Superior thermally robust energetic materials featuring Z–E isomeric bis(3,4-diamino-1,2,4-triazol-5-yl)-1H-pyrazole: self-assembly nitrogen-rich tubes and templates with Hofmeister anion capture architecture

CrystEngComm ◽  
2020 ◽  
Vol 22 (18) ◽  
pp. 3144-3154
Author(s):  
Wenjing Geng ◽  
Yunfei Jia ◽  
Ya Chen ◽  
Qing Ma ◽  
Guijuan Fan ◽  
...  
Keyword(s):  
Self Assembly ◽  
Energetic Materials ◽  
Supramolecular Assembly ◽  
Hofmeister Anions

A super thermally robust nitrogen-rich framework was synthesized, and Z → E isomerization as well as supramolecular assembly inclusion strategy gave rise to two different nitrogen-rich tubes and templates with Hofmeister anions capture architecture.

scholarly journals Taming nitroformate through encapsulation with nitrogen-rich hydrogen-bonded organic frameworks

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jichuan Zhang ◽  
Yongan Feng ◽  
Richard J. Staples ◽  
Jiaheng Zhang ◽  
Jean’ne M. Shreeve
Keyword(s):  
Thermal Stability ◽  
Hydrogen Bonds ◽  
Self Assembly ◽  
Energetic Materials ◽  
Decomposition Temperature ◽  
High Oxygen Content ◽  
The Poor ◽  
Simple Preparation ◽  
First Time ◽  
Hydrogen Bonded

AbstractOwing to its simple preparation and high oxygen content, nitroformate [−C(NO2)3, NF] is an extremely attractive oxidant component for propellants and explosives. However, the poor thermostability of NF-based derivatives has been an unconquerable barrier for more than 150 years, thus hindering its application. In this study, the first example of a nitrogen-rich hydrogen-bonded organic framework (HOF-NF) is designed and constructed through self-assembly in energetic materials, in which NF anions are trapped in pores of the resulting framework via the dual force of ionic and hydrogen bonds from the strengthened framework. These factors lead to the decomposition temperature of the resulting HOF-NF moiety being 200 °C, which exceeds the challenge of thermal stability over 180 °C for the first time among NF-based compounds. A large number of NF-based compounds with high stabilities and excellent properties can be designed and synthesized on the basis of this work.

Morphology engineering: dramatic roles of serine and threonine in supramolecular assembly

RSC Advances ◽  
2016 ◽  
Vol 6 (48) ◽  
pp. 41761-41764 ◽  
Author(s):  
M. B. Bijesh ◽  
Rituraj Mishra ◽  
Narayanan D. Kurur ◽  
V. Haridas
Keyword(s):  
Self Assembly ◽  
Supramolecular Assembly ◽  
Morphology Engineering ◽  
Self Assembled

Macrocycles containing serine self-assembled into fibres, while threonine induced vesicular self-assembly. Macrocycles with serine can be driven to form vesicular assembly by incorporating a non-planar spacer.

Transparent, flexible MAPbI3 perovskite microwire arrays passivated with ultra-hydrophobic supramolecular self-assembly for stable and high-performance photodetectors

Nanoscale ◽  
2020 ◽  
Vol 12 (22) ◽  
pp. 11986-11996
Author(s):  
K. D. M. Rao ◽  
Mozakkar Hossain ◽  
Umesh ◽  
Aniket Roy ◽  
Anudeepa Ghosh ◽  
...  
Keyword(s):  
Self Assembly ◽  
High Performance ◽  
Supramolecular Assembly

Fully transparent perovskite microwire arrays passivated with supramolecular assembly for stable and high-performance photodetectors.

scholarly journals Dual self-assembly of supramolecular peptide nanotubes to provide stabilisation in water

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Julia Y. Rho ◽  
Henry Cox ◽  
Edward D. H. Mansfield ◽  
Sean H. Ellacott ◽  
Raoul Peltier ◽  
...  
Keyword(s):  
Self Assembly ◽  
Supramolecular Assembly ◽  
Ordered Structures ◽  
Peptide Bonds ◽  
Self Assembling ◽  
Peptide Hydrogen ◽  
Aqueous Conditions ◽  
Β Sheet ◽  
Peptide Core ◽  
Hydrogen Bonded

Abstract Self-assembling peptides have the ability to spontaneously aggregate into large ordered structures. The reversibility of the peptide hydrogen bonded supramolecular assembly make them tunable to a host of different applications, although it leaves them highly dynamic and prone to disassembly at the low concentration needed for biological applications. Here we demonstrate that a secondary hydrophobic interaction, near the peptide core, can stabilise the highly dynamic peptide bonds, without losing the vital solubility of the systems in aqueous conditions. This hierarchical self-assembly process can be used to stabilise a range of different β-sheet hydrogen bonded architectures.

