Hydrate formation and its effects on the thermal expansion properties of HfMgW3O12

2020 ◽  
Vol 22 (22) ◽  
pp. 12605-12612 ◽  
Author(s):  
Gaojie Zeng ◽  
Huanli Yuan ◽  
Juan Guo ◽  
Qiang Sun ◽  
Qilong Gao ◽  
...  

The thermal expansion curve of HfMgW3O12 correlated with hydration/dehydration accompanying structure and Raman spectral changes.

2012 ◽  
Vol 468-471 ◽  
pp. 1022-1025
Author(s):  
Yuan Li

Thermal expansion behavior of ceramic green bodies could be used to determine appropriate sintering procedure for ceramic materials. In this paper, green bodies containing alumina and calcium hydroxide was prepared by slip casting and their thermal expansion behavior was measured. Thermal expansion curve indicated that calcium aluminate (CaO•Al2O3, CA) and calcium dialuminate (CaO•2Al2O3, CA2) are yielded by reaction sintering as intermediate phase compounds in green samples at temperature about 1160°C and 1240°C-1410°C, respectively; and calcium hexaluminate (CaO•6Al2O3, CA6) is yielded as target product at 1450°C-1560°C. Controlled sintering procedure was determined according to thermal expansion curve of green samples. Analysis result to properties of sintered samples indicated that thermal expansion behavior revealed to be a very simple and powerful tool to determine reaction sintering procedure of calcium hexaluminate ceramics.


2005 ◽  
Vol 412 (4-6) ◽  
pp. 395-398 ◽  
Author(s):  
Satoshi Sakamoto ◽  
Masanori Okumura ◽  
Zinggang Zhao ◽  
Yukio Furukawa

2015 ◽  
Vol 81 ◽  
pp. 83-89 ◽  
Author(s):  
Shufang Hu ◽  
Yanyan Feng ◽  
Daosen Zhang ◽  
Xiaoxu Lu ◽  
Jindong Tian ◽  
...  

X-ray measurements recently carried out by the author on the lattice expansion of silver and quartz showed that the coefficients of thermal expansion, over the ranges investigated, are the same as those observed for the specimen as a whole using optical methods. Goetz and Hergenrother, on the other hand, from X-ray measurements on the coefficients of thermal expansion of single crystals of bismuth, claimed to have found a large difference between values obtained by the two methods of measurement. A possible explanatiion of this that their accuracy is not sufficient to establish definitely the deviation of the X-ray measurements from the optical expansion curve. The author has since made X-ray measurements on the expansion of the bismuth lattice from room temperature to just below the melting point, and finds no evidence of such a discrepancy as Goetz and Hergenrother record.


2000 ◽  
Vol 320 (3-4) ◽  
pp. 323-327 ◽  
Author(s):  
Hideyuki Nakayama ◽  
Ken-ichi Saitow ◽  
Maki Sakashita ◽  
Kikujiro Ishii ◽  
Keiko Nishikawa

2011 ◽  
Vol 31 (1) ◽  
pp. 53-57 ◽  
Author(s):  
Yusuke Imai ◽  
Takahiro Takekiyo ◽  
Hiroshi Abe ◽  
Yukihiro Yoshimura

2002 ◽  
Vol 56 (7) ◽  
pp. 909-915 ◽  
Author(s):  
Wei-Te Chen ◽  
Graham A. Bowmaker ◽  
John M. Seakins ◽  
Ralph P. Cooney

Far-infrared, mid-infrared, and Raman spectroscopy were used to characterize iodine-doped poly(isothianaphthene) (PITN) films and powders. The far-infrared and mid-infrared results show changes from absorption mode to reflective mode as the doping level increases, consistent with the iodine-doped PITN becoming more metallic and more conductive at higher doping levels. The far-IR and Raman (514.5-nm laser excitation) results show that I3− is dominant in iodine-doped PITN. The Raman spectral changes observed using 1064-nm excitation are different from those measured using 514.5-nm excitation. The spectra recorded with 514.5-nm excitation show features due to the undoped parts of the polymer, and these indicate that the effective conjugated chain length decreases with increased doping. The Raman spectra obtained by using 1064-nm excitation show features due to polaron and bipolaron states in the doped polymer.


1990 ◽  
Vol 5 (6) ◽  
pp. 1246-1252 ◽  
Author(s):  
J. C. Parker ◽  
R. W. Siegel

A Raman microprobe study of as-compacted nanophase TiO2 was carried out to investigate the spatial inhomogeneity of its anatase and rutile phases. Also, changes in the observed Raman spectra (line shifts and broadening) were investigated as a function of annealing at temperatures up to 600°C in argon or air. Microscopic phase inhomogeneity is observed and Raman spectral changes are shown to result from inhomogeneous oxygen deficiency in the nanophase TiO2. The line positions corresponding to the Raman active Eg modes in both anatase and rutile are found to be sensitive to this oxygen deficiency and are potential quantitative indicators of such deviations from stoichiometry.


2000 ◽  
Vol 49 (9Appendix) ◽  
pp. 227-228
Author(s):  
Shigeru YAMAUCHI ◽  
Yoshinari KIKUCHI ◽  
Yasuji KURIMOTO

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