UV-photoelectron spectroscopy of stable radicals: the electronic structure of planar Blatter radicals as materials for organic electronics

2020 ◽  
Vol 22 (41) ◽  
pp. 23637-23644 ◽  
Author(s):  
Aniket A. Hande ◽  
Clovis Darrigan ◽  
Paulina Bartos ◽  
Patrick Baylère ◽  
Anna Pietrzak ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Gas Phase ◽  
Organic Electronics ◽  
Photoelectron Spectroscopy ◽  
Stable Radicals ◽  
Uv Photoelectron Spectroscopy

The electronic structure of a series of C(10)-substituted planar Blatter radical derivatives containing H, F, Cl, Br, CN, CF3 and OMe groups was investigated by gas phase UV-PES and results were correlated with solution electrochemical data.

Recent Studies on Flash Vacuum Thermolysis in Tandem with UV-Photoelectron Spectroscopy and Quantum Calculations

2014 ◽  
Vol 67 (9) ◽  
pp. 1166 ◽  
Author(s):  
Anna Chrostowska ◽  
Stanisław Leśniak
Keyword(s):  
Experimental Data ◽  
Electronic Structure ◽  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Quantum Calculations ◽  
Fundamental Information ◽  
Spectroscopic Characterisation ◽  
Uv Photoelectron Spectroscopy ◽  
Unambiguous Interpretation

Flash vacuum thermolysis (FVT) is a particular method that allows the synthesis of stable compounds or the generation of short-lived species. Its coupling with spectroscopic characterisation provides very useful tools for mechanistic investigations. One of the most efficient and especially well suited techniques for this purpose is ultraviolet–photoelectron spectroscopy (UV-PES), which in tandem with FVT provides the ionisation energies of in situ formed molecules in the gas phase. The experimental data thus obtained in real-time are supported by quantum chemical calculations for consistency of the assignments of PES spectra and constitute fundamental information about electronic structure and bonding. The FVT/UV-PES technique has been known for more than 40 years, but one advantage in the present age is the greater confidence in electronic structure computations for predicting ionisation energies, thus providing the necessary tool for unambiguous interpretation of experimental data. This mini-review aims to give some representative, original examples, chosen from a French–Polish collaboration that illustrates the efficiency and wide applicability of the FVT/UV-PES tandem methodology. The selected examples on the FVT of thione and imine derivatives will be presented.

Electronic Structure of Stable Radicals of the Heavy Group 14 Elements: UV-Photoelectron Spectroscopy Characterization

2008 ◽  
Vol 27 (13) ◽  
pp. 2915-2917 ◽  
Author(s):  
Anna Chrostowska ◽  
Alain Dargelos ◽  
Alain Graciaa ◽  
Patrick Baylère ◽  
Vladimir Ya. Lee ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Photoelectron Spectroscopy ◽  
Group 14 ◽  
Group 14 Elements ◽  
Stable Radicals ◽  
Uv Photoelectron Spectroscopy ◽  
Heavy Group

scholarly journals Unravelling the electronic structure and dynamics of an isolated molecular rotary motor in the gas-phase

2017 ◽  
Vol 8 (9) ◽  
pp. 6141-6148 ◽  
Author(s):  
Reece Beekmeyer ◽  
Michael A. Parkes ◽  
Luke Ridgwell ◽  
Jamie W. Riley ◽  
Jiawen Chen ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Quantum Chemistry ◽  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Structure And Dynamics ◽  
Quantum Chemistry Calculations ◽  
Anion Photoelectron Spectroscopy ◽  
Rotary Motor

Anion photoelectron spectroscopy and quantum chemistry calculations are employed to probe the electronic structure and dynamics of a unidirectional molecular rotary motor anion in the gas-phase.

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