Supramolecular assembly of dipeptide functionalized benzo[ghi]perylene monoimide directs white light emission via donor–acceptor interactions

RSC Advances ◽  
2015 ◽  
Vol 5 (109) ◽  
pp. 90158-90167 ◽  
Author(s):  
Manoj K. Manna ◽  
Dnyaneshwar B. Rasale ◽  
Apurba K. Das
Keyword(s):  
Energy Transfer ◽  
White Light ◽  
Self Assembly ◽  
Light Emission ◽  
Supramolecular Assembly ◽  
White Light Emission ◽  
Acid Molecule ◽  
Donor Acceptor

Optical and self-assembly nature of an aromatic dipeptide Phe-Phe (FF) functionalized benzo[ghi]perylene monoimide (BPI) are studied. Acceptor BPI-FF-OMe molecule shows white light emission upon energy transfer from donor pyrenebutyric acid molecule.

scholarly journals Geometric description of self-interaction potential in symmetric protein complexes

2019 ◽  
Vol 6 (1) ◽  
Author(s):  
Charly Empereur-Mot ◽  
Hector Garcia-Seisdedos ◽  
Nadav Elad ◽  
Sucharita Dey ◽  
Emmanuel D. Levy
Keyword(s):  
Self Assembly ◽  
Protein Complexes ◽  
Hot Spot ◽  
Point Mutations ◽  
Supramolecular Assembly ◽  
Internal Symmetry ◽  
Crystallographic Structure ◽  
Viral Capsids ◽  
Reliability Estimates ◽  
Order Structures

Abstract Proteins can self-associate with copies of themselves to form symmetric complexes called homomers. Homomers are widespread in all kingdoms of life and allow for unique geometric and functional properties, as reflected in viral capsids or allostery. Once a protein forms a homomer, however, its internal symmetry can compound the effect of point mutations and trigger uncontrolled self-assembly into high-order structures. We identified mutation hot spots for supramolecular assembly, which are predictable by geometry. Here, we present a dataset of descriptors that characterize these hot spot positions both geometrically and chemically, as well as computer scripts allowing the calculation and visualization of these properties for homomers of choice. Since the biological relevance of homomers is not readily available from their X-ray crystallographic structure, we also provide reliability estimates obtained by methods we recently developed. These data have implications in the study of disease-causing mutations, protein evolution and can be exploited in the design of biomaterials.

scholarly journals Mapping the supramolecular assembly space of poly(sarcosine)-b-poly(propylene sulfide) using a combinatorial copolymer library

2020 ◽  
Vol 56 (49) ◽  
pp. 6644-6647
Author(s):  
Molly Frey ◽  
Michael Vincent ◽  
Sharan Bobbala ◽  
Rajan Burt ◽  
Evan Scott
Keyword(s):  
Self Assembly ◽  
Supramolecular Assembly ◽  
Poly Propylene

A robust pipeline of synthesis, self-assembly, and characterization was employed to optimize the fabrication of poly(sarcosine)-b-poly(propylene sulfide) nanostructures.

The fabrication of supramolecular assembly with quadruple switchable fluorescence by ionic self-assembly strategy

2020 ◽  
Vol 596 ◽  
pp. 124708
Author(s):  
Pengliang Sui ◽  
Qiuhong Li ◽  
Huajie Yu ◽  
Dongqin Luo ◽  
Zhaoyu Zhang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Supramolecular Assembly ◽  
Assembly Strategy

scholarly journals Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage

2016 ◽  
Vol 45 (23) ◽  
pp. 9407-9411 ◽  
Author(s):  
Li Li ◽  
Yingjie Zhang ◽  
Maxim Avdeev ◽  
Leonard F. Lindoy ◽  
David G. Harman ◽  
...  
Keyword(s):  
Self Assembly ◽  
Supramolecular Assembly

A unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12·χsolvent has been synthesized via the supramolecular assembly between a non-centrosymmetric Dy(iii) metalloligand and Cu(ii) nitrate.

Supramolecular assembly of fluorogenic glyco-dots from perylenediimide-based glycoclusters for targeted imaging of cancer cells

2017 ◽  
Vol 53 (87) ◽  
pp. 11937-11940 ◽  
Author(s):  
Ying Liu ◽  
Ding-Kun Ji ◽  
Lei Dong ◽  
Nicolas Galanos ◽  
Yi Zang ◽  
...  
Keyword(s):  
Breast Cancer ◽  
Cancer Cells ◽  
Triple Negative Breast Cancer ◽  
Self Assembly ◽  
Breast Cancer Cells ◽  
Triple Negative ◽  
Supramolecular Assembly ◽  
Targeted Imaging

Supramolecular self-assembly between perylenediimide-based glycoclusters and a red-emitting fluorophore produces structurally uniform and stable glyco-dots amenable to targeted fluorogenic imaging of liver and triple-negative breast cancer cells.

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