Pre-organisation of ligand donor sets modulates the supramolecular structure of bis(pyridyl-imine) silver(I) chelates

CrystEngComm ◽  
2021 ◽  
Author(s):  
Chane Venter ◽  
Mathew P. Akerman
Keyword(s):  
Supramolecular Structure ◽  
Imine Ligands

Three bis(pyridyl-imine) ligands 1,2-bis(2-pyridylaminomethyl)benzene (L1), 1,3-bis(2- pyridylaminomethyl)benzene (L2) and 1,4-bis(2-pyridylaminomethyl)benzene (L3) were synthesised and complexed to silver(I) salts forming four novel complexes; 1,2-bis(2-pyridylaminomethyl)benzene-silver(I) hexafluoroantimonate(V) [Ag(L1)](SbF6), bis(1,3-bis(2-pyridylaminomethyl)benzene-di-silver(I)) bis(hexafluoroantimonate(V)) [Ag2-µ-(L2)2](SbF6)2, catena-1,4-bis(2-pyridylaminomethyl)benzene-silver(I)) hexafluoroantimonate(V)...

Acid-base properties and supramolecular structure ofN-[(hydroxymethyl)triazolyl]triflamides: DFT, ab initio, and FTIR study

2016 ◽  
Vol 30 (5) ◽  
pp. e3623 ◽  
Author(s):  
Bagrat A. Shainyan ◽  
Nina N. Chipanina ◽  
Larisa P. Oznobikhina ◽  
Vladimir I. Meshcheryakov
Keyword(s):  
Ab Initio ◽  
Supramolecular Structure ◽  
Acid Base ◽  
Ftir Study ◽  
Base Properties

Photo-responsive Schottky Diode Behavior of a Donor-Acceptor Co-crystal with Violet Blue Light Emission

CrystEngComm ◽  
2021 ◽  
Author(s):  
Sanjay Kumar ◽  
Soumen Singha ◽  
Rajkumar Jana ◽  
RITUPARNA MONDAL ◽  
Partha Pratim Bag ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Transport Property ◽  
Schottky Diode ◽  
Electronic Transport ◽  
Supramolecular Structure ◽  
Light Emission ◽  
Electronic Transport Property ◽  
Blue Light Emission ◽  
Donor Acceptor ◽  
Diode Behavior

Herein, we report the crystal structure, supramolecular structure, electronic transport property and optoelectronic behaviour of a co-crystal made of tetrabromoterephthalic acid (TBTA) and quinoxaline (QUIN) (1:1). The sample has been...

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