Excited-state intramolecular proton transfer in the kinetic-control regime

2020 ◽  
Vol 22 (39) ◽  
pp. 22271-22278
Author(s):  
Zong-Ying Liu ◽  
Jiun-Wei Hu ◽  
Teng-Hsing Huang ◽  
Kew-Yu Chen ◽  
Pi-Tai Chou
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Intramolecular Proton Transfer ◽  
Kinetic Control ◽  
Amino Group ◽  
Reaction Barriers ◽  
Control Regime

A new series of ESIPT molecules has been investigated. We found that these compounds undergo kinetic-control ESIPT and the reaction barriers along proton transfer coordinate can be finetuned by different substitution on amino group.

Excited state intramolecular proton transfer in amino 2-(2′-hydroxyphenyl)benzazole derivatives: Effects of the solvent and the amino group position

2007 ◽  
Vol 126 (2) ◽  
pp. 728-734 ◽  
Author(s):  
Fabiano Severo Rodembusch ◽  
Fernando Paulus Leusin ◽  
Leandra Franciscato Campo ◽  
Valter Stefani
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Intramolecular Proton Transfer ◽  
Amino Group ◽  
Group Position

Effect of amino group on the excited-state intramolecular proton transfer (ESIPT) mechanisms of 2-(2′-hydroxyphenyl)benzoxazole and its amino derivatives

RSC Advances ◽  
2016 ◽  
Vol 6 (6) ◽  
pp. 5134-5140 ◽  
Author(s):  
Chaozheng Li ◽  
Yonggang Yang ◽  
Chi Ma ◽  
Yufang Liu
Keyword(s):  
Excited State ◽  
Hydrogen Bonds ◽  
Proton Transfer ◽  
Intramolecular Proton Transfer ◽  
Amino Group ◽  
Electronic Density ◽  
Intramolecular Hydrogen Bonds ◽  
Amino Derivatives ◽  
Intramolecular Hydrogen

The electronic density redistributes and it migrates in opposite directions for HBO when compared to those of 5A-HBO and 6A-HBO. The amino group in the HBO framework can change the behavior of the intramolecular hydrogen bonds.

scholarly journals An enhanced sampling QM/AMOEBA approach: The case of the excited state intramolecular proton transfer in solvated 3-hydroxyflavone

2021 ◽  
Vol 154 (18) ◽  
pp. 184107
Author(s):  
Michele Nottoli ◽  
Mattia Bondanza ◽  
Filippo Lipparini ◽  
Benedetta Mennucci
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Intramolecular Proton Transfer ◽  
Enhanced Sampling

scholarly journals The development of aryl-substituted 2-phenylimidazo[1,2-a]pyridines (PIP) with various colors of excited-state intramolecular proton transfer (ESIPT) luminescence in the solid state

2016 ◽  
Vol 4 (16) ◽  
pp. 3599-3606 ◽  
Author(s):  
Toshiki Mutai ◽  
Tatsuya Ohkawa ◽  
Hideaki Shono ◽  
Koji Araki
Keyword(s):  
Excited State ◽  
Solid State ◽  
Proton Transfer ◽  
Intramolecular Proton Transfer ◽  
Aryl Group ◽  
Red Emission ◽  
Wide Range

The color of ESIPT luminescence of HPIP is tuned in a wide range by the introduction of aryl group(s), and thus a series of PIPs showing blue to red emission is realized.

ChemInform Abstract: EXCITED-STATE INTRAMOLECULAR PROTON TRANSFER AND VIBRATIONAL RELAXATION IN 2-(2-HYDROXYPHENYL)BENZOTHIAZOLE

1983 ◽  
Vol 14 (28) ◽  
Author(s):  
K. DING ◽  
S. J. COURTNEY ◽  
A. J. G. STRANDJORD ◽  
S. FLOM ◽  
D. M. FRIEDRICH ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Vibrational Relaxation ◽  
Intramolecular Proton Transfer

Reaction-based sensing of fluoride ions using desilylation method for triggering excited-state intramolecular proton transfer

2016 ◽  
Vol 28 (7-8) ◽  
pp. 693-706 ◽  
Author(s):  
Ajit Kumar Mahapatra ◽  
Sanchita Mondal ◽  
Saikat Kumar Manna ◽  
Kalipada Maiti ◽  
Rajkishor Maji ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Intramolecular Proton Transfer ◽  
Fluoride Ions
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