Alkali metal complexes of bis-o-xylyl-(17-crown-5): from a dinuclear monomer and a dinuclear polymer to sandwich polymer

CrystEngComm ◽  
2020 ◽  
Vol 22 (34) ◽  
pp. 5601-5605 ◽  
Author(s):  
Seulgi Kim ◽  
In-Hyeok Park ◽  
Shim Sung Lee ◽  
Wonbo Sim ◽  
Jai Young Lee

The self-assembly reactions of bis-o-xylyl-(17-crown-5) with alkali metal salts afforded binding mode (good fit, perching and sandwich)-dependent supramolecular complexes, including a sandwich-type cesium(i) coordination polymer.

Author(s):  
Jan Czapkiewicz ◽  
Jose L. del Castillo ◽  
Piotr Milart ◽  
Julio R. Rodriguez ◽  
Bożena Tutaj

RSC Advances ◽  
2016 ◽  
Vol 6 (84) ◽  
pp. 80916-80923 ◽  
Author(s):  
Srinivas Anga ◽  
Indrani Banerjee ◽  
Hari Pada Nayek ◽  
Tarun K. Panda

Alkali metal salts of {(CHPh2)2-pyr} and {(CPh3)2-pyr} were prepared and in the molecular structures of these complexes a nuclearity shift from the dimer to monomer were observed due to the substitutions of CHPh2 to CPh3 groups in imine nitrogen of the ligand.


Soft Matter ◽  
2021 ◽  
Vol 17 (13) ◽  
pp. 3654-3663
Author(s):  
Botian Li ◽  
Da Xiao ◽  
Xiaodong Gai ◽  
Bo Yan ◽  
Haimu Ye ◽  
...  

A multi-responsive self-healable organogel and colloid were fabricated by the assembly of a coordination polymer derived from Ag(i) and azopyridine ligands.


CrystEngComm ◽  
2019 ◽  
Vol 21 (47) ◽  
pp. 7249-7259 ◽  
Author(s):  
Li-Na Zhu ◽  
Zhao-Peng Deng ◽  
Li-Hua Huo ◽  
Shan Gao

The self-assembly of d10 metal salts and two racemic bis(pyridyl) diamine ligands generates ten complexes, showing diverse helical and wavelike chains, (4,4) layers, as well as 3D sqc and uog nets.


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