scholarly journals CH2OO Criegee intermediate UV absorption cross-sections and kinetics of CH2OO + CH2OO and CH2OO + I as a function of pressure

2020 ◽  
Vol 22 (17) ◽  
pp. 9448-9459 ◽  
Author(s):  
Zara S. Mir ◽  
Thomas R. Lewis ◽  
Lavinia Onel ◽  
Mark A. Blitz ◽  
Paul W. Seakins ◽  
...  
Keyword(s):  
Cross Sections ◽  
Uv Absorption ◽  
Absorption Cross ◽  
Kinetics Of

The UV absorption cross-sections of the Criegee intermediate CH2OO, and kinetics of the CH2OO self-reaction and the reaction of CH2OO with I are reported as a function of pressure at 298 K.

Kinetics of the gas phase reaction OH + NO(+M)→HONO(+M) and the determination of the UV absorption cross sections of HONO

1997 ◽  
Vol 272 (5-6) ◽  
pp. 383-390 ◽  
Author(s):  
Palle Pagsberg ◽  
Erling Bjergbakke ◽  
Emil Ratajczak ◽  
Alfred Sillesen
Keyword(s):  
Gas Phase ◽  
Cross Sections ◽  
Uv Absorption ◽  
Phase Reaction ◽  
Absorption Cross ◽  
Gas Phase Reaction ◽  
Kinetics Of

Gas-phase UV absorption cross-sections and photolysis kinetics of 4-hydroxy-3-hexanone: Atmospheric implications

2017 ◽  
Vol 688 ◽  
pp. 43-46 ◽  
Author(s):  
L. Aslan ◽  
H. Laversin ◽  
E. Roth ◽  
P. Coddeville ◽  
C. Fittschen ◽  
...  
Keyword(s):  
Gas Phase ◽  
Cross Sections ◽  
Uv Absorption ◽  
Absorption Cross ◽  
Kinetics Of

scholarly journals Ultraviolet Absorption Cross-Sections of Ammonia at Elevated Temperatures for Nonintrusive Quantitative Detection in Combustion Environments

2021 ◽  
pp. 000370282199044
Author(s):  
Wubin Weng ◽  
Shen Li ◽  
Marcus Aldén ◽  
Zhongshan Li
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Absorption Cross Section ◽  
Elevated Temperatures ◽  
Uv Absorption ◽  
Energy Utilization ◽  
Quantitative Detection ◽  
Absorption Cross ◽  
Hot Gas

Ammonia (NH3) is regarded as an important nitrogen oxides (NOx) precursor and also as an effective reductant for NOx removal in energy utilization through combustion, and it has recently become an attractive non-carbon alternative fuel. To have a better understanding of thermochemical properties of NH3, accurate in situ detection of NH3 in high temperature environments is desirable. Ultraviolet (UV) absorption spectroscopy is a feasible technique. To achieve quantitative measurements, spectrally resolved UV absorption cross-sections of NH3 in hot gas environments at different temperatures from 295 K to 590 K were experimentally measured for the first time. Based on the experimental results, vibrational constants of NH3 were determined and used for the calculation of the absorption cross-section of NH3 at high temperatures above 590 K using the PGOPHER software. The investigated UV spectra covered the range of wavelengths from 190 nm to 230 nm, where spectral structures of the [Formula: see text] transition of NH3 in the umbrella bending mode, v2, were recognized. The absorption cross-section was found to decrease at higher temperatures. For example, the absorption cross-section peak of the (6, 0) vibrational band of NH3 decreases from ∼2 × 10−17 to ∼0.5 × 10−17 cm2/molecule with the increase of temperature from 295 K to 1570 K. Using the obtained absorption cross-section, in situ nonintrusive quantification of NH3 in different hot gas environments was achieved with a detection limit varying from below 10 parts per million (ppm) to around 200 ppm as temperature increased from 295 K to 1570 K. The quantitative measurement was applied to an experimental investigation of NH3 combustion process. The concentrations of NH3 and nitric oxide (NO) in the post flame zone of NH3–methane (CH4)–air premixed flames at different equivalence ratios were measured.

UV absorption cross sections of nitrous acid

2000 ◽  
Vol 34 (1) ◽  
pp. 13-19 ◽  
Author(s):  
A.S. Brust ◽  
K.H. Becker ◽  
J. Kleffmann ◽  
P. Wiesen
Keyword(s):  
Cross Sections ◽  
Nitrous Acid ◽  
Uv Absorption ◽  
Absorption Cross

scholarly journals Absorption cross sections and kinetics of formation of AlO at 298 K

2017 ◽  
Vol 675 ◽  
pp. 56-62 ◽  
Author(s):  
Juan Carlos Gómez Martín ◽  
Shane M. Daly ◽  
James S.A. Brooke ◽  
John M.C. Plane
Keyword(s):  
Cross Sections ◽  
Absorption Cross ◽  
Kinetics Of Formation ◽  
Kinetics Of

UV absorption spectrum and absorption cross sections of COF2at 296 K in the range 200 - 230 nm

1992 ◽  
Vol 19 (3) ◽  
pp. 281-284 ◽  
Author(s):  
Andreas Nölle ◽  
Horst Heydtmann ◽  
Richard Meller ◽  
Wolfgang Schneider ◽  
Geert K. Moortgat
Keyword(s):  
Absorption Spectrum ◽  
Cross Sections ◽  
Uv Absorption ◽  
Absorption Cross ◽  
Uv Absorption Spectrum

Atmospheric Photolysis of Methyl Ethyl, Diethyl, and Propyl Ethyl Ketones: Temperature‐Dependent UV Absorption Cross Sections

2019 ◽  
Author(s):  
Jared F. Brewer ◽  
Dimitrios K. Papanastasiou ◽  
James B. Burkholder ◽  
Emily V. Fischer ◽  
Yangang Ren ◽  
...  
Keyword(s):  
Cross Sections ◽  
Uv Absorption ◽  
Absorption Cross ◽  
Methyl Ethyl ◽  
Temperature Dependent

Atmospheric Degradation of 2-Butanol, 2-Methyl-2-butanol, and 2,3-Dimethyl-2-butanol:  OH Kinetics and UV Absorption Cross Sections

2005 ◽  
Vol 109 (48) ◽  
pp. 10903-10909 ◽  
Author(s):  
Elena Jiménez ◽  
Beatriz Lanza ◽  
Andrés Garzón ◽  
Bernabé Ballesteros ◽  
José Albaladejo
Keyword(s):  
Cross Sections ◽  
Uv Absorption ◽  
Absorption Cross ◽  
Atmospheric Degradation
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