Energetics and structures of the tilted phases of fatty acid Langmuir monolayers

2020 ◽  
Vol 22 (21) ◽  
pp. 12092-12103
Author(s):  
Óscar Toledano ◽  
Miguel A. Rubio ◽  
Óscar Gálvez

Langmuir monolayers are monomolecular deep films composed of amphiphilic molecules which are typically confined to a water/air interface in a bi-dimensional structure.

2019 ◽  
Vol 21 (21) ◽  
pp. 11203-11213 ◽  
Author(s):  
Óscar Toledano ◽  
Óscar Gálvez

Langmuir monolayers are monomolecular wide films composed of amphiphilic molecules with a bi-dimensional structure typically formed at the air–water interface.


Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4445
Author(s):  
Tiphaine Wong ◽  
Lorette Brault ◽  
Eric Gasparotto ◽  
Romuald Vallée ◽  
Pierre-Yves Morvan ◽  
...  

Marine polysaccharides are part of the huge seaweeds resources and present many applications for several industries. In order to widen their potential as additives or bioactive compounds, some structural modifications have been studied. Among them, simple hydrophobization reactions have been developed in order to yield to grafted polysaccharides bearing acyl-, aryl-, alkyl-, and alkenyl-groups or fatty acid chains. The resulting polymers are able to present modified physicochemical and/or biological properties of interest in the current pharmaceutical, cosmetics, or food fields. This review covers the chemical structures of the main marine polysaccharides, and then focuses on their structural modifications, and especially on hydrophobization reactions mainly esterification, acylation, alkylation, amidation, or even cross-linking reaction on native hydroxyl-, amine, or carboxylic acid functions. Finally, the question of the necessary requirement for more sustainable processes around these structural modulations of marine polysaccharides is addressed, considering the development of greener technologies applied to traditional polysaccharides.


Langmuir ◽  
1996 ◽  
Vol 12 (20) ◽  
pp. 4966-4968 ◽  
Author(s):  
Jan Czapkiewicz ◽  
Patrycja Dynarowicz ◽  
Piotr Milart

1991 ◽  
Vol 199 (2) ◽  
pp. 271-276 ◽  
Author(s):  
Anke MULLER-FAHRNOW ◽  
Ursula EGNER ◽  
T. Alwyn JONES ◽  
Heinz RUDEL ◽  
Friedrich SPENER ◽  
...  

1997 ◽  
Vol 106 (5) ◽  
pp. 1913-1920 ◽  
Author(s):  
Ellis Teer ◽  
Charles M. Knobler ◽  
Carsten Lautz ◽  
Stefan Wurlitzer ◽  
John Kildae ◽  
...  

Langmuir ◽  
1999 ◽  
Vol 15 (5) ◽  
pp. 1784-1790 ◽  
Author(s):  
V. B. Fainerman ◽  
D. Vollhardt

2003 ◽  
Vol 107 (36) ◽  
pp. 9780-9788 ◽  
Author(s):  
Maxim I. Boyanov ◽  
Jan Kmetko ◽  
Tomohiro Shibata ◽  
Alokmay Datta ◽  
Pulak Dutta ◽  
...  

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