Synthesis of MOF-on-MOF architectures in the context of interfacial lattice matching

CrystEngComm ◽  
2021 ◽  
Author(s):  
Junsu Ha ◽  
Hoi Ri Moon

Functional materials based on metal-organic frameworks (MOFs), especially MOF-on-MOF architectures, have attracted great interest for their potential application in a range of fields. The well-defined crystalline features of MOFs encourage...

2021 ◽  
Author(s):  
Dae-Woon Lim ◽  
Hiroshi Kitagawa

Since the transition of energy platforms, the proton-conductive metal–organic frameworks (MOFs) exhibiting high performance have been extensively investigated with rational strategies for their potential application in solid-state electrolytes.


2018 ◽  
Vol 1123 ◽  
pp. 012055
Author(s):  
Norani Muti Mohamed ◽  
Robabeh Bashiri ◽  
Muhammad Umair Shahid ◽  
Chong Fai kait ◽  
Suriati Sufian

Author(s):  
Peiyu Cai ◽  
Wenmiao Chen ◽  
Gregory S. Day ◽  
Hannah F. Drake ◽  
Elizabeth A. Joseph ◽  
...  

2017 ◽  
Vol 53 (7) ◽  
pp. 1249-1252 ◽  
Author(s):  
Kang Liang ◽  
Ru Wang ◽  
Manon Boutter ◽  
Cara M. Doherty ◽  
Xavier Mulet ◽  
...  

Biomimetic mineralization exploits natural biomineralization processes for the design and fabrication of synthetic functional materials.


2021 ◽  
Author(s):  
Adam Sapnik ◽  
Christopher W. Ashling ◽  
Lauren K. Macreadie ◽  
Seok J. Lee ◽  
Tim Johnson ◽  
...  

<div><p>Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas adsorption in the topologically disordered Fe-BTC framework and its crystalline counterpart, MIL‑100. Despite their similar chemistry and local structure, they exhibit very different sorption behaviour towards a range of industrial gases, noble gases and hydrocarbons. Virial analysis reveals that Fe-BTC has enhanced interaction strength with guest molecules compared to MIL‑100. Most notably, we observe striking discrimination between the adsorption of C<sub>3</sub>H<sub>6</sub> and C<sub>3</sub>H<sub>8</sub> in Fe‑BTC, with over a twofold increase in the amount of C<sub>3</sub>H<sub>6</sub> being adsorbed than C<sub>3</sub>H<sub>8</sub>. Thermodynamic selectivity towards a range of industrially relevant binary mixtures is probed using ideal adsorbed solution theory (IAST). Together, this suggests the disordered material may possess powerful separation capabilities that are rare even amongst crystalline frameworks.</p></div>


2019 ◽  
Vol 11 (19) ◽  
pp. 17350-17358 ◽  
Author(s):  
Philipp Brandt ◽  
Alexander Nuhnen ◽  
Marcus Lange ◽  
Jens Möllmer ◽  
Oliver Weingart ◽  
...  

ChemInform ◽  
2012 ◽  
Vol 43 (26) ◽  
pp. no-no
Author(s):  
Pounraj Thanasekaran ◽  
Tzuoo-Tsair Luo ◽  
Jing-Yun Wu ◽  
Kuang-Lieh Lu

Author(s):  
Adam Sapnik ◽  
Christopher W. Ashling ◽  
Lauren Macreadie ◽  
Seok J. Lee ◽  
Timothy Johnson ◽  
...  

Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas...


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