Adsorption and oxidation of SO2 on the surface of TiO2 nanoparticles: the role of terminal hydroxyl and oxygen vacancy–Ti3+ states

2020 ◽  
Vol 22 (18) ◽  
pp. 9943-9953
Author(s):  
Bing Wang ◽  
Xue Li ◽  
Shanshan Liang ◽  
Runxuan Chu ◽  
Dan Zhang ◽  
...  

The absorption and oxidation reactions of SO2 on TiO2 nanoparticles were investigated by using a flow chamber, synchrotron X-ray absorption near-edge structure and high resolution synchrotron X-ray photoelectron spectroscopy techniques.

2018 ◽  
Vol 27 (11) ◽  
pp. 113101
Author(s):  
Jing Hu ◽  
Xiu-Neng Song ◽  
Sheng-Yu Wang ◽  
Juan Lin ◽  
Jun-Rong Zhang ◽  
...  

2009 ◽  
Vol 18 (7) ◽  
pp. 2734-2738 ◽  
Author(s):  
Zhang Hui ◽  
Liu Ying-Shu ◽  
Wang Bao-Yi ◽  
Wei Long ◽  
Kui Re-Xi ◽  
...  

2016 ◽  
Vol 4 (18) ◽  
pp. 6946-6954 ◽  
Author(s):  
E. N. K. Glover ◽  
S. G. Ellington ◽  
G. Sankar ◽  
R. G. Palgrave

The nature and effects of rhodium and antimony doping in TiO2 have been investigated using X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Extended X-ray Absorption Fine Structure (EXAFS), X-ray Absorption Near Edge Structure (XANES) and diffuse reflectance spectroscopy.


2020 ◽  
Vol 27 (2) ◽  
pp. 507-514
Author(s):  
Geonhwa Kim ◽  
Youngseok Yu ◽  
Hojoon Lim ◽  
Beomgyun Jeong ◽  
Jouhahn Lee ◽  
...  

Beamline 8A (BL 8A) is an undulator-based soft X-ray beamline at Pohang Accelerator Laboratory. This beamline is aimed at high-resolution ambient-pressure X-ray photoelectron spectroscopy (AP-XPS), soft X-ray absorption spectroscopy (soft-XAS) and scanning photoemission microscopy (SPEM) experiments. BL 8A has two branches, 8A1 SPEM and 8A2 AP-XPS, that share a plane undulator, the first mirror (M1) and the monochromator. The photon beam is switched between the two branches by changing the refocusing mirrors after the monochromator. The acceptance angle of M1 is kept glancing at 1.2°, and Pt is coated onto the mirrors to achieve high reflectance, which ensures a wide photon energy range (100–2000 eV) with high resolution at a photon flux of ∼1013 photons s−1. In this article, the main properties and performance of the beamline are reported, together with selected experiments performed on the new beamline and experimental system.


2003 ◽  
Vol 17 (18n20) ◽  
pp. 3745-3748 ◽  
Author(s):  
B. H. Kim ◽  
J. S. Kim ◽  
D. C. Kim ◽  
Y. W. Park ◽  
A. Maignan ◽  
...  

Valence state of the doped Ru at the Mn sites in Pr 0.5 Sr 0.5 MnO 3 has been studied using Ru K-edge X-ray absorption near-edge structure (XANES) spectroscopy. In comparison with XANES of reference ruthenates, it is found that the Mn-site doped Ru is dominantly in tetravalent state. This result suggests that the change of charge carrier density by Ru doping is not sufficient to understand drastic enhancement of ferromagnetism observed in the transport properties of Ru-doped Pr 0.5 Sr 0.5 MnO 3. The prime role of Ru in Mn 3+– O – Mn 4+ networks is discussed in terms of the valency effect and the magnetic interactions between doped Ru and Mn ions.


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