Crystal structure and migration paths of alkaline ions in NaVPO4F

2020 ◽  
Vol 22 (28) ◽  
pp. 15876-15884
Author(s):  
D. O. Semykina ◽  
I. V. Yakovlev ◽  
O. B. Lapina ◽  
A. A. Kabanov ◽  
N. V. Kosova

A sample with a nominal composition ‘NaVPO4F’ is prepared by mechanochemically assisted solid-state synthesis using quenching.

1996 ◽  
Vol 21 (5) ◽  
pp. 398-400 ◽  
Author(s):  
Genta Sakane ◽  
Takashi Shibahara ◽  
Hongwei Hou ◽  
Yu Liu ◽  
Xinquan Xin

2001 ◽  
Vol 56 (2) ◽  
pp. 209-212 ◽  
Author(s):  
Anja-Verena Mudring ◽  
Martin Jansen

Abstract The solid state synthesis and the crystal structure of Cs6Cl4O(Pearson-code hR22, R3c, a = 1324.7(6), c = 1658(1) pm, Z = 6, 931 reflections with Io > 2σ(I), R1 = 0.040, wR2 = 0.114) are reported. The compound crystallises isotypically with Rb6Cl4O in the anti-K4CdCl6 type of structure. The structure consists of infinite chains of alternating face-sharing OCs6 octahedra and ClCs6 trigonal prisms which are separated by chloride anions. The underlying structural concept and the analogy to perovskites are outlined.


2009 ◽  
Vol 2009 (9) ◽  
pp. 547-548 ◽  
Author(s):  
Han-Mao Kuang ◽  
Wen-Tong Chen ◽  
Hua-Long Chen ◽  
Shao-Ming Ying

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