Synthesis and photophysics of gold(i) alkynyls bearing a benzothiazole-2,7-fluorenyl moiety: a comparative study analyzing influence of ancillary ligand, bridging moiety, and number of metal centers on photophysical properties

2020 ◽  
Vol 22 (21) ◽  
pp. 11915-11927
Author(s):  
Joseph J. Mihaly ◽  
Alexis T. Phillips ◽  
David J. Stewart ◽  
Zachary M. Marsh ◽  
Christopher L. McCleese ◽  
...  
Keyword(s):  
Comparative Study ◽  
Photophysical Properties ◽  
Ancillary Ligand ◽  
Metal Centers ◽  
Aryl Complexes

Three new gold(i) alkynyl complexes containing a benzothiazole fluorenyl ligand were prepared. Their photophysical properties are compared with previously published dinuclear and mononuclear gold(i) aryl complexes with the same chromophoric ligand.

A comparative study on the photophysical properties of anthocyanins and pyranoanthocyanins

2021 ◽  
Author(s):  
Kim Phan ◽  
Steven De Meester ◽  
Katleen Raes ◽  
Karen De Clerck ◽  
Veronique Van Speybroeck
Keyword(s):  
Comparative Study ◽  
Photophysical Properties

A unified understanding of the direct coordination of NO to first-transition-row metal centers in metal–ligand complexes

2017 ◽  
Vol 19 (41) ◽  
pp. 28098-28104 ◽  
Author(s):  
Hyunjoo Lee ◽  
Joongoo Kang
Keyword(s):  
Comparative Study ◽  
First Principles ◽  
Metal Centers ◽  
Chemical Trends ◽  
Binding Mechanisms ◽  
Metal Ligand

Our first-principles comparative study provides insights into understanding the binding mechanisms of NO to metal–ligand complexes and related chemical trends.

Effect of fluorine substitution of the β-ketoiminate ancillary ligand on photophysical properties and electroluminescence ability of new iridium(iii) complexes

2018 ◽  
Vol 6 (32) ◽  
pp. 8688-8708 ◽  
Author(s):  
Ewelina Witkowska ◽  
Gabriela Wiosna-Salyga ◽  
Ireneusz Glowacki ◽  
Bartosz Orwat ◽  
Myong-joon Oh ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Photophysical Properties ◽  
Ancillary Ligand ◽  
Fluorine Substitution

The influence and emissive properties of N,O-donating ligands with fluorinatedN-aryl moieties on the electronic structure of complexes of the formula [Ir(bzq)2(O∧N)] are reported.

Efficient red emission from poly(vinyl butyral) films doped with a novel europium complex based on a terpyridyl ancillary ligand: synthesis, structural elucidation by Sparkle/RM1 calculation, and photophysical properties

2016 ◽  
Vol 7 (5) ◽  
pp. 1147-1157 ◽  
Author(s):  
Chaolong Yang ◽  
Shaojun Liu ◽  
Jing Xu ◽  
Youbing Li ◽  
Mingyong Shang ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Europium Complex ◽  
Structural Elucidation ◽  
Ancillary Ligand ◽  
Red Emission ◽  
Ligand Synthesis ◽  
Complex Polymer ◽  
Vinyl Butyral

The first example of doped Eu-complex/polymer fluorescent films based on a PVB matrix is reported.

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