scholarly journals Hypersensitive pressure-dependence of the conversion temperature of hysteretic valence tautomeric manganese–nitronyl nitroxide radical 2D-frameworks

2021 ◽  
Vol 57 (19) ◽  
pp. 2376-2379
Author(s):  
Constance Lecourt ◽  
Yuuta Izumi ◽  
Kseniya Maryunina ◽  
Katsuya Inoue ◽  
Nicolas Bélanger-Desmarais ◽  
...  

Under a mild external pressure of 0.1 GPa valence tautomeric compounds {[Mn2(NITIm)3]X}n with nitronyl nitroxide radical NITIm and X = ClO4− or BF4− have their conversion shifted upwards by almost 40 K with respect to room temperature.

2021 ◽  
Author(s):  
Hongdao Li ◽  
Pei Jing ◽  
Jiao Lu ◽  
Lu Xi ◽  
Qi Wang ◽  
...  

A family of 3d–4f heterometallic ring-shaped clusters on the basis of a nitrogen-rich nitronyl nitroxide radical have been obtained, and they feature polyfunctionality including magnetic properties, thermodynamics and luminescence behavior.


1989 ◽  
Vol 28 (16) ◽  
pp. 3230-3234 ◽  
Author(s):  
Cristiano Benelli ◽  
Andrea Caneschi ◽  
Dante Gatteschi ◽  
Luca Pardi ◽  
Paul Rey

Nanoscale ◽  
2021 ◽  
Author(s):  
Lorenzo Poggini ◽  
Alessandro Lunghi ◽  
Alberto Collauto ◽  
Antonio Barbon ◽  
Lidia Armelao ◽  
...  

A combined Tof-SIMS, XPS and STM characterization has been adopted here to study the deposition of a sulphur-functionalized nitronyl nitroxide radical on Au(111) clearly demonstrating the chemisorption of intact molecules....


1991 ◽  
Vol 180 (4) ◽  
pp. 327-331 ◽  
Author(s):  
Philippe Turek ◽  
Kiyokazu Nozawa ◽  
Daisuke Shiomi ◽  
Kunio Awaga ◽  
Tamotsu Inabe ◽  
...  

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