for Cashew-nut tree gum and PEG molecular weight of 1500 at two different temperatures. The influence of several parameters including concentrations of polymers, pH, salt addition and temperature on the partitioning of these proteins were investigated.. The results of this research demonstrated the importance of the protein characteristics for partitioning in aqueous biphasic system.


2013 ◽  
Vol 8 (3) ◽  
pp. 352-362 ◽  
Author(s):  
Paula A. J. Rosa ◽  
Ana M. Azevedo ◽  
S. Sommerfeld ◽  
Martina Mutter ◽  
Werner Bäcker ◽  
...  

2021 ◽  
Vol 60 (15) ◽  
pp. 5403-5410
Author(s):  
Martha Alicia González-Félix ◽  
Luis Alberto Mejía-Manzano ◽  
Bertha A. Barba-Dávila ◽  
Sergio O. Serna-Saldívar ◽  
José González-Valdez

2021 ◽  
Vol 778 ◽  
pp. 146293
Author(s):  
Thivaharan Varadavenkatesan ◽  
Shraddha Pai ◽  
Ramesh Vinayagam ◽  
Arivalagan Pugazhendhi ◽  
Raja Selvaraj

Small ◽  
2012 ◽  
Vol 8 (15) ◽  
pp. 2356-2360 ◽  
Author(s):  
Shaohua Ma ◽  
Julian Thiele ◽  
Xin Liu ◽  
Yunpeng Bai ◽  
Chris Abell ◽  
...  

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