Interface synthesis for controllable construction of 2D Zn(Bim)(OAc) nanosheets via oil/water system and their application in oil

CrystEngComm ◽  
2021 ◽  
Author(s):  
Fei-Fei Wang ◽  
Haiyang Ding ◽  
Guang Tan ◽  
Zan Liu ◽  
Zhi-Lin Cheng
Keyword(s):  
Water System ◽  
Water Interface ◽  
Interface Synthesis ◽  
Oil Water

Fabrication of 2D Zn(Bim)(OAc) MOFs-structured nanosheets based on the oil/water interface.

scholarly journals Interfacial and Bulk Stabilization of Oil/Water System: A Novel Synergistic Approach

Nanomaterials ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 356 ◽  
Author(s):  
Ahmad Shakeel ◽  
Ujala Farooq ◽  
Claire Chassagne
Keyword(s):  
Volume Fraction ◽  
Water System ◽  
Water Interface ◽  
Long Term Stability ◽  
System A ◽  
Interfacial Modification ◽  
Solvent Type ◽  
Synergistic Approach ◽  
Oil Water ◽  
External Stimuli

Oil/water emulsions are usually stabilized either by interfacial modification using nanoparticles and surfactants (stated as pickering emulsion or bijels) or by bulk stabilization with the help of low-molecular-weight or polymeric gelators (known as bigels) in response to some external stimuli (e.g., pH, temperature). Both these approaches result in different systems that are quite useful for different applications, including catalysis, pharmaceutical and agrochemicals. However, these systems also possess some inherent drawbacks that need to be addressed, like difficulty in fabrication and ensuring the permanent binding of nanoparticles at the oil/water interface, in case of nanoparticles stabilized emulsions (i.e., interfacial stabilization). Similarly, the long-term stability of the oil/water systems produced by using (hydro/organo) gelators (i.e., bulk stabilization) is a major concern. Here, we show that the oil/water system with improved mechanical and structural properties can be prepared with the synergistic effect of interfacial and bulk stabilization. We achieve this by using nanoparticles to stabilize the oil/water interface and polymeric gelators to stabilize the bulk phases (oil and water). Furthermore, the proposed strategy is extremely adaptable, as the properties of the resultant system can be finely tuned by manipulating different parameters such as nanoparticles content and their surface functionalization, solvent type and its volume fraction, and type and amount of polymeric gelators.

OIL/WATER INTERFACE SYNTHESIS AND OPTICAL PROPERTY OF STRONTIUM TUNGSTATE NANORODS

NANO ◽  
2007 ◽  
Vol 02 (03) ◽  
pp. 195-199 ◽  
Author(s):  
Y. CHEN ◽  
Q. S. WU ◽  
Y. P. DING
Keyword(s):  
Solid Solution ◽  
Optical Properties ◽  
Optical Property ◽  
Formation Process ◽  
Lattice Parameters ◽  
Water Interface ◽  
Jcpds Card ◽  
Interface Synthesis ◽  
Oil Water ◽  
First Time

Strontium tungstate nanorods with uniform morphology were controllably synthesized for the first time via a facile liquid–solid–solution (LSS) process through oil/water interface. These nanorods have diameters of about 50 nm and length of about 500 nm. XRD curves indicated that as-obtained nanorods were body-centered tetragonal phases with lattice parameters of a = 5.416 Å and c = 11.95 Å, which is consistent with the values reported in JCPDS card No. 08-0490. Study on the optical properties of as-obtained nanorods showed that SrWO 4 nanorods possess different optical properties from bulk counterpart. A mechanism of the formation process was also discussed.

Porous materials from cellulose nanocrystal and mxene surfactants at the oil/water interface

2020 ◽  
Author(s):  
Bingqing qian ◽  
Haiqiao Wang ◽  
Dong Wang ◽  
Hao-Bin Zhang ◽  
Jessica Wu ◽  
...  
Keyword(s):  
Porous Materials ◽  
Cellulose Nanocrystal ◽  
Water Interface ◽  
Oil Water

Polarizability and nonpolarizability of oil-water interfaces with relevance to a.c. impendance measurements

1991 ◽  
Vol 56 (1) ◽  
pp. 112-129 ◽  
Author(s):  
Takashi Kakiuchi ◽  
Mitsugi Senda
Keyword(s):  
Charge Transfer ◽  
Numerical Calculation ◽  
Supporting Electrolyte ◽  
Water Interface ◽  
Migration Effect ◽  
Ac Current ◽  
Stationary Interface ◽  
Oil Water ◽  
Anion Transfer

We have estimated the degree of polarizability of a polarized oil-water interface used as a working interface and that of the nonpolarizability of a nonpolarized interface used as a reference oil-water interface from the numerical calculation of dc and ac current vs potential behavior at both interfaces. Theoretical equations of dc and ac currents for simultaneous cation and anion transfer of supporting electrolytes have been derived for the planar stationary interface for reversible and quasi-reversible cases. In the derivation, the migration effect and the coupling of the cation and anion transfer have been incorporated. The transfer of ions constituting a supporting electrolyte contributes to the total admittance of the interface even in the region where the interface may be considered as polarized in dc sense, as pointed out first by Samec et al. (J. Electroanal. Chem. 126, 121 (1981)). Moreover, the reference oil-water interface is not ideally reversible, so that the contribution from this interface to the measured admittance cannot be negligible, unless the area of the reference oil-water interface is much larger than that of the working oil-water interface. The effect of non-ideality of the reference oil-water interface on the determination of double layer capacitances and kinetic parameters of charge transfer at the working oil-water interface has been estimated.

scholarly journals New insights into the mechanisms of ultrasonic emulsification in the oil-water system and the role of gas bubbles

2021 ◽  
pp. 105501
Author(s):  
W.H. Wu ◽  
D.G. Eskin ◽  
A. Priyadarshi ◽  
T. Subroto ◽  
I. Tzanakis ◽  
...  
Keyword(s):  
Water System ◽  
Gas Bubbles ◽  
Ultrasonic Emulsification ◽  
Oil Water

Metal–Phenolic Network Covering on Zein Nanoparticles as a Regulator on the Oil/Water Interface

2020 ◽  
Vol 68 (31) ◽  
pp. 8471-8482
Author(s):  
Di Wu ◽  
Yalei Dai ◽  
Yunan Huang ◽  
Jin Gao ◽  
Hongshan Liang ◽  
...  
Keyword(s):  
Water Interface ◽  
Oil Water
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