Tuning the electronic structures of monolayer triphosphides MP3 (M = Sn and Ge) for CO2 electroreduction through interface engineering: a theoretical prediction

2020 ◽  
Vol 22 (13) ◽  
pp. 6896-6905 ◽  
Author(s):  
Zhongxu Wang ◽  
Jingxiang Zhao

By DFT computations, SnP3 and GeP3 monolayers were identified as hopeful electrocatalysts with high-efficiency and high-selectivity for CO2 reduction by interface engineering with graphene, which is ascribed to the charge transfer at the interface.

2020 ◽  
Vol 8 (17) ◽  
pp. 8360-8375
Author(s):  
Shuai Xu ◽  
Ming-Hui Huang ◽  
Tao Li ◽  
Zhi-Quan Wei ◽  
Xin Lin ◽  
...  

An ionic polyelectrolyte was for the first time revealed to serve as an unexpected high-efficiency cascade charge transfer mediator toward versatile photoredox organic transformations under visible light irradiation.


Carbon ◽  
2021 ◽  
Author(s):  
Huijuan Yang ◽  
Xingpu Wang ◽  
ShengBao Wang ◽  
Pengyang Zhang ◽  
Chi Xiao ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Mingzi Sun ◽  
Qiuyang Lu ◽  
Zhong Lin Wang ◽  
Bolong Huang

AbstractThe charge transfer phenomenon of contact electrification even exists in the liquid–solid interface by a tiny droplet on the solid surface. In this work, we have investigated the contact electrification mechanism at the liquid–solid interface from the electronic structures at the atomic level. The electronic structures display stronger modulations by the outmost shell charge transfer via surface electrostatic charge perturbation than the inter-bonding-orbital charge transfer at the liquid–solid interface, supporting more factors being involved in charge transfer via contact electrification. Meanwhile, we introduce the electrochemical cell model to quantify the charge transfer based on the pinning factor to linearly correlate the charge transfer and the electronic structures. The pinning factor exhibits a more direct visualization of the charge transfer at the liquid–solid interface. This work supplies critical guidance for describing, quantifying, and modulating the contact electrification induced charge transfer systems in triboelectric nanogenerators in future works.


RSC Advances ◽  
2019 ◽  
Vol 9 (69) ◽  
pp. 40292-40300
Author(s):  
Anantharaj Gopalraman ◽  
Subbian Karuppuchamy ◽  
Saranyan Vijayaraghavan

VOC–JSC trade off is eliminated. Newly created surface states by OA in TiO2 facilitated the charge transfer kinetics.


2021 ◽  
Vol 426 ◽  
pp. 131867
Author(s):  
Xiaoshan Wang ◽  
Wenhang Wang ◽  
Jinqiang Zhang ◽  
Hongzhi Wang ◽  
Zhongxue Yang ◽  
...  

Nano Research ◽  
2018 ◽  
Vol 12 (2) ◽  
pp. 345-349 ◽  
Author(s):  
Zhao Cai ◽  
Yusheng Zhang ◽  
Yuxin Zhao ◽  
Yueshen Wu ◽  
Wenwen Xu ◽  
...  

2019 ◽  
Vol 244 ◽  
pp. 529-535 ◽  
Author(s):  
Lulu Zhang ◽  
Hongwen Zhang ◽  
Bo Wang ◽  
Xueyan Huang ◽  
Yun Ye ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (64) ◽  
pp. 40615-40620 ◽  
Author(s):  
Kui Du ◽  
Shizhen Niu ◽  
Li Qiao ◽  
Yandong Dou ◽  
Qing Zhu ◽  
...  

A simple ratiometric sensor (L1) for the cascade detection of Zn2+ and H2PO4− with high selectivity was reported based on the intermolecular charge transfer (ICT) mechanism.


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