Luminescent coordination polymers constructed using a mixed-ligand strategy for highly selective luminescence sensing of nitrobenzene, Fe3+ and Cr2O72− ions and photodegradation of rhodamine B

CrystEngComm ◽  
2020 ◽  
Vol 22 (27) ◽  
pp. 4650-4664 ◽  
Author(s):  
Jun-Jie Wang ◽  
Fei-Fan Wu ◽  
Ning Su ◽  
Pan-Pan Li ◽  
Si-Yin Wang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Rhodamine B ◽  
Mixed Ligand ◽  
Highly Sensitive ◽  
Photocatalytic Activities

Using a mixed ligand strategy, ten new LCPs were constructed. They all display highly sensitive and selective luminescence sensing for NB, Cr2O72−and Fe3+ ions. Moreover, 3–10 also exhibit high photocatalytic activities toward the degradation of RhB.

Hydrothermal synthesis of two 2D uranyl coordination polymers: structure, luminescence, and photocatalytic degradation of rhodamine B

CrystEngComm ◽  
2020 ◽  
Vol 22 (35) ◽  
pp. 5716-5722 ◽  
Author(s):  
Xiaolan Tong ◽  
Shan Wang ◽  
HongXia Gao ◽  
Yingchong Ge ◽  
Jun Zuo ◽  
...  
Keyword(s):  
Hydrothermal Synthesis ◽  
Photocatalytic Degradation ◽  
Coordination Polymers ◽  
Rhodamine B ◽  
Equilibrium Time ◽  
Photocatalytic Activities

Two hydrothermal synthesized uranyl-organic coordination polymers showing effective photocatalytic activities for RhB degradation with quick equilibrium time in water.

scholarly journals Two mixed-ligand coordination polymers based on 2,5-thiophenedicarboxylic acid and flexible N-donor ligands: the protective effect on periodontitis via reducing the release of IL-1β and TNF-α

2020 ◽  
Vol 18 (1) ◽  
pp. 391-398
Author(s):  
Shao-Hsuan Wu ◽  
Jun-Hui Huang
Keyword(s):  
Coordination Polymers ◽  
Gingival Crevicular Fluid ◽  
Mixed Ligand ◽  
Donor Ligands ◽  
X Ray Diffraction ◽  
Functional Studies ◽  
Tnf Α ◽  
Mucosal Cells ◽  
Ligand Coordination ◽  
Crevicular Fluid

AbstractTwo novel mixed-ligand coordination polymers, {[Co(tdc)(btrp)]·0.67DMF}n (1) and {[Zn2(bimb)2(tdc)2]·2H2O}n (2) involving 2,5-thiophenedicarboxylate (H2tdc), and bitopic flexible N-donor ligands, 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) and 1,4-bis((1H-benzo[d]imidazol-1-yl)methyl)benzene (bimb), have been synthesized by the hydrothermal method and characterized via IR, elemental analysis, thermal analysis, and powder X-ray diffraction. The biological functional studies were performed; the treatment activity of the compounds on periodontitis and the specific mechanism was explored. First, the real-time RT-PCR was carried out to determine the inflammatory genes nf-κb and p53 relative expression in periodontal mucosal cells after treating with compounds 1 and 2. Then, the level of the inflammatory cytokine in the gingival crevicular fluid after treating with compounds was also determined by the ELISA detection kit.

scholarly journals Synthesis and characterization of Z-scheme heterostructure CoWO4/g-C3N4 as a visible-light photocatalyst for removal of organic pollutant

2021 ◽  
Vol 10 (2) ◽  
pp. 59-63
Author(s):  
Hai Pham Viet ◽  
Anh Dao Thi Ngoc ◽  
Viet Nguyen Minh ◽  
Ha Tran Thi Viet ◽  
Dang Do Van ◽  
...  
Keyword(s):  
Visible Light ◽  
Rhodamine B ◽  
High Performance ◽  
Organic Pollutant ◽  
Photogenerated Electron ◽  
Morphological Properties ◽  
Electron Hole ◽  
Visible Light Photocatalyst ◽  
Photocatalytic Activities

In this study, direct Z–scheme heterostructure CoWO4/g-C3N4 was synthesized by a facile hydrothermal method. The structural, morphological properties of the prepared samples were characterised by XRD, SEM, UV–Vis and PL measurements. The as-obtained heterostructure CoWO4/g-C3N4 exhibited enhanced photocatalytic activities toward the degradation of Rhodamine B under visible light irradiation with 92% Rhodamine B removal after 80 minutes irritation, which exceeded pristine g-C3N4 and CoWO4. The enhanced photocatalytic performance ascribed to interfacial contact between g-C3N4 and CoWO4, thus further inhibiting the recombination of photogenerated electron/hole pairs. It is anticipated that the construction of Z–scheme heterostructure CoWO4/g-C3N4 is an effective strategy to develop high-performance photocatalysts for the degradation of organic pollutants in water.

Synthesis, Crystal Structure and Fluorescence of Two Novel Mixed-Ligand Cadmium Coordination Polymers with Different Structural Motifs

2003 ◽  
Vol 2003 (14) ◽  
pp. 2705-2710 ◽  
Author(s):  
Junhua Luo ◽  
Maochun Hong ◽  
Ruihu Wang ◽  
Rong Cao ◽  
Lei Han ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Mixed Ligand ◽  
Structural Motifs
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