High-efficiency Pd nanoparticles loaded porous organic polymers membrane catalytic reactors

2021 ◽  
Author(s):  
Yaohan Chen ◽  
Yonggang Li ◽  
Lei Dai ◽  
Guorui Qin ◽  
Jing Guo ◽  
...  

Cross-linked porous organic polymer membranes were fabricated via interfacial azo-coupling polymerization and demonstrated to be a high-performance membrane catalytic reactor with a flux of 27.3 t m−2 day−1 for reducing the nitrophenols.

Author(s):  
Yifeng He ◽  
Man He ◽  
Beibei Chen ◽  
Bin Hu

A novel sulfur-containing functional core-shell magnetic porous organic polymer (Fe3O4@BD-TpMA-S-SH MOPs) was synthesized as magnetic solid phase extraction (MSPE) sorbent for mercury speciation followed by high performance liquid chromatography (HPLC)...


2017 ◽  
Vol 5 (42) ◽  
pp. 22163-22169 ◽  
Author(s):  
Baolong Zhou ◽  
Liangzhen Liu ◽  
Pingwei Cai ◽  
Guang Zeng ◽  
Xiaoqiang Li ◽  
...  

Two nitrogen-rich porous organic polymers (POPs) were prepared via Schiff base chemistry. Carbonization of these POPs results in porous carbon nanohybrids which exhibit excellent catalytic activity toward the oxygen reduction reaction (ORR).


Catalysts ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 802
Author(s):  
Chang Sun ◽  
Yingxin Mu ◽  
Yuxin Wang

Electrochemical ammonia synthesis, which is an alternative approach to the Haber–Bosch process, has attracted the attention of researchers because of its advantages including mild working conditions, environmental protection, and simple process. However, the biggest problem in this field is the lack of high-performance catalysts. Here, we report high-efficiency electroreduction of N2 to NH3 on γ-MnO2-supported Pd nanoparticles (Pd/γ-MnO2) under ambient conditions, which exhibits excellent catalytic activity with an NH3 yield rate of 19.72 μg·mg−1Pd h−1 and a Faradaic efficiency of 8.4% at −0.05 V vs. the reversible hydrogen electrode (RHE). X-ray diffraction (XRD) and transmission electron microscopy (TEM) characterization shows that Pd nanoparticles are homogeneously dispersed on the γ-MnO2. Pd/γ-MnO2 outperforms other catalysts including Pd/C and γ-MnO2 because of its synergistic catalytic effect between Pd and Mn.


RSC Advances ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 1586-1590 ◽  
Author(s):  
Lirong Xu ◽  
Ruiying Liu ◽  
Fang Wang ◽  
Shina Yan ◽  
Xinxin Shi ◽  
...  

POPM–TFP which exhibit well-defined rapid redox processes and high capacitance was prepared under solvothermal conditions.


2016 ◽  
Vol 128 (52) ◽  
pp. 16357-16360 ◽  
Author(s):  
Dong Won Kang ◽  
Kwang Soo Lim ◽  
Kyung Jin Lee ◽  
Jong Hyeon Lee ◽  
Woo Ram Lee ◽  
...  

2016 ◽  
Vol 5 (1) ◽  
pp. 1033-1045 ◽  
Author(s):  
Karnekanti Dhanalaxmi ◽  
Ramana Singuru ◽  
Sujan Mondal ◽  
Linyi Bai ◽  
Benjaram Mahipal Reddy ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (16) ◽  
pp. 9414-9419 ◽  
Author(s):  
Xianzhao Shao ◽  
Xinyi Miao ◽  
Xiaohu Yu ◽  
Wei Wang ◽  
Xiaohui Ji

Precise design of catalytic supports is an encouraging technique for simultaneously improving the activity and stability of the catalyst.


2019 ◽  
Vol 11 (27) ◽  
pp. 24140-24153 ◽  
Author(s):  
Subhash Chandra Shit ◽  
Paramita Koley ◽  
Boby Joseph ◽  
Carlo Marini ◽  
Lingaiah Nakka ◽  
...  

2020 ◽  
Vol 12 (41) ◽  
pp. 47110-47110
Author(s):  
Subhash Chandra Shit ◽  
Paramita Koley ◽  
Boby Joseph ◽  
Carlo Marini ◽  
Lingaiah Nakka ◽  
...  

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